(E,E)-N-Isopropyl-1-aza-1,3-pentadien | 32820-49-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (E,E)-N-Isopropyl-1-aza-1,3-pentadien
• 英文别名: trans-butenylidene-isopropylamine；N-isopropyl-(E)-2-butene-1-imine；trans-N-crotonyliden-isopropylamin
• CAS: 32820-49-8
• 化学式: C₇H₁₃N
• 分子量: 111.187
• InChiKey: TXVBMRBYDNEBDJ-DVBIZMGNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.04
• 重原子数：
  8.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  (E,E)-N-Isopropyl-1-aza-1,3-pentadien 在 六甲基磷酰三胺 、 N,N-二乙基苯胺 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 38.0h， 生成
  参考文献：
  名称：

  制备和的级联反应Ñ -butadienyl- Ñ -alkylketene Ñ，ö -叔丁基二甲基缩醛

  摘要：

  的制备Ñ -butadienyl- Ñ -alkylketene Ñ，ö -叔丁基二甲基缩醛（11A - d）从容易获得的原料进行说明。级联Diels-Alder反应，然后将这些烯酮缩醛酰化，可得到具有高非对映选择性的双环和三环产物7.13a，b和14c，d。

  DOI：

  10.1016/0040-4020(96)00646-1
• 作为产物：
  描述：

  巴豆醛 、 异丙胺 在 4 A molecular sieve 作用下， 以 乙醚 为溶剂， 生成 (E,E)-N-Isopropyl-1-aza-1,3-pentadien
  参考文献：
  名称：

  制备和的级联反应Ñ -butadienyl- Ñ -alkylketene Ñ，ö -叔丁基二甲基缩醛

  摘要：

  的制备Ñ -butadienyl- Ñ -alkylketene Ñ，ö -叔丁基二甲基缩醛（11A - d）从容易获得的原料进行说明。级联Diels-Alder反应，然后将这些烯酮缩醛酰化，可得到具有高非对映选择性的双环和三环产物7.13a，b和14c，d。

  DOI：

  10.1016/0040-4020(96)00646-1

文献信息

• Silylcuprates from Allene and Their Reaction with α,β-Unsaturatedd Nitriles and Imines. Synthesis of Silylated Oxo Compounds Leading to Cyclopentane and Cycloheptane Ring Formation
  作者：Asunción Barbero、Yolanda Blanco、Francisco J. Pulido

  DOI：10.1021/jo0509814

  日期：2005.8.1

  silylcupration of allenes and the subsequent capture of the intermediate cuprate with α,β-unsaturated nitriles is reported. The influence of the substitution of the nitrile, the nature of the silylcopper species, and the temperature on the selectivity of the reaction is studied. An interesting diaddition process was observed (1,2-addition and 1,4-addition), leading to oxo compounds which simultaneously have an allylsilane

  报道了丙二烯的甲硅烷基化和随后用α，β-不饱和腈捕获中间铜酸盐。研究了腈的取代，甲硅烷基铜物种的性质以及温度对反应选择性的影响。观察到一个有趣的二加成过程（1,2-加成和1,4-加成），导致同时具有烯丙基硅烷基和乙烯基硅烷基的氧代化合物。这两个单元的分子内烯丙基硅烷封端的环化反应已采用了这两个单元的不同反应性，其中乙烯基硅烷部分保持不变。为了阐明反应途径，还研究了α，β-不饱和亚胺的行为，并提出了一种新的方便的环庚烷环化方法。
• CHEMICAL VAPOR DEPOSITION RAW MATERIAL INCLUDING DINUCLEAR RUTHENIUM COMPLEX AND CHEMICAL DEPOSITION METHOD USING CHEMICAL VAPOR DEPOSITION RAW MATERIAL
  申请人：TANAKA KIKINZOKU KOGYO K.K.

  公开号：US20180201636A1

  公开（公告）日：2018-07-19

  The present invention relates to a chemical vapor deposition raw material for producing a ruthenium thin film or a ruthenium compound thin film by a chemical deposition method, the chemical vapor deposition raw material including a dinuclear ruthenium complex in which carbonyl and a nitrogen-containing organic ligand (L) are coordinated to metallically bonded two rutheniums, the dinuclear ruthenium complex being represented by the following formula ( 1 ): A raw material according to the present invention is capable of producing a high-purity ruthenium thin film, and has a low melting point and moderate thermal stability. Thus, the raw material according to the present invention is suitable for use in electrodes of various kinds of devices.

  本发明涉及一种化学气相沉积原料，用于通过化学沉积法制备钌薄膜或钌化合物薄膜，该化学气相沉积原料包括一个二核钌配合物，其中羰基和含氮有机配体（L）与两个钌金属键合配位，该二核钌配合物由以下公式（1）表示：本发明的原料能够产生高纯度的钌薄膜，具有较低的熔点和适中的热稳定性。因此，本发明的原料适用于各种设备的电极。
• Reactions of monoazadienes with metal carbonyl complexes.II. REACTIONS OF N-ALKYL-(E)-CROTONALDIMINE WITH Ru3(CO)12. THE X-RAY CRYSTAL STRUCTURE OF Ru3(CO)6(CH3-CCH-CHN-C3H7-i)2, AN ACYCLIC CLUSTER WHICH IS ISOLOBALLY RELATED TO RUTHENOCENE
  作者：Wilhelmus P. Mul、Cornelis J. Elsevier、Kees Vrieze、Wilberth J. J. Smeets、Anthony L. Spek

  DOI：10.1002/recl.19881070335

  日期：——

  The reaction of Ru3(CO)12 with CH3-CHCH-CHN-C3H7-i in refluxing heptane yields RU3(CO)6(CH3-CCH-CHN-C3H7-i)2 in two stereoisomeric forms, together with several other products. One of the stereoisomers was purified. The X-ray crystal structure shows an unprecedented bent trinuclear metal core with two metal-metal bonds. The two γ-metallated monoazadienyl ligands each donate 7e to the acyclic cluster

  钌的反应3（CO）12用CH 3 -CHCH-CHN-C 3 H ^ 7 -i在回流的正庚烷产生RU 3（CO）6（CH 3 -CCH-CHN-C 3 H ^ 7 -i）2在两种立体异构形式，以及其他几种产品。纯化了一种立体异构体。X射线晶体结构显示出前所未有的具有两个金属-金属键的弯曲三核金属核。两个γ-金属化的单氮杂二烯基配体各自为无环簇贡献7e。
• FT-IR investigation of the proton acceptor ability of trans-butenylidene-isopropylamine
  作者：P. Migchels、Th. Zeegers-Huyskens

  DOI：10.1016/0022-2860(91)87071-o

  日期：1991.7

  by OH⋯N bonds. The proton transfer constants have been calculated for complexes involving phenols (p K a =6−3.5). The variation of the stretching frequencies v (OH⋯N↔3O − ⋯H + N), and of the isotopic ratio of the stretching frequencies as a function of Δp K a shows a minimum at a Δ K a value between 2 and 2.5. This value corresponds to a double minimum for the potential surface of the proton and not

  摘要 在四氯化碳和 1,2-二氯乙烷中通过 FT-IR 光谱研究了反式亚丁烯基异丙胺 (BIPA) 和苯酚衍生物 (p K a =10.2-0.4) 之间的氢键。BIPA与苯酚之间形成氢键的热力学参数（p K a =10.20-7.75）表明配合物很强，光谱行为表明它们以OH⋯N键为特征。已经计算了涉及酚的复合物的质子转移常数 (p K a =6-3.5)。伸缩频率 v (OH⋯N↔3O − ⋯H + N) 的变化以及作为 Δp K a 函数的伸缩频率的同位素比的变化在 Δ K a 值介于 2 和 2.5 之间时显示出最小值。
• Chemical vapor deposition raw material including dinuclear ruthenium complex and chemical deposition method using chemical vapor deposition raw material
  申请人：TANAKA KIKINZOKU KOGYO K.K.

  公开号：US10815260B2

  公开（公告）日：2020-10-27

  The present invention relates to a chemical vapor deposition raw material for producing a ruthenium thin film or a ruthenium compound thin film by a chemical deposition method, the chemical vapor deposition raw material including a dinuclear ruthenium complex in which carbonyl and a nitrogen-containing organic ligand (L) are coordinated to metallically bonded two rutheniums, the dinuclear ruthenium complex being represented by the following formula (1): A raw material according to the present invention is capable of producing a high-purity ruthenium thin film, and has a low melting point and moderate thermal stability. Thus, the raw material according to the present invention is suitable for use in electrodes of various kinds of devices.

  本发明涉及一种通过化学沉积方法生产钌薄膜或钌化合物薄膜的化学气相沉积原料，该化学气相沉积原料包括二核钌络合物，其中羰基和含氮有机配体（L）与金属键合的两个钌配位，二核钌络合物由下式（1）表示：根据本发明的原材料能够生产出高纯度的钌薄膜，并具有低熔点和适度的热稳定性。因此，本发明的原材料适用于各种设备的电极。