methyl 2-{4-[N-methyl-N-(7-chloro-1,2,4-benzotriazin-3-yl)amino]phenoxy}propionate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl 2-{4-[N-methyl-N-(7-chloro-1,2,4-benzotriazin-3-yl)amino]phenoxy}propionate
• 英文别名: methyl 2-[4-[(7-chloro-1,2,4-benzotriazin-3-yl)-methylamino]phenoxy]propanoate
• 化学式: C₁₈H₁₇ClN₄O₃
• 分子量: 372.811
• InChiKey: KRPORSDDZYKAJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  77.4
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  methyl 2-{4-[N-methyl-N-(7-chloro-1,2,4-benzotriazin-3-yl)amino]phenoxy}propionate 、 双氧水 生成 Methyl 2-[4-[(7-chloro-2-oxido-1,2,4-benzotriazin-2-ium-3-yl)-methylamino]phenoxy]propanoate
  参考文献：
  名称：

  SERBAN, A.;FARQUHARSON, G. J.;LYDIATE, J.;BIRD, G. J.

  摘要：

  DOI：
• 作为产物：
  描述：

  对甲氨基酚 以 乙醇 为溶剂， 生成 methyl 2-{4-[N-methyl-N-(7-chloro-1,2,4-benzotriazin-3-yl)amino]phenoxy}propionate
  参考文献：
  名称：

  -Methyl as a bioisostere for the oxygen link between the aromatic rings of aryloxyphenoxypropionate herbicides

  摘要：

  The herbicidal activity of a set of (N) under bar,methyl arylaminophenoxypropionate esters 3 has been compared to the analogous aryloxyphenoxypropionates 1. The usefulness of (N) under bar-methyl as a novel bioisostere for ether links is shown by the surprisingly high herbicidal activity of the 6-chloroquinazolin-2-yl- and 7-chloro-1,2,4-benzotriazin-3-yl-N-methylamino-phenoxypropionate esters 3h and 3i. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0960-894x(97)00235-7

文献信息

• Herbicidal 1,2,4-benzotriazines
  申请人：ICI Australia Limited

  公开号：US04310347A1

  公开（公告）日：1982-01-12

  The invention concerns novel compounds of the formula I ##STR1## The compounds are herbicides and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal composition containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I.

  本发明涉及公式I的新化合物。该化合物是除草剂，进一步地，本发明提供了制备公式I化合物的过程，制备公式I化合物的中间体，含有公式I化合物作为活性成分的除草剂组合物，以及通过向植物或植物生长介质施加有效量的公式I化合物来严重损伤或杀死不需要的植物的方法。
• 1,2,4-Benzotriazinylaminophenoxyalkane carboxylic acid derivatives, processes for their preparation and their use as herbicides
  申请人：ICI AUSTRALIA LIMITED

  公开号：EP0024931A2

  公开（公告）日：1981-03-11

  The invention concerns novel compounds of the formula The compounds are herbicides and in further embodi- mentsthe invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal composition containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I.

  本发明涉及式如下的新型化合物 这些化合物是除草剂，在进一步的实施方案中，本发明提供了制备式 I 化合物的工艺、用于制备式 I 化合物的中间体、含有作为活性成分的式 I 化合物的除草组合物，以及通过向植物或植物的生长介质施用有效量的式 I 化合物来严重损害或杀死不需要的植物的工艺。
• SERBAN, A.;FARQUHARSON, G. J.;LYDIATE, J.;BIRD, G. J.
  作者：SERBAN, A.、FARQUHARSON, G. J.、LYDIATE, J.、BIRD, G. J.

  DOI：——

  日期：——
• US4310347A
  申请人：——

  公开号：US4310347A

  公开（公告）日：1982-01-12
• -Methyl as a bioisostere for the oxygen link between the aromatic rings of aryloxyphenoxypropionate herbicides
  作者：Graham J. Bird、Lindsay E. Cross、Graeme J. Farquharson、Wendy A. Jensen、Jack Lydiate、Alexander Serban、Richard B. Warner、Keith G. Watson、John E.D. Barton、Chris Coles、David J. Collins、John W. Slater

  DOI：10.1016/s0960-894x(97)00235-7

  日期：1997.6

  The herbicidal activity of a set of (N) under bar,methyl arylaminophenoxypropionate esters 3 has been compared to the analogous aryloxyphenoxypropionates 1. The usefulness of (N) under bar-methyl as a novel bioisostere for ether links is shown by the surprisingly high herbicidal activity of the 6-chloroquinazolin-2-yl- and 7-chloro-1,2,4-benzotriazin-3-yl-N-methylamino-phenoxypropionate esters 3h and 3i. (C) 1997 Elsevier Science Ltd.