methacrylic acid-(2-nitro-phenyl ester) | 59070-45-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: methacrylic acid-(2-nitro-phenyl ester)
• 英文别名: Methacrylsaeure-(2-nitro-phenylester)；Nitrophenylmetha-crylate；(2-nitrophenyl) 2-methylprop-2-enoate
• CAS: 59070-45-0
• 化学式: C₁₀H₉NO₄
• 分子量: 207.186
• InChiKey: OBSKPJKNWVTXJQ-UHFFFAOYSA-N

物化性质

• 沸点：
  169-171 °C(Press: 15 Torr)
• 密度：
  1.226 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  72.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  硝苯酚 、 甲基丙烯酰氯 在 sodium hydroxide 作用下， 生成 methacrylic acid-(2-nitro-phenyl ester)
  参考文献：
  名称：

  Preparation and Polymerization of Aryl Methacrylates and N-Arylmethacrylamides

  摘要：

  DOI：

  10.1021/ja01123a523

文献信息

• [EN] FORCE-RESPONSIVE POLYMERSOMES AND NANOREACTORS; PROCESSES UTILIZING THE SAME<br/>[FR] POLYMERSOMES ET NANORÉACTEURS SENSIBLES À LA FORCE; PROCÉDÉS LES UTILISANT
  申请人：ADOLPHE MERKLE INSTITUTE UNIV OF FRIBOURG

  公开号：WO2019034597A1

  公开（公告）日：2019-02-21

  The mechanically induced melting properties of DNA were employed to achieve force labile membranes is described. Nucleobase pairs were used as mechanophores. Adenine and thymine functionalized complementary amphiphilic block copolymers were self-assembled into polymersomes. The nucleobases formed hydrogen bonds which were disrupted upon force stimulation. The exposure of the disconnected nucleobases to the hydrophobic matrix of the membranes lead to a change of permeability which permitted the exchange of water-soluble molecules throughout the polymer matrix. Moreover, the encapsulation of horseradish peroxidase enabled the reaction of luminol with hydrogen peroxide to yield a luminescence producing species similar to the marine bioluminescence. Moreover, the same nano-reactors were employed to catalyze the formation of a polyacrylamide gel when force was applied. Insights into the change of permeability of supramolecular networks upon force are provided. These systems are useful for drug delivery, as nanoreactors and for the selective release of curing agents for 3D printing, or fragrances.

  DNA的机械诱导熔化特性被用来实现易受力破裂的膜。核碱基对被用作机械感受器。腺嘌呤和胸腺嘧啶功能化的互补两性分块共聚物自组装成聚合体囊。核碱基形成氢键，在受力刺激下被破坏。断开的核碱基暴露在膜的疏水基质中，导致渗透性的改变，从而允许水溶性分子在聚合物基质中交换。此外，封装辣根过氧化物酶使得辣根酰胺与过氧化氢反应产生类似海洋生物发光的发光物种。此外，当施加力时，相同的纳米反应器被用来催化聚丙烯酰胺凝胶的形成。提供了关于受力下超分子网络渗透性变化的见解。这些系统可用于药物传递、纳米反应器以及用于3D打印的固化剂或香料的选择性释放。
• Hydrophilic copolymer compositions useful as contact lenses
  申请人：DIAMOND SHAMROCK CORPORATION

  公开号：EP0101300A2

  公开（公告）日：1984-02-22

  Novel hydrophilic copolymers are prepared containing a major portion of polymerized units of an hydroxyalkyl acrylate or methacrylate monomer and a minor portion of a nitro-substituted aryl acrylate or methacrylate monomer, and optionally with a minor amount of an alkylene glycol diacrylate or methacrylate as a cross-linking agent. These copolymers are made by a free radical polymerization mechanism or by gamma radiation of the reaction mixture. These copolymers are particularly useful as soft contact lens polymers, being extremely resistant to clouding and/or discoloration in use.

  新型亲水共聚物的制备过程中，主要成分是丙烯酸羟烷基酯或甲基丙烯酸酯单体的聚合单元，次要成分是硝基取代的丙烯酸芳基酯或甲基丙烯酸酯单体，还可选择加入少量烷二醇二丙烯酸酯或甲基丙烯酸酯作为交联剂。这些共聚物是通过自由基聚合机制或反应混合物的伽马射线辐射制成的。这些共聚物特别适合用作软性隐形眼镜聚合物，在使用中具有极强的抗混浊和/或变色能力。
• Pigment dispersions containing aqueous branched polymer dispersant
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1293523A2

  公开（公告）日：2003-03-19

  A water-based dispersion useful for forming aqueous coating composition containing dispersed pigment, an aqueous carrier and a branched polymer dispersant (binder); the branched polymer has a weight average molecular weight of about 5,000 - 100,000 and contains 20-80% by weight of a hydrophilic backbone and correspondingly 80-20% by weight of macromonomer side chains; wherein the backbone is of polymerized ethylenically unsaturated monomers and 2-30% by weight, based on the weight of the backbone of polymerized ethylenically unsaturated monomers having an acid-functional group; and wherein at least 10% of the acid-functional groups are neutralized with an amine or an inorganic base and is hydrophilic in comparison to the side chains; the side chains are of macromonomers of polymerized ethylenically unsaturated monomers that are polymerized into the backbone via an ethylencially unsaturated group and the macromonomers have a weight average molecular weight of about 1,000 - 30,000 and wherein the weight ratio of pigment to binder is about 1/100 - 200/100.

  一种用于形成水性涂料组合物的水基分散体，含有分散颜料、水性载体和支链聚合物分散剂（粘结剂）；支链聚合物的重量平均分子量约为 5,000 - 100,000，含有 20-80% （重量）的亲水主链和相应的 80-20% （重量）的大单体侧链；其中骨架为聚合乙烯基不饱和单体，且以骨架重量计，2-30%为具有酸官能团的聚合乙烯基不饱和单体；其中至少 10%的酸官能团用胺或无机碱中和，与侧链相比具有亲水性；侧链是聚合乙烯基不饱和单体的大单体，通过乙烯基不饱和基团聚合到主链中，大单体的重量平均分子量约为 1,000 - 30,000，颜料与粘合剂的重量比约为 1/100 - 200/100。
• Titanium dioxide slurries for ink applications
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1609825A1

  公开（公告）日：2005-12-28

  A titanium dioxide slurry comprises (a) a titanium dioxide pigment; (b) a combination of dispersants comprising: (1) a graft copolymer having a weight average molecular weight of about 4,000 to 100,000, comprising about 90 to 50% by weight of a polymeric backbone and correspondingly about 10 to 50% by weight of macromonomer side chains attached to the backbone, the polymeric backbone and macromonomer side chains comprising 100 wt% of the graft copolymer, wherein (i) the polymeric backbone is hydrophobic in comparison to the macromonomer side chains and comprises one or more polymerized ethylenically unsaturated hydrophobic monomers and, optionally, up to about 20% by weight, based on the weight of the graft copolymer, of polymerized ethylenically unsaturated acid monomers; and (ii) each of the macromonomer side chains individually is a hydrophilic polymer containing acid groups attached to the polymeric backbone at a single terminal point and (A) has a weight average molecular weight of about 1,000 to 30,000, and (B) comprises from about 2% to about 100% by weight, based on the weight of the macromonomer side chain, of a polymerized ethylenically unsaturated acid monomer and (C) wherein the acid groups are at least partially neutralized with an inorganic base and/or an amine; (2) a block copolymer of type AB, ABA, or ABC wherein at least one of the blocks in the block copolymer is an adsorbing segment and wherein at least one of the blocks in the block copolymer is a stabilizing segment; and (c) a liquid carrier.

  二氧化钛浆料包括 (a) 二氧化钛颜料；(b) 分散剂组合，包括(1) 接枝共聚物，其重量平均分子量约为 4,000 至 100,000，包括约 90 至 50%（按重量计）的聚合物主链和相应地约 10 至 50%（按重量计）连接到主链上的大单体侧链，聚合物主链和大单体侧链占接枝共聚物的 100 wt%、其中(i) 聚合物主链与大单体侧链相比是疏水性的，并包括一种或多种聚合乙烯基不饱和疏水单体，以及可选地，基于接枝共聚物重量，最多约20%（重量）的聚合乙烯基不饱和酸单体；(ii) 每条大单体侧链都是亲水性聚合物，含有在单个末端点连接到聚合物骨架的酸基，并且 (A) 具有约 1,000 至 30,000 的重量平均分子量，以及 (B) 基于大单体侧链的重量，包含约 2%至约 100%（按重量计）的聚合乙烯基不饱和酸单体，以及 (C) 其中酸基至少部分被无机碱和/或胺中和；(2) AB、ABA 或 ABC 型嵌段共聚物，其中嵌段共聚物中至少有一个嵌段是吸附段，嵌 段共聚物中至少有一个嵌段是稳定段；以及 (c) 液体载体。
• Structure, method for producing structure, composition for forming absorption layer, solid-state imaging element, and image display device
  申请人：FUJIFILM Corporation

  公开号：US11152413B2

  公开（公告）日：2021-10-19

  A structure has a color filter having two or more different types of pixels and an absorption layer including at least one selected from a yellow colorant or a colorant having a maximum absorption wavelength in a wavelength range of 400 to 500 nm, in which the structure has the absorption layer on an optical path of at least one pixel of the pixels of the color filter and on the side through which light is incident on the pixel.

  一种结构具有一个彩色滤光片，该彩色滤光片具有两种或两种以上不同类型的像素和一个吸收层，该吸收层包括从黄色着色剂或最大吸收波长在 400 至 500 纳米范围内的着色剂中选出的至少一种着色剂，其中该结构的吸收层位于彩色滤光片像素中至少一个像素的光路上，并且位于光线入射到像素的一侧。