{(C4H9)4N}{NiI3Triphenylphosphin} | 14320-07-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {(C4H9)4N}{NiI3Triphenylphosphin}
• CAS: 14320-07-1
• 化学式: C₁₆H₃₆N*C₁₈H₁₅I₃NiP
• 分子量: 944.163
• InChiKey: BNOVVDOGIFQRAN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  40.0
• 可旋转键数：
  16.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  {C18H15PC4H9}{NiJ3(Triphenylphosphin)} 在 methanol 作用下， 以 乙醚 、 正丁醇 为溶剂， 生成 {(C4H9)4N}{NiI3Triphenylphosphin}
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 8.18.1, page 1041 - 1052

  摘要：

  DOI：

文献信息

• A NEW TYPE OF TETRAHEDRAL COMPLEX OF NICKEL(II)
  作者：F. A. Cotton、D. M. L. Goodgame

  DOI：10.1021/ja01496a074

  日期：1960.6

  ABS>The preparation and properties are reported for two tetrahedral complex compounds of nickel(II), STA(C/sub 2/H/su)/sub 4/N! STA (C/sub 6/H/su)/ sub 3/PNiBr/sub 3/! and STA (n-C/sub 4/H/sub 9/)/sub 4/H! STA(C/sub 6/H/su)/sub 3/ PNiI/sub 3/!. The prop erties given are electric conductance of solutions in nitromethane, magnetic moments of the solids, and visible spectra of the solutions. (D.J.C.)

  ABS>报道了镍(II)、STA(C/sub 2/H/su)/sub 4/N的两种四面体络合物的制备和性能！STA (C/sub 6/H/su)/sub 3/PNiBr/sub 3/! 和 STA (nC/sub 4/H/sub 9/)/sub 4/H！STA(C/sub 6/H/su)/sub 3/ PNiI/sub 3/!。给出的特性是硝基甲烷溶液的电导率、固体的磁矩和溶液的可见光谱。(DJC)
• Preparation, Spectra and Electronic Structures of Tetrahedral Nickel(II) Complexes Containing Triphenylphosphine and Halide Ions as Ligands
  作者：F. A. Cotton、O. D. Faut、D. M. L. Goodgame

  DOI：10.1021/ja01463a021

  日期：1961.1
• Hydrogen-Bonding Interaction of Chloroform with Metal Complexes. Chloroform Nuclear Magnetic Resonance Contact Shifts
  作者：Michael F. Rettig、Russell S. Drago

  DOI：10.1021/ja00965a016

  日期：1966.7
• Isotropic Shifts of Some Ionic Complexes of Cobalt(II) and Nickel(II) : Evidence for Ion Pairing
  作者：Gerd N. La Mar

  DOI：10.1063/1.1725664

  日期：1964.11.15

  Isotropic proton resonance shifts have been observed for the ionic complexes, [Bu4N][φ3P)CoI3] and [Bu4N][φ3P)NiI3]. In addition to the phenyl (φ) proton shifts for the complex anions, isotropic shifts were observed for the cation protons as well. These shifts for the tetra-n-butylammonium cations are interpreted as arising solely from a pseudocontact interaction with the metal in the complex anion through partial ion pairing in the deuterochloroform solutions. From the magnitudes of the shifts for the butyl protons, an estimate is made for the relative extent of g-tensor anisotropies for the two anionic complexes. The observed shifts for the phenyl protons are interpreted as arising from both contact and pseudocontact interactions. Based on the postulate that the unpaired spin will distribute itself in a like manner in a given ligand whether attached to cobalt or nickel, and using the estimate of the relative anisotropies of the two metals, the phenyl proton shifts are separated into their respective contact and pseudocontact contributions. The resulting unpaired spin densities on the phenyl rings compare well with those reported for the related bis(triphenylphosphine) complexes.