1,4-bis(4-hydroxyphenyl)cyclohexane | 10466-91-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis(4-hydroxyphenyl)cyclohexane
• 英文别名: 4,4-cyclohexylidene bisphenol；1,4-bis(p-hydroxyphenyl)cyclohexane；4,4'-(Cyclohexane-1,4-diyl)diphenol；4-[4-(4-hydroxyphenyl)cyclohexyl]phenol
• CAS: 10466-91-8
• 化学式: C₁₈H₂₀O₂
• 分子量: 268.356
• InChiKey: WZCQOMUGRAWORP-UHFFFAOYSA-N

物化性质

• 熔点：
  230-232 °C
• 沸点：
  463.6±45.0 °C(Predicted)
• 密度：
  1.158±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-bis(4-hydroxyphenyl)cyclohexane 以43%的产率得到
  参考文献：
  名称：

  YAMADA, MITSUO;KAYANO, XIROMITI;EHNDO, TAKEHSI;ISII, KEHJDZO;AOKI, XIDOSI

  摘要：

  DOI：
• 作为产物：
  描述：

  1,1,4,4-四(4-羟基苯基)环己烷 生成 1,4-bis(4-hydroxyphenyl)cyclohexane
  参考文献：
  名称：

  MIURA, TORU;NAGATA, TEHRUYUKI

  摘要：

  DOI：

文献信息

• POLYCARBONATE RESIN COMPOSITION AND FORMED PRODUCT THEREOF
  申请人：Monden Toshiki

  公开号：US20110245388A1

  公开（公告）日：2011-10-06

  In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

  在含有聚碳酸酯树脂和聚碳硅烷化合物的聚碳酸酯树脂组合物中，使用聚碳硅烷化合物可以改变聚碳酸酯树脂组合物的表面特性，而不会对聚碳酸酯树脂的固有特性产生不利影响，如透明度、耐热性和机械性能（例如冲击强度）。含有100质量部聚碳酸酯树脂、0.001至1质量部金属盐化合物和0.005至5质量部聚碳硅烷化合物的聚碳酸酯树脂组合物具有显著提高的阻燃性和高透明度，显著减少气体排放和模具污染，同时不会损失冲击强度和耐热性。
• METHOD OF PRODUCING POLY(ORTHO-METHYLPHENOL)
  申请人：AZUMA Rie

  公开号：US20070197832A1

  公开（公告）日：2007-08-23

  Poly(ortho-methylphenol) is obtainable at high purities and yields using industrial processes by causing a secondary amine and formaldehyde to react with a polyphenol (first step), and then breaking down the aminomethyl group of the obtained poly(ortho-aminomethyl)phenol by means of hydrogenolysis in the presence of a hydrogenation catalyst (second step).

  聚(正甲基苯酚)可通过工业过程获得高纯度和高收率，方法是首先使二级胺和甲醛与多酚反应（第一步），然后在氢化催化剂的存在下通过氢解分解所得的聚(正甲基氨甲基苯酚)的氨甲基基团（第二步）。
• Diphenol and process for producing the same
  申请人：——

  公开号：US20040049086A1

  公开（公告）日：2004-03-11

  The invention provides a diphenol represented by the general formula (I) 1 wherein X is a divalent cyclic hydrocarbon group selected from 1-cyclohexene-1,4-ylene group, 1,4-cyclohexylene group and p-phenylene group, R is an alkyl group of 1-4 carbon atoms, n is 0 or an integer of 1-3 when X is 1-cyclohexene-1,4-ylene group and an integer of 1-3 when X is 1,4-cyclohexylene group or p-phenylene group. The invention further provides a process for the production of the same.

  本发明提供了一种由通式（I）1表示的二苯酚，其中X是从1-环己烯-1,4-亚基基团、1,4-环己亚基基团和p-苯亚基基团中选择的二价环烃基团，R是1-4碳原子的烷基基团，当X是1-环己烯-1,4-亚基基团时，n为0或1-3的整数，当X是1,4-环己亚基基团或p-苯亚基基团时，n为1-3的整数。本发明还提供了一种其生产方法。
• Improved flame retardant polycarbonate compositions
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0127818A1

  公开（公告）日：1984-12-12

  Improved non-opaque flame retardant compositions comprised of, in admixture: (i) at least one aromatic polycarbonate resin derived from (a) at least one halogen-free and sulfurree dihydric phenol, (b) a minor amount of at least one halogen-free thiodiphenol, and (c) a carbonate precursor; and (ii) a minor amount of at least one organic alkali or alkaline earth metal salt of sulfonic acid.

  改良型不透明阻燃剂组合物，其混合物包括 (i) 至少一种芳香族聚碳酸酯树脂，由以下物质衍生而成：(a) 至少一种无卤素和无硫的二元苯酚，(b) 少量的至少一种无卤素的硫代二苯酚，和 (c) 一种碳酸盐前体；以及 (ii) 至少一种有机碱金属或碱土金属磺酸盐的少量。
• POLYESTER COMPOSITION AND MOLDINGS THEREOF
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0180648A1

  公开（公告）日：1986-05-14

  A polyester composition comprising (a) an aromatic polyester having a relative viscosity of 1.2 to 20, (b) an aromatic polycarbonate having a number-average molecular weight of 10,000 to 80,000, and (c) a glycidyl group- containing copolymer of 0.1 to 100 in melt index containing as major components an α-olefin and a glycidyl ester of an a, ε-unsaturated acid. This composition possesses excellent fluidity and residence stability upon molding, and excellent mechanical properties, particularly impact resistance, thus being useful as electric and electronic device parts and automobile parts. This composition can be molded into various moldings in a conventional manner.

  一种聚酯组合物，包括：(a) 相对粘度为 1.2 至 20 的芳香族聚酯；(b) 数均分子量为 10,000 至 80,000 的芳香族聚碳酸酯；(c) 熔体指数为 0.1 至 100 的含缩水甘油基的共聚物，其主要成分为 α-烯烃和 a，ε-不饱和酸的缩水甘油酯。 这种组合物在成型时具有优异的流动性和停留稳定性，以及优异的机械性能，尤其是抗冲击性，因此可用作电子电气设备零件和汽车零件。 这种组合物可以常规方式成型为各种模具。