tri-p-tolylantimony dinitrate | 671791-21-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tri-p-tolylantimony dinitrate
• 英文别名: (p-Tol)3Sb(NO3)2；[tris(4-methylphenyl)-nitrooxy-λ5-stibanyl] nitrate
• CAS: 671791-21-2；360572-78-7
• 化学式: C₂₁H₂₁N₂O₆Sb
• 分子量: 519.158
• InChiKey: IWGZZSYZWYGZKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.45
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  110
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  tri-p-tolylantimony dinitrate 、 penta(p-tolyl)antimony(V) 以 甲苯 为溶剂， 以97%的产率得到tetra-p-tolylantimony nitrate
  参考文献：
  名称：

  摘要：

  The reactions of pentaarylantimony with antimony derivatives Ar3SbX2 (Ar = Ph or p-Tol and X = OC(O)C6F5 or NO3) afford tetraphenylantimony pentafluorobenzoate (Ph4SbOC(O)C6F5) and tetra-p-tolylantimony nitrate (p-Tol(4)SbONO(2)). The compounds obtained were structurally characterized by X-ray diffraction analysis. The Sb atom in Ph4SbOC(O)C,FS has a distorted trigonal-bipyramidal environment with an axial perfluorobenzoate group. The trigonal-bipyramidal coordination of antimony in p-Tol(4)SbONO(2) is strongly distorted, with the O atom of the nitrato group lying in the axial plane.

  DOI：

  10.1023/a:1011335724711
• 作为产物：
  描述：

  三(对甲基苯基)二溴化锑 、 silver nitrate 以 甲苯 为溶剂， 生成 tri-p-tolylantimony dinitrate
  参考文献：
  名称：

  摘要：

  The reactions of pentaarylantimony with antimony derivatives Ar3SbX2 (Ar = Ph or p-Tol and X = OC(O)C6F5 or NO3) afford tetraphenylantimony pentafluorobenzoate (Ph4SbOC(O)C6F5) and tetra-p-tolylantimony nitrate (p-Tol(4)SbONO(2)). The compounds obtained were structurally characterized by X-ray diffraction analysis. The Sb atom in Ph4SbOC(O)C,FS has a distorted trigonal-bipyramidal environment with an axial perfluorobenzoate group. The trigonal-bipyramidal coordination of antimony in p-Tol(4)SbONO(2) is strongly distorted, with the O atom of the nitrato group lying in the axial plane.

  DOI：

  10.1023/a:1011335724711

文献信息

• ——
  作者：V. V. Sharutin、O. K. Sharutina、T. P. Platonova、A. P. Pakusina、L. P. Panova、G. K. Fukin、L. N. Zakharov

  DOI：10.1023/a:1024945617228

  日期：——

  Triarylantimony bis(arenesulfonates) were prepared by reaction of triarylantimonies with hydrogen peroxide in the presence of arenesulfonic acids. The steric structure of the products was assessed. Triarylantimony bis(arenesulfonates) were reacted with sodium salts to obtain sodium arenesulfonates and the corresponding triarylantimony derivatives.