Synthesis of 3(2-haloethyl)aryltriazenes and study of their reactions in aqueous solution
作者:J. William Lown、Ranjit Singh
DOI:10.1139/v81-198
日期:1981.5.1
rates of decomposition in aqueous media at pH7 were determined polarographically employing the electrochemically active triazene moiety. In two selected cases the rates of decomposition increase markedly with lowered pH in the range 9.3 to 4.65. The products of aqueousdecomposition, both volatile and involatile, were identified and quantitated by gc and gc–ms. Discriminationbetweenalternative decomposition