pyridine-2,6-dicarboxylic acid (S,S)-bis-[(1-naphthalen-1-yl-ethyl)amide] | 952093-67-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: pyridine-2,6-dicarboxylic acid (S,S)-bis-[(1-naphthalen-1-yl-ethyl)amide]
• 英文别名: 2-N,6-N-bis[(1S)-1-naphthalen-1-ylethyl]pyridine-2,6-dicarboxamide
• CAS: 952093-67-3
• 化学式: C₃₁H₂₇N₃O₂
• 分子量: 473.574
• InChiKey: RTLBZBIDGKKNIG-SFTDATJTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  71.1
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  pyridine-2,6-dicarboxylic acid (S,S)-bis-[(1-naphthalen-1-yl-ethyl)amide] 、 ytterbium(III) triflate 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Self-Assembly of Chiral Luminescent Lanthanide Coordination Bundles

  摘要：

  The synthesis and characterization of several highly ordered lanthanide complexes formed by the use of f-metal directed supramolecular synthesis is described. These unique self-assemblies or bundles are chiral as well as luminescent, where the lanthanide-based emission is observed upon excitation of the ligands (antennae) employed. These structures also give rise to chiral lanthanide luminescence (using CPL) demonstrating the chiral nature of these self-assemblies.

  DOI：

  10.1021/ja073049e
• 作为产物：
  描述：

  2,6-氯甲酰吡啶 、 (S)-(-)-1-(1-萘基)乙胺 在 TEA 作用下， 以 四氢呋喃 为溶剂， 以0.7779 g的产率得到pyridine-2,6-dicarboxylic acid (S,S)-bis-[(1-naphthalen-1-yl-ethyl)amide]
  参考文献：
  名称：

  Self-Assembly of Chiral Luminescent Lanthanide Coordination Bundles

  摘要：

  The synthesis and characterization of several highly ordered lanthanide complexes formed by the use of f-metal directed supramolecular synthesis is described. These unique self-assemblies or bundles are chiral as well as luminescent, where the lanthanide-based emission is observed upon excitation of the ligands (antennae) employed. These structures also give rise to chiral lanthanide luminescence (using CPL) demonstrating the chiral nature of these self-assemblies.

  DOI：

  10.1021/ja073049e

文献信息

• Self-Assembly of Chiral Luminescent Lanthanide Coordination Bundles
  作者：Joseph P. Leonard、Paul Jensen、Thomas McCabe、John E. O'Brien、Robert D. Peacock、Paul E. Kruger、Thorfinnur Gunnlaugsson

  DOI：10.1021/ja073049e

  日期：2007.9.1

  The synthesis and characterization of several highly ordered lanthanide complexes formed by the use of f-metal directed supramolecular synthesis is described. These unique self-assemblies or bundles are chiral as well as luminescent, where the lanthanide-based emission is observed upon excitation of the ligands (antennae) employed. These structures also give rise to chiral lanthanide luminescence (using CPL) demonstrating the chiral nature of these self-assemblies.