(4-ethylphenyl)triphenylsilane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-ethylphenyl)triphenylsilane
• 英文别名: (4-Ethylphenyl)-triphenylsilane
• 化学式: C₂₆H₂₄Si
• 分子量: 364.562
• InChiKey: PMRQVWXBERSCDT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.63
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-乙基-4-碘苯 、 三苯基硅烷 在 二(三叔丁基膦)钯 potassium phosphate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 5.0h， 以53%的产率得到(4-ethylphenyl)triphenylsilane
  参考文献：
  名称：

  Palladium-Catalyzed Silylations of Hydrosilanes with Aryl Halides Using Bulky Alkyl Phosphine

  摘要：

  A palladium-catalyzed direct trialkylsilyl transfer to aryl halides has been developed. In the presence of Pd(t-Bu3P)(2) and K3PO4, electron-rich para- or meta-substitute aryl iodides were coupled efficiently with triethylsilane, triphenylsilane, and dimethylphenylsilane to afford the corresponding silylated products in moderate to good yields.

  DOI：

  10.1021/jo051131r

文献信息

• Palladium-Catalyzed Silylations of Hydrosilanes with Aryl Halides Using Bulky Alkyl Phosphine
  作者：Yoshinori Yamanoi

  DOI：10.1021/jo051131r

  日期：2005.11.1

  A palladium-catalyzed direct trialkylsilyl transfer to aryl halides has been developed. In the presence of Pd(t-Bu3P)(2) and K3PO4, electron-rich para- or meta-substitute aryl iodides were coupled efficiently with triethylsilane, triphenylsilane, and dimethylphenylsilane to afford the corresponding silylated products in moderate to good yields.