1-perfluoro-n-octylnaphthalene-5-sulfonyl chloride | 138715-06-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-perfluoro-n-octylnaphthalene-5-sulfonyl chloride
• 英文别名: 5-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)naphthalene-1-sulfonyl chloride
• CAS: 138715-06-7
• 化学式: C₁₈H₆ClF₁₇O₂S
• 分子量: 644.736
• InChiKey: VNXPLFWWOFHPPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.23
• 重原子数：
  39.0
• 可旋转键数：
  8.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  34.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  1-perfluoro-n-octylnaphthalene-5-sulfonyl chloride 在 氢氧化钾 作用下， 以 水 为溶剂， 反应 24.0h， 生成 Potassium; 5-heptadecafluorooctyl-naphthalene-1-sulfonate
  参考文献：
  名称：

  Perfluoroalkylbenzenesulfonyl chlorides, perfluoroalkylnaphthalenesulfonyl chlorides, and their metal salts

  摘要：

  Meta-perfluoro-n-alkylbenzenesulfonyl chlorides and 1-perfluoro-n-alkylnaphthalene-5-sulfonyl chlorides were synthesized from the corresponding perfluoroalkylaromatics in good yield by the action of chlorosulfonic acid. From the acid chlorides, salts (RSO3M, where M = Li, K, Ba, Zn and Al) were prepared and their TGA curves obtained. With the exception of the aluminum salts, the materials were stable to at least 350-degrees-C. All the salts were essentially insoluble in Cl(CFClCF2)3-4Cl.

  DOI：

  10.1016/s0022-1139(00)80959-8
• 作为产物：
  描述：

  1-碘萘 在 铜 氯磺酸 作用下， 以 二甲基亚砜 为溶剂， 反应 16.0h， 生成 1-perfluoro-n-octylnaphthalene-5-sulfonyl chloride
  参考文献：
  名称：

  Perfluoroalkylbenzenesulfonyl chlorides, perfluoroalkylnaphthalenesulfonyl chlorides, and their metal salts

  摘要：

  Meta-perfluoro-n-alkylbenzenesulfonyl chlorides and 1-perfluoro-n-alkylnaphthalene-5-sulfonyl chlorides were synthesized from the corresponding perfluoroalkylaromatics in good yield by the action of chlorosulfonic acid. From the acid chlorides, salts (RSO3M, where M = Li, K, Ba, Zn and Al) were prepared and their TGA curves obtained. With the exception of the aluminum salts, the materials were stable to at least 350-degrees-C. All the salts were essentially insoluble in Cl(CFClCF2)3-4Cl.

  DOI：

  10.1016/s0022-1139(00)80959-8