4-vinyloxymethyl-1,3-dioxolane | 99848-38-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: 4-vinyloxymethyl-1,3-dioxolane
• 英文别名: 4-vinyloximethyl-[1,3]dioxolane；4-Vinyloxymethyl-[1,3]dioxolan；4-Vinyl-oxymethyl-1,3-dioxolane；4-(ethenoxymethyl)-1,3-dioxolane
• CAS: 99848-38-1
• 化学式: C₆H₁₀O₃
• 分子量: 130.144
• InChiKey: LBEMCYGUGODFOX-UHFFFAOYSA-N

物化性质

• 沸点：
  45-47 °C(Press: 9 Torr)
• 密度：
  1.030±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 作用下， 生成 4-vinyloxymethyl-1,3-dioxolane
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：

文献信息

• Vinylation of hydroxy-containing cyclic formaldehyde acetals with acetylene
  作者：L. A. Oparina、O. V. Vysotskaya、L. N. Parshina、M. Ya. Khil’ko、N. K. Gusarova

  DOI：10.1134/s1070428008100060

  日期：2008.10

  Nucleophilic addition of alcohols having cyclic acetal fragments to acetylene smoothly occurs under relatively mild conditions (KOH, 100-125C, 1-2 h, initial acetylene pressure 11-12 atm) to give the corresponding vinyl ethers in 80-83% yield.
• NONAQUEOUS ELECTROLYTE, CAPACITOR DEVICE USING SAME, AND CARBOXYLIC ACID ESTER COMPOUND USED IN SAME
  申请人：MU IONIC SOLUTIONS CORPORATION

  公开号：US20210320334A1

  公开（公告）日：2021-10-14

  The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics in the case of using an energy storage device at a high temperature and at a high voltage and further capable of inhibiting the gas generation while maintaining a capacity retention rate after storage at a high temperature and at a high voltage and also provides an energy storage device using the same. Disclosed is a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing a carboxylic acid ester compound represented by the following general formula (I). In the formula, each of R 1 and R 2 independently represents a hydrogen atom, a —C(═O)—OR 4 group, or the like, and R 1 and R 2 may be bonded to each other to form a ring structure. R 3 represents a hydrogen atom or the like, and n represents an integer of 1 to 3. When n is 1, then L and R 4 represent an alkyl group having 1 to 6 carbon atoms or the like; and when n is 2 or 3, then L represents an n-valent connecting group, X represents a —C(═O)— group, an —S(═O)— group, an —S(═O) 2 — group, an —S(═O) 2 —R 5 —S(═O) 2 — group or a CR 6 R 7 group, R 5 represents an alkylene group having 1 to 4 carbon atoms, and each of R 6 and R 7 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.
• Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104
  作者：Reppe et al.

  DOI：——

  日期：——