1-(1-benzyloxybutyl)benzene | 112476-31-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(1-benzyloxybutyl)benzene
• 英文别名: 1-benzyloxy-1-phenylbutane；Benzene, [(1-phenylbutoxy)methyl]-；1-phenylbutoxymethylbenzene
• CAS: 112476-31-0
• 化学式: C₁₇H₂₀O
• 分子量: 240.345
• InChiKey: DLTHDUNRSUSYAH-UHFFFAOYSA-N

物化性质

• 沸点：
  326.0±11.0 °C(Predicted)
• 密度：
  1.003±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-(benzyloxy)-4-phenyl-1-butene 在 platinum(IV) oxide 氢气 作用下， 以 various solvent(s) 为溶剂， 反应 3.0h， 以91%的产率得到1-(1-benzyloxybutyl)benzene
  参考文献：
  名称：

  Poly(ethylene Glycol) (400) as Superior Solvent Medium against Ionic Liquids for Catalytic Hydrogenations with PtO₂

  摘要：

  Adams' catalyst in poly(ethylene glycol) (PEG) (400) has been found to be a superior solvent over the ionic liquids by severalfold in promoting the hydrogenation of various functional groups. Both the catalyst and PEG were recycled efficiently over 10 runs without loss of activity, and substrate cross contamination was not observed despite a change in the substrate four times.

  DOI：

  10.1021/jo052604x

文献信息

• Iron-catalysed, general and operationally simple formal hydrogenation using Fe(OTf)₃ and NaBH₄
  作者：Alistair J. MacNair、Ming-Ming Tran、Jennifer E. Nelson、G. Usherwood Sloan、Alan Ironmonger、Stephen P. Thomas

  DOI：10.1039/c4ob00945b

  日期：——

  An operationally simple and environmentally benign formal hydrogenation protocol has been developed using a highly abundant iron(iii) salt and an inexpensive, bench stable, stoichiometric reductant, NaBH₄, in ethanol, under ambient conditions.

  已开发出一种操作简单且环境友好的正规氢化方案，使用高丰度的铁（III）盐和廉价、台面稳定、化学计量还原剂NaBH4，在乙醇中，在常温下进行。
• A Novel Method for the Preparation of Ethers from Carbonyl Compounds with Benzenetellurol Catalyzed by ZnI₂
  作者：Keiichi Nagakawa、Masahiro Osuka、Kazuaki Sasaki、Yoshio Aso、Tetsuo Otsubo、Fumio Ogura

  DOI：10.1246/cl.1987.1331

  日期：1987.7.5

  Benzenetellurol is shown to behave as an effective reagent for the reductive conversion of carbonyl compounds into unsymmetrical ethers under the catalytic influence of ZnI2.

  苯碲酚被证明是一种有效的试剂，在ZnI2的催化作用下能够将羰基化合物还原转化为非对称醚。
• NAGAKAWA, KEIICHI;OSUKA, MASAHIRO;SASAKI, KAZUAKI;ASO, YOSHIO;OTSUBO, TET+, CHEM. LETT.,(1987) N 7, 1331-1334
  作者：NAGAKAWA, KEIICHI、OSUKA, MASAHIRO、SASAKI, KAZUAKI、ASO, YOSHIO、OTSUBO, TET+

  DOI：——

  日期：——
• Poly(ethylene Glycol) (400) as Superior Solvent Medium against Ionic Liquids for Catalytic Hydrogenations with PtO₂
  作者：Srivari Chandrasekhar、Samala Jaya Prakash、Chennamaneni Lohitha Rao

  DOI：10.1021/jo052604x

  日期：2006.3.1

  Adams' catalyst in poly(ethylene glycol) (PEG) (400) has been found to be a superior solvent over the ionic liquids by severalfold in promoting the hydrogenation of various functional groups. Both the catalyst and PEG were recycled efficiently over 10 runs without loss of activity, and substrate cross contamination was not observed despite a change in the substrate four times.