4,4',4"-tris[4-(2-bithienyl)phenyl]amine | 339985-35-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4,4',4"-tris[4-(2-bithienyl)phenyl]amine
• 英文别名: tris(4-(5-(thiophen-2-yl)thiophen-2-yl)phenyl)amine；tris[4-(2,2'-bithiophene-5-yl)phenyl]amine；4-(5-thiophen-2-ylthiophen-2-yl)-N,N-bis[4-(5-thiophen-2-ylthiophen-2-yl)phenyl]aniline
• CAS: 339985-35-2
• 化学式: C₄₂H₂₇NS₆
• 分子量: 738.079
• InChiKey: ANODXOVSOLCNIZ-UHFFFAOYSA-N

物化性质

• 密度：
  1.343±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  49
• 可旋转键数：
  9
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  173
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4,4',4"-tris[4-(2-bithienyl)phenyl]amine 在 N-溴代丁二酰亚胺(NBS) 、 溶剂黄146 作用下， 以 氯仿 为溶剂， 反应 2.5h， 以68%的产率得到tris(4-(5-(5-bromothiophen-2-yl)thiophen-2-yl)phenyl)amine
  参考文献：
  名称：

  New star-shaped molecules derived from thieno[3,2-b]thiophene unit and triphenylamine

  摘要：

  A series of new substituted triphenylamine (TPA) derivatives with alkyl thieno[3,2-b]thiophene and thiophene units were synthesized in a combinatorial manner. Suzuki coupling of a dioxaborolane TPA derivative and 2-bromo-3-nonylthieno[3,2-b]thiophene or Stille coupling of fresh stannyl thieno[3,2-b]thiophene was used. All compounds were characterized by H-1 and C-13 NMR, HRMS, UV-vis spectrometry and DSC measurements. It was demonstrated that the optical and thermal properties of these materials can be tuned by varying both the conjugation length and thienothiophene and thiophene combination on the TPA branches. Moreover, the measured molar extinction coefficients were increasing from 63,000 (lambda(max) = 354 nm) to 131,000 L mol(-1) cm(-1) (lambda(max) = 428 nm) for TPA-thienothiophenes and TPA-bithiophene thienothiophenes, respectively. Some of them showed molecular glass behavior. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.10.082
• 作为产物：
  描述：

  三[4-(2-噻吩基)苯基]胺 在 N-溴代丁二酰亚胺(NBS) 、 magnesium 作用下， 以 乙醚 、 二氯甲烷 、 溶剂黄146 为溶剂， 反应 15.0h， 生成 4,4',4"-tris[4-(2-bithienyl)phenyl]amine
  参考文献：
  名称：

  Synthesis and Electrochemical Properties of Oligo- and Poly(thienylphenylamine)s

  摘要：

  The oxidative polymerization of tris(thienylphenyl)amine derivatives was performed in acetonitrile by electrochemical and chemical methods. Oligomers were synthesized by stepwise coupling using coupling reactions. The polymer prepared using the trifunctional monomer on a Pt electrode showed significantly better redox behavior compared to that of the linear polymeric analogue, The branching polymers exhibit conductivity of 2-6 S/cm, which is more than 1 order of magnitude greater than the analogous linear polymer. The electropolymerization of trifunctional monomers provides the formation of a large amount of redox active polymers with a large capacity (ca. 40 mC/cm(2)) and a good redox activity in the electron transfer of ferrocene on the electrode.

  DOI：

  10.1021/ma011018c

文献信息

• 전하 수송성 바니시, 전하 수송성 박막 및 유기 일렉트로루미네센스 소자
  申请人：Nissan Chemical Corporation 닛산 가가쿠 가부시키가이샤(519980958906)

  公开号：KR20150040218A

  公开（公告）日：2015-04-14

  유기 EL 소자의 정공 주입층에 적용한 경우에 우수한 휘도 특성을 실현할 수 있는 박막을 부여하는 전하 수송성 바니시, 전하 수송성 박막 및 유기 EL 소자를 제공하는 것. 식(1)으로 표시되는 티오펜 유도체로 이루어지는 전하 수송성 물질과, 도펀트와, 유기 용매를 포함하는 것을 특징으로 하는 전하 수송성 바니시. (식 중, R~R은 각각 독립으로, 수소 원자, 할로겐 원자, 나이트로기, 사이아노기, 알데하이드기, 하이드록시기, 티올기, 카복실산기, 알킬기, 알케닐기, 알키닐기, 탄소수 6~20의 아릴기, -C(O)Y기, -OY기, -SY기, -C(O)OY기, -OC(O)Y기, -C(O)NHY기 또는 -C(O)NYY기를 나타낸다.)

  在应用于유기 EL器件的正极注入层时，提供能够实现优越光度特性的薄膜，提供具有电荷传输性质的涂层，以及提供电荷传输性质的薄膜和유기 EL器件。 具有由式（1）表示的由噻吩诱导体组成的电荷传输性材料，包括噻吩诱导体，氟醚和유机溶剂的电荷传输性涂层。 （在方程中，R〜R分别独立表示氢原子，卤原子，硝基，氰基，醛基，羟基，硫醇基，羧酸基，烷基，烯基，炔基，含有6〜20个碳的芳基，-C(O)Y基，-OY基，-SY基，-C(O)OY基，-OC(O)Y基，-C(O)NHY基或-C(O)NYY基。）
• Organic semiconductor material, organic semiconductor element and field effect transistor using the same
  申请人：Li Jian

  公开号：US20070045618A1

  公开（公告）日：2007-03-01

  An organic semiconductor material comprising an amine unit having a secondary or tertiary amine structure and a thiophene unit having a thiophene ring structure and preferably the amine unit has the following structure: wherein R 1 , R 2 , and R 3 independently represent hydrogen, an optionally substituted alkyl group, an optionally substituted alkoxy group, an optionally substituted ether group, or an optionally substituted aryl group and may be same or different from each other.

  一种有机半导体材料，包括具有二级或三级胺结构的胺单元和具有噻吩环结构的噻吩单元，优选的胺单元具有以下结构：其中R1、R2和R3独立地表示氢、可选择取代的烷基团、可选择取代的烷氧基团、可选择取代的醚基团或可选择取代的芳基团，且它们可以相同也可以不同。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Yabunouchi Nobuhiro

  公开号：US20110297924A1

  公开（公告）日：2011-12-08

  Provided are a long-lifetime organic electroluminescence device which can be fabricated in an improved yield owing to suppressed crystallization of molecules, and an aromatic amine derivative that realizes the device, i.e., a novel aromatic amine derivative having a specific structure. Specifically provided are an organic electroluminescence device, including an organic thin film layer formed of one or more layers including at least a light emitting layer, the organic thin film layer being interposed between a cathode and an anode, and an aromatic amine derivative for at least one layer of the organic thin film layer, in particular, a hole transporting layer, the derivative having at least one such structure that a substituent in which two or more specific heterocycles are linked to each other, in particular, a substituent in which two or more specific heterocycles are linked through an aryl group is bonded to an amine through an aryl group.

  提供了一种长寿命有机电致发光器件，由于分子的结晶被抑制，可以提高制造产量，以及实现该器件的芳香胺衍生物，即具有特定结构的新型芳香胺衍生物。具体提供了一种有机电致发光器件，包括由一个或多个层组成的有机薄膜层，其中至少包括一个发光层，有机薄膜层被夹在阴极和阳极之间，以及用于有机薄膜层的至少一层的芳香胺衍生物，特别是用于传输空穴的层，该衍生物具有至少一种这样的结构，其中通过芳基基团将两个或更多个特定的杂环连接在一起的取代基，特别是通过芳基基团将两个或更多个特定的杂环连接在一起的取代基与胺基通过芳基基团键合。
• TWI630193
  申请人：——

  公开号：——

  公开（公告）日：——
• US7781757B2
  申请人：——

  公开号：US7781757B2

  公开（公告）日：2010-08-24