二(3-甲基苯基氧基)巯基膦硫醚 | 7595-89-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二(3-甲基苯基氧基)巯基膦硫醚
• 英文名称: dithiophosphoric acid O,O'-di-m-tolyl ester
• 英文别名: Dithiophosphorsaeure-O,O'-di-m-tolylester；Dithiophosphorsaeure-O,O-bis-m-tolylester；O,O'-Di-m-cresyl dithiophosphate；bis(3-methylphenoxy)-sulfanyl-sulfanylidene-λ5-phosphane
• CAS: 7595-89-3
• 化学式: C₁₄H₁₅O₂PS₂
• 分子量: 310.378
• InChiKey: GKNITEVWPONLFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  51.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二(3-甲基苯基氧基)巯基膦硫醚 在 氨 作用下， 以 苯 为溶剂， 反应 0.5h， 生成
  参考文献：
  名称：

  Synthesis and spectroscopic characterization of toluene-3,4-dithiolatoarsenic(III)-O,O’-ditolyl/alkylene dithiophosphate compounds: crystal structure of [CH₃C₆H₃S₂As{S₂P(OC₆H₄Me-m)₂}]

  摘要：

  Toluene-3,4-dithiolate complexes, [CH3C6H3S2As{S2P(OR)(2)}] and [CH(3)C(6)H(3)S(2)AsS(2)POGO] (R = o-, m-, p-C6H4Me; G = -CH2C(CH3)(2)CH2-, -CHCH3CH2(CH3)(2)C-), have been synthesized by reaction of toluene-3,4-dithiolatoarsenic(III) chloride [C6H3(CH3)S2AsCl] with ammonium salts of the corresponding O,O'-ditolyl/alkylene dithiophosphate by refluxing in benzene followed by stirring. These complexes have been characterized by elemental analysis and IR, H-1, and P-31 NMR spectroscopy. Single-crystal X-ray diffraction analysis of [CH3C6H3S2As{S2P(OC6H4Me-m)(2)}] revealed distorted trigonal-bipyramidal geometry with an anisobidentate chelating mode of the ditolyl moiety in these complexes.

  DOI：

  10.1080/00958972.2014.899356
• 作为产物：
  描述：

  间甲酚 在 tetraphosphorus decasulfide 作用下， 生成 二(3-甲基苯基氧基)巯基膦硫醚
  参考文献：
  名称：

  Oktawiec, 1957, vol. 9, p. 320,322

  摘要：

  DOI：

文献信息

• Zemlyanskii,N.I.; Glushkova,L.V., Journal of general chemistry of the USSR, 1966, vol. 36, p. 2187 - 2188
  作者：Zemlyanskii,N.I.、Glushkova,L.V.

  DOI：——

  日期：——
• Fridland, S. V.; Shaikhiev, I. G.; Mukhutdinov, A. A., Journal of general chemistry of the USSR, 1991, vol. 61, # 3.1., p. 575 - 578
  作者：Fridland, S. V.、Shaikhiev, I. G.、Mukhutdinov, A. A.、Il'yasov, A. V.、Musin, R. Z.

  DOI：——

  日期：——
• Semljanskii; Gluschkowa, Zhurnal Obshchei Khimii, 1966, vol. 36, p. 2193; engl. Ausg. S. 2187
  作者：Semljanskii、Gluschkowa

  DOI：——

  日期：——
• AXMEDZADE D. A.; YASNOPOLSKIJ V. D.; DZHANIBEKOV N. F., EHSEHRLEHR KULIJJATY. AZEHRBSSR. ELMLEHR AKAD. NEFT-KIMJA PROSESLERI INST+
  作者：AXMEDZADE D. A.、 YASNOPOLSKIJ V. D.、 DZHANIBEKOV N. F.

  DOI：——

  日期：——
• Synthesis and spectroscopic characterization of toluene-3,4-dithiolatoarsenic(III)-<i>O</i>,<i>O</i>’-ditolyl/alkylene dithiophosphate compounds: crystal structure of [CH₃C₆H₃S₂As{S₂P(OC₆H₄Me-<i>m</i>)₂}]
  作者：Seema Maheshwari、Kavita Bundela、Krishan Gopal Ojha

  DOI：10.1080/00958972.2014.899356

  日期：2014.3.19

  Toluene-3,4-dithiolate complexes, [CH3C6H3S2AsS2P(OR)(2)}] and [CH(3)C(6)H(3)S(2)AsS(2)POGO] (R = o-, m-, p-C6H4Me; G = -CH2C(CH3)(2)CH2-, -CHCH3CH2(CH3)(2)C-), have been synthesized by reaction of toluene-3,4-dithiolatoarsenic(III) chloride [C6H3(CH3)S2AsCl] with ammonium salts of the corresponding O,O'-ditolyl/alkylene dithiophosphate by refluxing in benzene followed by stirring. These complexes have been characterized by elemental analysis and IR, H-1, and P-31 NMR spectroscopy. Single-crystal X-ray diffraction analysis of [CH3C6H3S2AsS2P(OC6H4Me-m)(2)}] revealed distorted trigonal-bipyramidal geometry with an anisobidentate chelating mode of the ditolyl moiety in these complexes.