europium(III) 2,2'-((((carboxylatomethyl)azanediyl)bis(ethane-2,1-diyl))bis(([2,2'-bipyridin]-5-ylmethyl)azanediyl))diacetate | 618886-76-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: europium(III) 2,2'-((((carboxylatomethyl)azanediyl)bis(ethane-2,1-diyl))bis(([2,2'-bipyridin]-5-ylmethyl)azanediyl))diacetate
• CAS: 618886-76-3
• 化学式: C₃₂H₃₂N₇O₆*Eu
• 分子量: 762.609
• InChiKey: KCVYTKDCPBATFO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -1.54
• 重原子数：
  46.0
• 可旋转键数：
  18.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  181.67
• 氢给体数：
  0.0
• 氢受体数：
  13.0

反应信息

• 作为产物：
  描述：

  2,2'-((((carboxymethyl)azanediyl)bis(ethane-2,1-diyl))bis(([2,2'-bipyridin]-5-ylmethyl)azanediyl))diacetic acid 、 氯化铕(III) 在 borate buffer 作用下， 以 水 为溶剂， 生成 europium(III) 2,2'-((((carboxylatomethyl)azanediyl)bis(ethane-2,1-diyl))bis(([2,2'-bipyridin]-5-ylmethyl)azanediyl))diacetate
  参考文献：
  名称：

  Sensitization of europium(III) luminescence in bis(bipyridine) DTPA and DTTA-based ligands: effect of the deletion of amide groups

  摘要：

  Two new ligands containing two 2,2'-bipyridine groups and derived from diethylenetriaminepentaacetic acid (DTPA) (1) or diethylenetriaminetriacetic acid (DTTA) (2) were synthesized and the luminescent properties of their europium(III) complexes were investigated in aqueous solutions. In the two systems, the 2,2'-bipyridine chromophores act as antenna for the sensitization of the lanthanide ion and are not coordinated to the metal. It is shown that the change in ligand structure from 1 to 2 creates a higher antenna-to-metal energy transfer, and consequently a better luminescence quantum yield. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00162-x