[PdCl2{PhN(CH2PPh2)2}] | 129690-55-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [PdCl2{PhN(CH2PPh2)2}]
• 英文别名: [PdCl₂{PhN(CH₂PPh₂)₂}]
• CAS: 129690-55-7
• 化学式: C₃₂H₂₉Cl₂NP₂Pd
• 分子量: 666.862
• InChiKey: GRUVCWRKSLSJAY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  8.05
• 重原子数：
  38.0
• 可旋转键数：
  5.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  sodium cyanide 、 [PdCl2{PhN(CH2PPh2)2}] 以 甲醇 为溶剂， 反应 2.0h， 以84%的产率得到[Pd(CN)₂{PhN(CH₂PPh₂)₂}]
  参考文献：
  名称：

  Reprint of Bis(phosphinomethyl)phenylamines and bis(phosphinomethyl)sulfides and their reaction with d8-platinum group precursors

  摘要：

  The potentially tridentate phosphines R2PCH2XCH2PR2 [X = NPh, R = Ph (1), Bu-t (2), Cy (3), X = S, R = Ph (4), Bu-t (5)] were treated with different Pd(II), Pt(II) as well as Rh(I) and Ir(l) complex precursors. All new palladium and platinum compounds are formed as cis bisphosphine complexes. This is also the case if the sterically demanding phosphines 2 and 3 are treated with MCl(CO)(PPh3)(2) while the comparable reaction with 1 generates trigonal bipyramidal complexes. In contrast to this the reaction of 5 with Ir(CO)(2)Cl(p-TolNH(2)) forms the macrocycle 5b. All new compounds have been characterized by H-1, C-13, P-31 NMR and IR spectroscopy. Single crystal X-ray analysis has been performed from most of the compounds as well. (C) 2013 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2013.02.001

文献信息

• Bis(phosphinomethyl)phenylamines and bis(phosphinomethyl)sulfides and their reaction with d8-platinum group precursors
  作者：Marc Stickel、Caecilia Maichle-Moessmer、Lars Wesemann、Hermann A. Mayer

  DOI：10.1016/j.poly.2012.07.083

  日期：2012.10

  The potentially tridentate phosphines R2PCH2XCH2PR2 [X = NPh, R = Ph (1), Bu-t (2), Cy (3), X = S, R = Ph (4), Bu-t (5)] were treated with different Pd(II), Pt(II) as well as Rh(I) and Ir(I) complex precursors. All new palladium and platinum compounds are formed as cis bisphosphine complexes. This is also the case if the sterically demanding phosphines 2 and 3 are treated with MCl(CO)(PPh3)(2) while the comparable reaction with 1 generates trigonal bipyramidal complexes. In contrast to this the reaction of 5 with Ir(CO)(2)Cl(p-TolNH(2)) forms the macrocycle 5b. All new compounds have been characterized by H-1, C-13, P-31 NMR and IR spectroscopy. Single crystal X-ray analysis has been performed from most of the compounds as well. (C) 2012 Elsevier Ltd. All rights reserved.
• Reprint of Bis(phosphinomethyl)phenylamines and bis(phosphinomethyl)sulfides and their reaction with d8-platinum group precursors
  作者：Marc Stickel、Caecilia Maichle-Moessmer、Lars Wesemann、Hermann A. Mayer

  DOI：10.1016/j.poly.2013.02.001

  日期：2013.3

  The potentially tridentate phosphines R2PCH2XCH2PR2 [X = NPh, R = Ph (1), Bu-t (2), Cy (3), X = S, R = Ph (4), Bu-t (5)] were treated with different Pd(II), Pt(II) as well as Rh(I) and Ir(l) complex precursors. All new palladium and platinum compounds are formed as cis bisphosphine complexes. This is also the case if the sterically demanding phosphines 2 and 3 are treated with MCl(CO)(PPh3)(2) while the comparable reaction with 1 generates trigonal bipyramidal complexes. In contrast to this the reaction of 5 with Ir(CO)(2)Cl(p-TolNH(2)) forms the macrocycle 5b. All new compounds have been characterized by H-1, C-13, P-31 NMR and IR spectroscopy. Single crystal X-ray analysis has been performed from most of the compounds as well. (C) 2013 Published by Elsevier Ltd.