N-propylidene-(2-ethyl-hexen-1-yl-amine) | 69882-94-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-propylidene-(2-ethyl-hexen-1-yl-amine)
• 英文别名: N-propylidene-(2-ethylhexen-1-yl-amine)；N-(2-ethylhex-1-enyl)propan-1-imine
• CAS: 69882-94-6
• 化学式: C₁₁H₂₁N
• 分子量: 167.294
• InChiKey: HLXJOOIVRPZTET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-propylidene-(2-ethyl-hexen-1-yl-amine) 生成 3,12-diethyl-3-n-butyl-1-aza-1,5,9-cyclododecatriene
  参考文献：
  名称：

  Substituted 1,11-diaminoundecanes, processes for producing them, and

  摘要：

  描述了新型取代的1,11-二胺十一烷，特别是那些符合以下式的化合物[R.sub.1是具有1-12个碳原子的烷基，R.sub.2是氢或具有1-12个碳原子的烷基，R.sub.3是具有1-12个碳原子的烷基，环烷基具有4-12个碳原子，芳基具有7或8个碳原子，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R.sub.4是氢，具有1-12个碳原子的烷基，环烷基具有4-12个碳原子，或未取代或取代的芳基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4一起是具有3-11个碳原子的亚基]，以及生产它们的过程。式I的化合物可以用于生产聚缩酸酯产品，特别是聚酰胺。它们也可以用作环氧树脂的固化剂。

  公开号：

  US04460790A1
• 作为产物：
  描述：

  (2-ethyl-hexylidene)-allylamine 、 potassium tert-butylate 以 四氢呋喃 为溶剂， 以85.2%的产率得到N-propylidene-(2-ethyl-hexen-1-yl-amine)
  参考文献：
  名称：

  1-Aza-1,5,9-cyclododecatrienes

  摘要：

  描述了公式##STR1##的化合物及其制备方法，方法是通过在催化剂存在下将氮丁二烯与二烯反应，特别是1,3-丁二烯。在公式I中，R.sub.1和R.sub.3彼此独立地是氢或具有1-8个碳原子的烷基，R.sub.2和R.sub.4彼此独立地是具有1-8个碳原子的烷基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4与连接的碳原子一起形成具有4-8个碳原子的环脂环，R.sub.5和R.sub.6彼此独立地是氢或具有1-4个碳原子的烷基。公式I的化合物是用于制备用于对抗植物害虫的活性化合物的有价值的中间体。

  公开号：

  US04213901A1

文献信息

• Substituted 11-aminoundecanols
  申请人：Ciba-Geigy Corporation

  公开号：US04332969A1

  公开（公告）日：1982-06-01

  Novel substituted 11-aminoundecanols of the formula ##STR1## and a process for their preparation are described; in the formula, R.sub.1 and R.sub.3 independently of one another are hydrogen or alkyl having 1-8 C atoms and R.sub.2 and R.sub.4 independently of one another are alkyl having 1-8 C atoms, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together with the bonding C atom form a cycloaliphatic ring having 4-8 C atoms, and R.sub.5 and R.sub.6 independently of one another are hydrogen or alkyl having 1-4 C atoms. The compounds of the formula I are valuable active compounds for combating plant pests.

  描述了一种新颖的替代品，其为式##STR1##的11-氨基十一醇，以及其制备方法；在该式中，R.sub.1和R.sub.3彼此独立地是氢或具有1-8个碳原子的烷基，R.sub.2和R.sub.4彼此独立地是具有1-8个碳原子的烷基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4与连接碳原子一起形成具有4-8个碳原子的环脂环，R.sub.5和R.sub.6彼此独立地是氢或具有1-4个碳原子的烷基。式I的化合物是用于对抗植物害虫的有价值的活性化合物。
• Substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal
  申请人：Ciba-Geigy Corporation

  公开号：US04277621A1

  公开（公告）日：1981-07-07

  Novel substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal aldehyde-derivatives of the formulae Ia ##STR1## in which R.sub.1 to R.sub.6, Y and m are as defined in patent claim 1, and processes for their preparation are described. The compounds of the formulae Ia and Ib can be catalytically hydrogenated to novel 1,11-diaminoundecanes, which, in turn, can be used, for example, for the preparation of polycondensation products, in particular transparent polyamides, or as curing agents for epoxide resins.

  小说中替代11-氨基十一烯醛和11-氨基十一醛的衍生物的化学式Ia ##STR1##其中R.sub.1到R.sub.6、Y和m的定义如专利权要求1中所定义，并描述了它们的制备过程。化学式Ia和Ib的化合物可以通过催化氢化制备新型1,11-二氨基十一烷，进而可以用于制备聚酰胺等聚合产物，特别是透明聚酰胺，或用作环氧树脂的固化剂。
• 2-Aza-1,3-dienes
  申请人：Ciba-Geigy Corporation

  公开号：US04289905A1

  公开（公告）日：1981-09-15

  There are described compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another represent alkyl having 1-8 C atoms, or together with the bond C atom they represent a cycloaliphatic ring having 4-8 C atoms, and R.sub.3 represents ethyl; or wherein R.sub.1 represents alkyl having 1-8 C atoms, R.sub.2 represents hydrogen, or alkyl having 1-8 C atoms, and R.sub.3 represents tertiary alkyl having 4-8 C atoms. The compounds of the formula I can be produced in a simple manner, in good to very good yields, by isomerisation of suitably substituted allylamines in an inert organic solvent and in the presence of a catalyst. The compounds of the formula I constitute valuable intermediates for producing active substances for combating plant pests.

  本文描述了以下式子的化合物：##STR1## 其中R.sub.1和R.sub.2分别独立地代表具有1-8个碳原子的烷基，或者与C原子的键一起代表具有4-8个碳原子的环状脂肪族环；而R.sub.3代表乙基；或者其中R.sub.1代表具有1-8个碳原子的烷基，R.sub.2代表氢原子或具有1-8个碳原子的烷基，而R.sub.3代表具有4-8个碳原子的三级烷基。式I的化合物可以通过在惰性有机溶剂和催化剂存在下，适当取代的烯丙胺异构化反应中简单地，收率良好地制备。式I的化合物是制造用于对抗植物害虫的活性物质的有价值的中间体。
• 1-Aza-1,5,9-cyclododecatrienes
  申请人：Ciba-Geigy Corporation

  公开号：US04213901A1

  公开（公告）日：1980-07-22

  Compounds of the formula ##STR1## and a process for their preparation by reacting azabutadienes with dienes, especially 1,3-butadiene, in the presence of catalysts are described. In the formula I, R.sub.1 and R.sub.3 independently of one another are hydrogen or alkyl having 1-8 C atoms and R.sub.2 and R.sub.4 independently of one another are alkyl having 1-8 C atoms, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together with the bonding C atom form a cycloaliphatic ring having 4-8 C atoms, and R.sub.5 and R.sub.6 independently of one another are hydrogen or alkyl having 1-4 C atoms. The compounds of the formula I are valuable intermediates for the preparation of active compounds for combating plant pests.

  描述了公式##STR1##的化合物及其制备方法，方法是通过在催化剂存在下将氮丁二烯与二烯反应，特别是1,3-丁二烯。在公式I中，R.sub.1和R.sub.3彼此独立地是氢或具有1-8个碳原子的烷基，R.sub.2和R.sub.4彼此独立地是具有1-8个碳原子的烷基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4与连接的碳原子一起形成具有4-8个碳原子的环脂环，R.sub.5和R.sub.6彼此独立地是氢或具有1-4个碳原子的烷基。公式I的化合物是用于制备用于对抗植物害虫的活性化合物的有价值的中间体。
• Substituted 1,11-diaminoundecanes, processes for producing them, and
  申请人：Ciba-Geigy Corporation

  公开号：US04460790A1

  公开（公告）日：1984-07-17

  There are described novel substituted 1,11-diaminoundecanes, particularly those of the formula ##STR1## [R.sub.1 is alkyl having 1-12 C atoms, R.sub.2 is hydrogen or alkyl having 1-12 C atoms, R.sub.3 is alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, aralkyl having 7 or 8 C atoms, unsubstituted or substituted aryl, pyridyl, furyl or thienyl, R.sub.4 is hydrogen, alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, or unsubstituted or substituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are alkylene having 3-11 C atoms], and processes for prducing them. The compound of the formula I can be used for example for producing polycondensation products, particularly polyamides. They can be used also as curing agents for epoxide resins.

  描述了新型取代的1,11-二胺十一烷，特别是那些符合以下式的化合物[R.sub.1是具有1-12个碳原子的烷基，R.sub.2是氢或具有1-12个碳原子的烷基，R.sub.3是具有1-12个碳原子的烷基，环烷基具有4-12个碳原子，芳基具有7或8个碳原子，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R.sub.4是氢，具有1-12个碳原子的烷基，环烷基具有4-12个碳原子，或未取代或取代的芳基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4一起是具有3-11个碳原子的亚基]，以及生产它们的过程。式I的化合物可以用于生产聚缩酸酯产品，特别是聚酰胺。它们也可以用作环氧树脂的固化剂。