N-(3,5-diiodo-salicylidene)cycloheptylamine | 1262508-42-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N-(3,5-diiodo-salicylidene)cycloheptylamine
• 英文别名: 2-(Cycloheptyliminomethyl)-4,6-diiodophenol
• CAS: 1262508-42-8
• 化学式: C₁₄H₁₇I₂NO
• 分子量: 469.104
• InChiKey: FFVIREAGLIFAME-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(3,5-diiodo-salicylidene)cycloheptylamine 、 氯化铪 在 n-BuLi 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 以70%的产率得到[hafnium(dichloride)(N-(3,5-diiodo-salicylidene)cycloheptylamine(-H))2]
  参考文献：
  名称：

  Catalysts for UHMWPE and UHMWPE-copolymers

  摘要：

  Classic inorganic and more recent organometallic compounds capable of polymerizing ethylene to ultra high molecular are compared. Activated catalysts showed varying degrees of productivity when challenged with co-monomers. The general activity trend followed TiCl3 < Mg/Si-TiCl3 < metallocenes. A new phenoxyimine catalyst complex N-(3,5-diiodosalicylidene) cycloheptylamine titanium dichloride was useful in making UHMWPE and compared to previously reported phenoxyimine catalyst structures capable of living polyolefin polymerizations. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.08.050
• 作为产物：
  描述：

  3,5-二碘邻羟基苯醛 、 环庚胺 以 正戊烷 为溶剂， 反应 4.0h， 生成 N-(3,5-diiodo-salicylidene)cycloheptylamine
  参考文献：
  名称：

  Catalysts for UHMWPE and UHMWPE-copolymers

  摘要：

  Classic inorganic and more recent organometallic compounds capable of polymerizing ethylene to ultra high molecular are compared. Activated catalysts showed varying degrees of productivity when challenged with co-monomers. The general activity trend followed TiCl3 < Mg/Si-TiCl3 < metallocenes. A new phenoxyimine catalyst complex N-(3,5-diiodosalicylidene) cycloheptylamine titanium dichloride was useful in making UHMWPE and compared to previously reported phenoxyimine catalyst structures capable of living polyolefin polymerizations. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.08.050