4-(chlorodimethylsilyl)styrene | 1009-44-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(chlorodimethylsilyl)styrene
• 英文别名: p-(Chlorodimethylsilyl)styrene；chloro-(4-ethenylphenyl)-dimethylsilane
• CAS: 1009-44-5
• 化学式: C₁₀H₁₃ClSi
• 分子量: 196.752
• InChiKey: ZRZLAQZGAAWEIF-UHFFFAOYSA-N

物化性质

• 沸点：
  52.5 °C(Press: 0.34 Torr)
• 密度：
  1.041 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.98
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  4-(chlorodimethylsilyl)styrene 在 五氯化磷 、 二氧化硫 作用下， 以 苯 为溶剂， 生成 (4-(chlorodimethylsilyl)styryl)phosphonic dichloride
  参考文献：
  名称：

  Addition of phosphorus pentachloride to unsaturated organosilicon compounds

  摘要：

  DOI：

  10.1007/bf00908748
• 作为产物：
  描述：

  三氯(4-乙烯基苯基)硅烷 生成 4-(chlorodimethylsilyl)styrene
  参考文献：
  名称：

  Manami, Kogyo Kagaku zasshi / Journal of the Society of Chemical Industry, 1959, vol. 62, p. 529

  摘要：

  DOI：

文献信息

• Diphenylsiloxane oligomers functionalized at both terminal and method
  申请人：Dow Corning Asia, Ltd.

  公开号：US05502229A1

  公开（公告）日：1996-03-26

  There is disclosed a diphenylsiloxane oligomer functionalized at both terminals, and methods for the preparation thereof, said oligomer having the following general formula G-(OSi(Ph).sub.2).sub.m O--G wherein Ph denotes a phenyl radical, m is 3 to 50 and G is has a formula independently selected from the group consisting of ##STR1## in which R.sup.1 is independently selected from the group consisting of hydrogen and a monovalent hydrocarbon group having 2 to 8 carbon atoms, said monovalent hydrocarbon group excluding phenyl, tolyl, xylyl, and ethylphenyl radicals, R is independently selected from the group consisting of R.sup.1, methyl radical and phenyl radical, Q is a divalent hydrocarbon group and n is an integer having a value of 1 to 3.

  披露了一种在两个末端进行官能化的二苯基硅氧烷寡聚物，以及其制备方法，所述寡聚物具有以下一般式 G-(OSi(Ph).sub.2).sub.m O--G，其中Ph代表苯基，m为3至50，G具有以下独立选择的公式：其中R^1独立选择自氢和具有2至8个碳原子的一价碳氢基团，所述一价碳氢基团不包括苯基、甲苯基、二甲苯基和乙基苯基基团，R独立选择自R^1、甲基基团和苯基，Q是二价碳氢基团，n是一个值为1至3的整数。
• A Facile Synthesis of Disiloxanes with Functional Groups
  作者：Atsunori Mori、Tatsuhiro Hishida、Yoshiya Soga、Yusuke Kawakami

  DOI：10.1246/cl.1995.107

  日期：1995.2

  A facile synthetic method to obtain mono and difunctionalized disiloxanes, which can be used as various monomers for speciality polymers is described. The ring-opening of cyclic siloxanes with functionalized organometallic reagents followed by quenching with a variety of silyl chlorides gives the functionalized disiloxanes in good to excellent yields.

  本文介绍了一种简便的合成方法，可获得单官能化和双官能化二硅氧烷，这些二硅氧烷可用作特种聚合物的各种单体。用官能化有机金属试剂对环状硅氧烷进行开环反应，然后用各种硅基氯化物进行淬火，就能得到官能化二硅氧烷，收率从良好到极佳。
• Polysiloxane-styrene-butadiene terpolymers and use in toners
  申请人：Xerox Corporation

  公开号：US04770968A1

  公开（公告）日：1988-09-13

  A branched polysiloxane styrene butadiene polymer of the following formula ##STR1## wherein m is a number of from about 2 to about 10; z is the number 3,4 or 5; n is a number of from about 10 to about 1,000; k, l and o are weight fraction numbers with k being from about 0.35 to about 0.95, l being from 0.1 to about 0.2, and o is from about 0.05 to about 0.5; R is an aromatic substituent, alkyl-CR"C(O)O, and alkylene-CR"C(O)O, wherein R" is hydrogen or an alkyl substituent, and R' is an alkyl substituent or a trialkylsilylether substituent.

  以下是式子：##STR1## 其中m的数值在2到10之间；z的数值为3、4或5；n的数值在10到1,000之间；k、l和o是重量分数，其中k的数值在0.35到0.95之间，l的数值在0.1到0.2之间，o的数值在0.05到0.5之间；R是芳香族取代基、烷基-CR"C(O)O，以及烷基-CR"C(O)O，其中R"是氢或烷基取代基，而R'是烷基取代基或三烷基硅醚取代基。
• Chernyshev,E.A. et al., Journal of general chemistry of the USSR, 1966, vol. 36, p. 1626 - 1628
  作者：Chernyshev,E.A. et al.

  DOI：——

  日期：——
• Manami, Kogyo Kagaku zasshi / Journal of the Society of Chemical Industry, 1959, vol. 62, p. 529
  作者：Manami

  DOI：——

  日期：——