Elaidinsaeurenitril | 19491-41-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Elaidinsaeurenitril
• 英文别名: elaidonitrile；Elaidinonitril；9-octadecenenitrile；(E)-octadec-9-enenitrile
• CAS: 19491-41-9
• 化学式: C₁₈H₃₃N
• 分子量: 263.467
• InChiKey: UIAMCVSNZQYIQS-MDZDMXLPSA-N

物化性质

• 沸点：
  335-340 °C
• 密度：
  0.842±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Elaidinsaeurenitril 在 乙醇 、 sodium 作用下， 生成 9-十八碳烯-1-胺
  参考文献：
  名称：

  Krafft; Tritschler, Chemische Berichte, 1900, vol. 33, p. 3582

  摘要：

  DOI：
• 作为产物：
  描述：

  (E)-9-十八碳烯酰胺 在 五氯化磷 作用下， 生成 Elaidinsaeurenitril
  参考文献：
  名称：

  Krafft; Tritschler, Chemische Berichte, 1900, vol. 33, p. 3582

  摘要：

  DOI：

文献信息

• PROCESS FOR PREPARING SATURATED AMINO ACIDS OR SATURATED AMINO ESTERS COMPRISING A METATHESIS STEP
  申请人：Couturier Jean Luc

  公开号：US20130116458A1

  公开（公告）日：2013-05-09

  The subject matter of the invention is a process for synthesizing a saturated long-chain o.,0)-amino ester (acid) obtained in a first step by cross-metathesis between an acrylic first compound and a monounsaturated second compound comprising at least one nitrile, acid or ester trivalent function, one of these compounds comprising a nitrile function and the other an acid or ester function, in the presence of a ruthenium carbene metathesis catalyst, and in a second step by hydrogenation of the monounsaturated nitrile ester (acid) obtained in the presence of the metathesis catalyst of the preceding stop, acting as a hydrogenation catalyst.

  发明的主题是一种合成饱和长链O.,0）-氨基酯（酸）的过程，该过程首先通过交叉复分解在丙烯酸第一种化合物和至少含有一种腈、酸或酯三价功能的单不饱和第二种化合物之间进行，其中一种化合物含有腈功能，另一种化合物含有酸或酯功能，在钌卡宾复分解催化剂的存在下，然后在第二步中，通过氢化在前一步中获得的单不饱和腈酯（酸），在前一步中的复分解催化剂作为氢化催化剂的作用下。
• Method for Synthesizing an Omega-Amino Acid or Ester from a Monounsaturated Fatty Acid or Ester
  申请人：Dubois Jean-Luc

  公开号：US20110300590A1

  公开（公告）日：2011-12-08

  The invention relates to a method for synthesizing ω-aminoalkanoic acids or esters thereof from unsaturated natural fatty acids, passing through a monounsaturated dinitrile intermediate compound. The method of the invention is simple to carry out and, compared to other known methods, avoids the environmental constraints and economic disadvantages due to reaction by-products.

  该发明涉及一种从不饱和天然脂肪酸合成ω-氨基烷基酸或其酯的方法，经过一种单不饱和二腈中间化合物。该发明的方法易于实施，并与其他已知方法相比，避免了由于反应副产物而带来的环境约束和经济劣势。
• PROCESS FOR THE SYNTHESIS OF OMEGA-UNSATURATED NITRILE-ACID/ESTER IN WHICH TWO TYPES OF CROSS METATHESIS ARE ALTERNATED CONSECUTIVELY, SWING PROCESS
  申请人：ARKEMA FRANCE

  公开号：US20150336879A1

  公开（公告）日：2015-11-26

  A process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound I including at least one trivalent nitrile, acid or ester functional group, wherein the process includes a stage in which two types of cross metathesis are alternated consecutively: — a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II including a nitrile functional group and the other of these compounds II or I including an acid or ester functional group, and—a second type of cross metathesis cm2 with a light C 2 to C 4 alkene compound III. Also, a process for the synthesis of an α,ω-amino ester (acid) obtained by a process including a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.

  一种通过交叉烯烃反应从不饱和化合物I开始合成单不饱和腈酯（酸）的方法，其中不饱和化合物I包括至少一个三价腈酸，酸或酯官能团，在该过程中包括一个阶段，其中连续交替两种交叉烯烃反应类型：-第一种交叉烯烃反应cm1与丙烯腈，丙烯酸或丙烯酯中选择的一种丙烯化合物II进行反应，其中化合物I或II包括腈官能团，而这两种化合物II或I中的另一种包括酸或酯官能团，-第二种交叉烯烃反应cm2与轻质C2到C4烯烃化合物III进行反应。此外，还提供了一种通过交替进行上述两种交叉烯烃反应的阶段，然后进行氢化阶段而获得的α，ω-氨基酯（酸）的合成方法。
• PROCESS FOR PREPARING AMINO ACIDS OR ESTERS COMPRISING A METATHESIS STEP
  申请人：Couturier Jean-Luc

  公开号：US20140163196A1

  公开（公告）日：2014-06-12

  A process for synthesizing a long-chain saturated α,ω-amino ester (acid) including from 6 to 17 carbon atoms, said process including a first step of cross metathesis between a first acrylic compound chosen from acrylonitrile, acrylic acid or an acrylic ester and a second monounsaturated compound including at least one nitrile, acid or ester trivalent function, one of these compounds including a nitrile function and the other an acid or ester function, in the presence of a ruthenium carbene metathesis catalyst, and a second step of hydrogenation of the monounsaturated nitrile-ester (acid) obtained, wherein said monounsaturated compound including at least one nitrile, acid or ester trivalent function has previously been subjected to a purification by thermal and/or chemical treatment.

  一种合成长链饱和α,ω-氨基酯（酸）的方法，包括6至17个碳原子，该方法包括第一步交叉烯烃基化反应，反应物为从丙烯腈、丙烯酸或丙烯酯中选择的第一丙烯酸化合物和含有至少一个腈、酸或酯三价功能的第二单不饱和化合物，其中这些化合物中一个包括腈功能，另一个包括酸或酯功能，在钌卡宾烯烃交联催化剂的存在下进行，并且第二步对所得的单不饱和腈酯（酸）进行氢化，其中所述含有至少一个腈、酸或酯三价功能的单不饱和化合物已经经过热和/或化学处理的纯化。
• [EN] PREPARATION OF NITRILE COMPOUNDS<br/>[FR] PRÉPARATION DE COMPOSÉS NITRILES
  申请人：DSM IP ASSETS BV

  公开号：WO2013007634A1

  公开（公告）日：2013-01-17

  The invention relates to novel nitrile compounds according to formula I and II: (I) Formula I wherein: X = -CH3 or -C≡N, (II) Formula II wherein: X = -CH3 or -C≡N, each Y is independently chosen from -OH or RC(0)0-, each R is independently chosen from a C1 -21 alkyl group. The invention also relates to processes for the preparation of nitrile compounds according to formula I and II and to uses of the nitrile compounds.

  本发明涉及新的腈化合物，其符合以下公式：（I）公式I，其中：X = -CH3或-C≡N，（II）公式II，其中：X = -CH3或-C≡N，每个Y都独立选择自-OH或RC（0）0-，每个R都独立选择自C1-21烷基。本发明还涉及根据公式I和II制备腈化合物的方法以及腈化合物的用途。