chloryl nitrate | 65415-98-7

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 非金属氧阴离子化合物
• 英文名称: chloryl nitrate
• CAS: 65415-98-7
• 化学式: ClNO₅
• 分子量: 129.457
• InChiKey: BHEFGWPNZYRSEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.72
• 重原子数：
  7.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  98.49
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  二氧化氯 、 Nitrate 以 gaseous matrix 为溶剂， 生成 chloryl nitrate
  参考文献：
  名称：

  Chloryl nitrate: a novel product of the chlorine oxide (OClO) + nitrate radical + M recombination

  摘要：

  The products of the reaction of OClO with NO3 were investigated between 220 and 298 K using a flow reactor and infrared, visible, and ultraviolet analysis. At temperatures below 250 K new infrared and ultraviolet absorption features were observed and assigned to the novel compound chloryl nitrate (O2ClONO2). Additionally, ClO and NO2 were observed as reaction products, indicating the existence of a second reaction channel. O2ClONO2 formation predominates at temperatures below 230 K. The reaction rate constant at 220 K is estimated to be on the order of 10(-14) cm3 molecule-1 s-1 in 1-5 Torr of helium. These observations suggest that O2ClONO2 may exist in the terrestrial stratosphere.

  DOI：

  10.1021/j100198a002