Dimethyl-octyl-pentyl-ammonium; chloride | 151645-62-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Dimethyl-octyl-pentyl-ammonium; chloride
• 英文别名: N,N-Dimethyl-N-pentyloctan-1-aminium chloride；dimethyl-octyl-pentylazanium;chloride
• CAS: 151645-62-4
• 化学式: C₁₅H₃₄N*Cl
• 分子量: 263.895
• InChiKey: LXRGFWWCMYEYRG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.62
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-氯戊烷 、 N,N-二甲基正辛胺 以 乙醇 为溶剂， 反应 72.0h， 生成 Dimethyl-octyl-pentyl-ammonium; chloride
  参考文献：
  名称：

  Thermodynamics ofN,N,N-octylpentyldimethyl-ammonium chloride in water-urea mixtures

  摘要：

  Specific conductivities, densities, heat capacities, and enthalpies of dilution at 25 degrees C were measured for N,N,N-octylpentyldimethylammonium chloride (OPAC) in water-urea mixtures at various urea concentrations m(u) as functions of the surfactant concentration m,. From conductivity data, the cmc and the degree of the counterion dissociation beta of the OPAC micelles were calculated. The cmc increases linearly with increasing m(u) while beta vs. m(u) is a smooth concave curve. From the experimental thermodynamic data, the apparent (Y-phi) and partial (Y-2) molar properties (volumes, heat capacities, and relative enthalpies) are derived as functions of m(u) and m(2). The effect of urea on the dependences of the different properties on m(s) are discussed. From data in the premicellar region the standard partial molar volumes V-2(0) and heat capacities C-p2(0) were evaluated. It was observed that V-2(0) increases linearly with m(u) while C-p2(0) decreases. The properties of OPAC in the dispersed and micellized forms at the cmc were obtained and, therefore, the thermodynamic functions of micellization were calculated on the basis of the pseudo-phase transition model.

  DOI：

  10.1007/bf02768264

文献信息

• Thermodynamics ofN,N,N-octylpentyldimethyl-ammonium chloride in water-urea mixtures
  作者：R. De Lisi、B. Marongiu、S. Milioto、B. Pittau、S. Porcedda

  DOI：10.1007/bf02768264

  日期：1997.9

  Specific conductivities, densities, heat capacities, and enthalpies of dilution at 25 degrees C were measured for N,N,N-octylpentyldimethylammonium chloride (OPAC) in water-urea mixtures at various urea concentrations m(u) as functions of the surfactant concentration m,. From conductivity data, the cmc and the degree of the counterion dissociation beta of the OPAC micelles were calculated. The cmc increases linearly with increasing m(u) while beta vs. m(u) is a smooth concave curve. From the experimental thermodynamic data, the apparent (Y-phi) and partial (Y-2) molar properties (volumes, heat capacities, and relative enthalpies) are derived as functions of m(u) and m(2). The effect of urea on the dependences of the different properties on m(s) are discussed. From data in the premicellar region the standard partial molar volumes V-2(0) and heat capacities C-p2(0) were evaluated. It was observed that V-2(0) increases linearly with m(u) while C-p2(0) decreases. The properties of OPAC in the dispersed and micellized forms at the cmc were obtained and, therefore, the thermodynamic functions of micellization were calculated on the basis of the pseudo-phase transition model.