methoxybis(triphenyl-l5-phosphaneyl)osmium(VI) chloride | 131931-43-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methoxybis(triphenyl-l5-phosphaneyl)osmium(VI) chloride
• CAS: 131931-43-6
• 化学式: C₃₇H₃₄Cl₃OOsP₂
• 分子量: 853.183
• InChiKey: DMVCBMDQYHCAFB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  methoxybis(triphenyl-l5-phosphaneyl)osmium(VI) chloride 在 (CH₃CO)2CH₂ 作用下， 以 甲醇 为溶剂， 以65%的产率得到cis-dichloro-acetylacetonato-trans-bis(triphenylphosphin)osmium(III)
  参考文献：
  名称：

  Complexes of osmium(III) derived from O,O-donor ligands

  摘要：

  DOI：

  10.1016/s0277-5387(00)86959-4
• 作为产物：
  描述：

  sodium hexachloroosmate(IV) dihydrate 在 P(C₆H₅)3 、 CH₃OH 、 HCl 作用下， 以 盐酸 、 乙二醇甲醚 为溶剂， 以80%的产率得到methoxybis(triphenyl-l5-phosphaneyl)osmium(VI) chloride
  参考文献：
  名称：

  Complexes of osmium(III) derived from O,O-donor ligands

  摘要：

  DOI：

  10.1016/s0277-5387(00)86959-4

文献信息

• Osmium(III)o-semiquinonato complexes and their use as catalysts for the oxidation of alcohols
  作者：Ahmed M. El-Hendawy

  DOI：10.1016/s0020-1693(00)85881-8

  日期：1991.1

  The new complexes [Os(III)Cl2(PPh3)2SQ'] (SQ' = o-semiquinone; 1,2-benzosemiquinone (SQ), 4-methyl-1,2-benzosemiquinone, 3,5-di(tert-butyl)-1,2-benzosemiquinone, tetrachloro(tetrabromo)-1,2-benzosemiquinone and 2,3-naphthosemiquinone) have been isolated. They were characterised by spectroscopic techniques and investigated by cyclic voltammetry. The complex [OsCl2(PPh3)2SQ] was found to be more efficient than the reported [Os(III)Cl2(PPh3)2acac] as a catalyst for the oxidation of primary alcohols to aldehydes and of secondary alcohols to ketones in the presence of N-methylmorpholine-N-oxide as co-oxidant.
• Complexes of lawsone with uranium, molybdenum, ruthenium and osmium, and their use as organic oxidants
  作者：Ahmed M. El-Hendawy

  DOI：10.1016/s0277-5387(00)86217-8

  日期：1991.1

  The new complexes trans-[UO2(NQ)2], cis-[MoO2(NQ)2] and [M(III)Cl2(EPh3)2 NQ] (M = Ru, E = As; M = Os, E = P; HNQ = lawsone, 2-hydroxyl-1,4-naphthoquinone) have been prepared. They were characterized by spectroscopic techniques and investigated by cyclic voltammetry. The complex [RuCl2(AsPh3)2NQ] was found to be a more efficient catalyst than that of the osmium complex for the oxidation of primary alcohols to aldehydes and of secondary alcohols to ketones in the presence of N-methylmorpholine-N-oxide as co-oxidant.