1,2,2-tributyl-3,4,4-triphenyl-1-borata-4-phosphoniacyclobutene-2 | 115471-50-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,2-tributyl-3,4,4-triphenyl-1-borata-4-phosphoniacyclobutene-2
• 英文别名: 2,2,3-tributyl-1,1,4-triphenyl-1-phosphonia-2-boranuidacyclobut-3-ene
• CAS: 115471-50-6
• 化学式: C₃₂H₄₂BP
• 分子量: 468.47
• InChiKey: CRRDYEFGSXOXLC-UHFFFAOYSA-N

物化性质

• 熔点：
  66-68 °C

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,2,2-tributyl-3,4,4-triphenyl-1-borata-4-phosphoniacyclobutene-2 在 O₂ 作用下， 以 吡啶 为溶剂， 以21%的产率得到{2-butyl-2-(dibutylboryl)-1-phenylvinyl}diphenylphosphine oxide
  参考文献：
  名称：

  Ermolaeva, L. V.; Balueva, A. S.; Erastov, O. A., Journal of General Chemistry of the USSR, 1990, vol. 60, p. 659 - 663

  摘要：

  DOI：
• 作为产物：
  描述：

  2,3,3-tributyl-1,6,6-triphenyl-5-trichloromethyl-3,4,6-borataoxaphosphoniacyclohexene 生成 1,2,2-tributyl-3,4,4-triphenyl-1-borata-4-phosphoniacyclobutene-2
  参考文献：
  名称：

  BALUEVA, A. S.;ERASTOV, O. A., IZV. AN CCCP. CEP. XIM.,(1988) N 1, 163-165

  摘要：

  DOI：

文献信息

• Reaction of 1,2-borylphosphinoethene with thiocyanates. Molecular and crystal structure of 2,2,3-tributyl-4,5,5-triphenyl-6-methylthio-1,5,2-azaphosphoniaboratacyclohexa-3,6-diene
  作者：B. A. Arbuzov、G. N. Nikonov、A. S. Balueva、R. M. Kamalov、G. S. Stepanov、M. A. Pudovik、I. A. Litvinov、A. T. H. Lenstra、H. J. Geise

  DOI：10.1007/bf00864194

  日期：1992.7

  The reaction of 1,2-borylphosphinoethenes with alkylthiocyanates leads to formation of substances having the structure of 6-alkylthio-1,5,2-azaphosphoniaboratacyclohexa-3,6-dienes in the crystal state. The structure of the compounds has been proven by x-ray diffraction analysis of 2,2,3-tributyl-4,4,5-triphenyl-5-methylthio-1,5,2-azaphosphoniaboratacyclohexa-3,6-diene. The heterocyclic moiety of the molecule is planar within 0.010(2) angstrom. The methylthio group lies practically in the plane of the heterocycle.
• Synthesis of 3,4,6-borataoxaphosphoniacyclohexenes
  作者：A. S. Balueva、O. A. Erastov

  DOI：10.1007/bf00962677

  日期：1988.1
• Reaction of 1,2-borylphosphinoethene with phenyl isothiocyanate and carbodiimides
  作者：A. S. Valueva、G. N. Nikonov、R. M. Kamalov、N. A. Khailova、M. A. Pudovik

  DOI：10.1007/bf00961383

  日期：1991.5

  The reaction of 1-butyl-1-dibutylboryl-2-phenyl-2-diphenylphosphinoethene with phenyl isothiocyanate is a [4 + 2]-cycloaddition that involves the C = N segment of the heterocumulene; it gives 2,2,3-tributyl-6-thioxo-1,4,5,5-tetraphenyl-1-aza-5-phosphine-2-boratacyclohex-3-ene. Similarly products of the reaction of 1,2-borylphosphinoethene with diphenyl- and dicyclohexylcarbodiimides rearrange via the 1,2-B --> anionotropic C shift of the butyl fragment; the products are the respective 1,6,6-tributyl-3-imino-4,4,5-triphenyl-2-aza-4-phosphine-1-bora-tabicyclo[3.1.0]hexanes.
• BALUEVA, A. S.;EFREMOV, YU. YA.;NEXOROSHKOV, V. M.;ERASTOV, O. A., IZV. AN CCCP. CEP. XIM.,(1989) N2, S. 2793-2796
  作者：BALUEVA, A. S.、EFREMOV, YU. YA.、NEXOROSHKOV, V. M.、ERASTOV, O. A.

  DOI：——

  日期：——