N,N’-双(甲氧基甲基)脲 | 141-07-1

• 物质功能分类: 化学试剂 - 有机试剂 - 脲
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 中文名称: N,N’-双(甲氧基甲基)脲
• 中文别名: 1,3-双(甲氧基甲基)脲；N,N-双(甲氧基甲基)脲
• 英文名称: N,N'-bis(methoxymethyl)urea
• 英文别名: 1,3-bis(methoxymethyl)urea；1,3-bismethoxymethyl urea；N,N'-bis-methoxymethyl-urea；N,N'-Bis-methoxymethyl-harnstoff；N.N'-Bis-hydroxymethyl-harnstoff-dimethylaether；N.N'-Dimethylol-harnstoff-dimethylaether
• CAS: 141-07-1
• 化学式: C₅H₁₂N₂O₃
• 分子量: 148.162
• InChiKey: XKALZGSIEJZJCZ-UHFFFAOYSA-N

物化性质

• 熔点：
  101 °C
• 沸点：
  284.7±25.0 °C(Predicted)
• 密度：
  1.069±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  59.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N,N’-双(甲氧基甲基)脲 在 镍 作用下， 100.0 ℃ 、13.73 MPa 条件下， 生成 1,3-二甲基脲
  参考文献：
  名称：

  Production of n-methylamides

  摘要：

  公开号：

  US02422400A1
• 作为产物：
  描述：

  甲醇 、 1'3-双羟甲基脲 在 盐酸 作用下， 反应 0.17h， 生成 N,N’-双(甲氧基甲基)脲
  参考文献：
  名称：

  The Formation Pathway of 3,5-Bis(methoxymethyl)perhydro-1,3,5-oxadiazin-4-one

  摘要：

  对尿素及其甲基衍生物与甲醛的反应的研究阐明了3,5-双(甲氧基甲基)全氢-1,3,5-氧二嗪-4-酮的形成途径。1) 随着甲醛分子数量的增加，尿素与甲醛的加成反应变得越来越困难，这可能是由于羟甲基的立体位阻造成的。2) 3,5-双(甲氧基甲基)全氢-1,3,5-氧二嗪-4-酮被认为是通过三(羟甲基)脲和3-(羟甲基)全氢-1,3,5-氧二嗪-4-酮从尿素中衍生出来的，而不是通过四(羟甲基)脲或全氢-1,3,5-氧二嗪-4-酮。

  DOI：

  10.1246/bcsj.62.1930

文献信息

• Quaternary nitrogen condensation products of methylol urea ethers
  申请人：AMERICAN CYANAMID CO

  公开号：US02344934A1

  公开（公告）日：1944-03-21

  Textiles are finished by impregnating them with an aqueous solution of a quaternary nitrogen salt of a melamine formaldehyde condensation product and decomposing the salt by subjecting the textiles to heat at temperatures above 80 DEG C. and setting the resin on the textile fibres. Methylol melamines or their alcohol reacted products are used in their uncured state in preparing the quaternary nitrogen salts, i.e. in unpolymerized or only partially polymerized products of general formula <;FORM:0587572/IV/1>; <;FORM:0587572/IV/2>; where A is -NH2, NHCH2OR or -N(CH2OR)2, B is -NH.CH2OR or -N(CH2OR)2, R1 is hydrogen or CH2OR, R is hydrogen or an alcohol forming radical, Mx represents the nucleus of a partially polymerized melamine - formaldehyde condensation product. In the alkylated products the alcohol used may be methyl, ethyl, propyl, isopropyl, butyl, isobutyl, amyl or isoamyl, but the water repellancy of the product is improved by using a higher aliphatic alcohol such as octyl, decyl, dodecyl, tetradecyl or octadecyl alcohols. Cyclo-aliphatic and aliphatic alcohols, e.g. cyclohexanol and benzyl alcohol respectively may be used. The more important classes of nitrogen bases to be condensed with the monomeric or uncured melamine formaldehyde products described above include the two of the formul <;FORM:0587572/IV/3>; <;FORM:0587572/IV/4>; where X1, X2 and X3 are alkyl radicals, Z is the residue of a pyridine base, Y is an anion, e.g. chlorine, bromine and iodine. The salts are prepared by heating the melamine-formaldehyde and tertiary nitrogen compounds together at temperatures not substantially higher than 80 DEG C., methanol or ethanol being present if desired. Salts of pyridine bases react quickly with the melamine-aldehyde condensation products at 50-70 DEG C. The salts are applied to the textiles in aqueous solution either alone or mixed with other materials, e.g. monomeric methylol melamines or their water-soluble methyl ethers, water-soluble methylol ureas, curing accelerators such as acid salts of phosphoric acid, hexamethylene tetramine, starches, gums and sulphonated oils. The textiles are impregnated by immersion, spraying or other mechanical means, then suspended in a drying oven at temperatures preferably between 240-300 DEG F. The cloth is washed with aqueous soap solution containing sodium carbonate. Cotton, linen, wool, viscose, cellulose acetate, spun rayon and silk may be satisfactorily treated as above.

  纺织品通过浸渍含有三元氮盐的三聚氰胺-甲醛缩合物的水溶液并在高于80摄氏度的温度下加热分解盐，使树脂在纤维上固定。在制备三元氮盐时，使用甲醇基三聚氰胺或其醇反应产物的未固化状态，即在未聚合或仅部分聚合的一般式为<;FORM:0587572/IV/1>; <;FORM:0587572/IV/2>; 的产物中。其中A为-NH2，NHCH2OR或-N（CH2OR）2，B为-NH.CH2OR或-N（CH2OR）2，R1为氢或CH2OR，R为氢或形成醇基的醇，Mx代表部分聚合三聚氰胺-甲醛缩合物的核。在烷基化产物中，所使用的醇可以是甲基、乙基、丙基、异丙基、丁基、异丁基、戊基或异戊基，但使用较高的脂肪醇，如辛醇、癸醇、十二烷基醇、十四烷基醇或十八烷基醇，可以提高产品的防水性。环烷基和脂肪醇，例如环己醇和苄醇，也可以使用。要与上述单体或未固化三聚氰胺-甲醛产品缩合的氮碱的更重要的类别包括两种公式<;FORM:0587572/IV/3>; <;FORM:0587572/IV/4>; 其中X1、X2和X3是烷基，Z是吡啶碱的残基，Y是阴离子，例如氯、溴和碘。如果需要，可以在不高于80摄氏度的温度下将三聚氰胺-甲醛和三级氮化合物一起加热制备盐，甲醇或乙醇可以存在。吡啶碱盐在50-70摄氏度下与三聚氰胺-甲醛缩合物迅速反应。这些盐可以单独或与其他材料混合在水溶液中应用于纺织品，例如单体甲醛三聚氰胺或其水溶性甲醚、水溶性甲醛脲、固化促进剂，例如磷酸的酸性盐、六亚甲基四胺、淀粉、胶和磺化油。纺织品通过浸泡、喷涂或其他机械手段进行浸渍，然后悬挂在干燥炉中，温度最好在240-300华氏度之间。布料用含有碳酸钠的水性肥皂溶液清洗。棉、亚麻、羊毛、粘胶、醋酸纤维素、人造丝和真丝都可以通过上述方法得到满意的处理。
• The Preparation and Structure of the Copper(II) Chloride Complex of 5,5′-Carbonylbis[1,3-dimethyl-3,4,5,6-tetrahydro-1,3,5-triazin-2(1<i>H</i>)-one]
  作者：Toichi Ebisuno、Michiaki Takimoto、Miyuki Takahashi、Ryuichi Shiba

  DOI：10.1246/bcsj.62.651

  日期：1989.2

  A new 1,3-dimethylurea–formaldehyde condensate like a crown compound with two rings, 5,5′-carbonylbis[1,3-dimethyl-3,4,5,6-tetrahydro-1,3,5-triazin-2(1H)-one], was prepared. The molecular structure of the complex with the condensate and copper(II) chloride (1:1) was determined by means of X-ray analysis. The copper(II) ion was coordinated intermolecularly between two oxygen atoms (O(2) and O(2)′ in

  一种新的 1,3-二甲基脲-甲醛缩合物，类似于具有两个环的冠化合物，5,5'-羰基双 [1,3-二甲基-3,4,5,6-四氢-1,3,5-triazin-2 (1H)-one]，制备。具有缩合物和氯化铜 (II) (1:1) 的配合物的分子结构通过 X 射线分析确定。铜 (II) 离子在两个氧原子之间进行分子间配位（相邻分子中的 O(2) 和 O(2)'）。
• Permanently stabilized polymers produced by after-treatment with
  申请人：Bayer Aktiengesellschaft

  公开号：US04153596A1

  公开（公告）日：1979-05-08

  This invention relates to permanently stabilized polymers containing substituted piperidine derivatives chemically attached to the polymer molecule through O- or N-atoms. Compounds based on 2,2,6,6-tetraalkyl piperidines have now been found which, on the one hand, have a very high stabilizing activity and, on the other hand, contain one or more reactive groups through which they are able to react with the polymers to be stabilized. Stabilized polymers, preferably polyurethane elastomer filaments, films and coatings with a permanent washing-resistant, boiling resistant, acid-resistant, dry-cleaning-resistant and solvent-resistant stabilization based on 2,2,6,6-tetraalkyl piperidine light stabilizers are thus obtained.

  本发明涉及一种永久稳定的聚合物，其中含有通过O-或N原子化学连接到聚合物分子上的取代哌啶衍生物。现已发现基于2,2,6,6-四烷基哌啶的化合物，一方面具有非常高的稳定活性，另一方面通过其中一个或多个反应性基团能够与待稳定的聚合物发生反应。因此，基于2,2,6,6-四烷基哌啶光稳定剂，可以获得具有永久耐洗、耐沸水、耐酸、耐干洗和耐溶剂稳定性的稳定聚合物，特别是聚氨酯弹性体丝、膜和涂层。
• Methylol derivatives of 2,2,6,6-tetraalkylpiperidines and their
  申请人：Bayer Aktiengesellschaft

  公开号：US04223147A1

  公开（公告）日：1980-09-16

  The invention relates to new methylol derivatives of 2,2,6,6-tetraalkylpiperidines, to their production and to their use as chemically attached stabilizers for polymers containing reactive OH- and NH-groups.

  本发明涉及新的2,2,6,6-四烷基哌啶甲醛衍生物，以及它们的制备和用作化学附着稳定剂的聚合物，这些聚合物含有反应性OH-和NH-基团。
• Dialkyl ethers of dimethylol urea and process for making same
  申请人：DU PONT

  公开号：US02213921A1

  公开（公告）日：1940-09-03