N-(3-bromophenyl)-N-phenylnaphthalen-1-amine | 1224893-33-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(3-bromophenyl)-N-phenylnaphthalen-1-amine
• CAS: 1224893-33-7
• 化学式: C₂₂H₁₆BrN
• 分子量: 374.28
• InChiKey: RZPIJOXIECJHAV-UHFFFAOYSA-N

物化性质

• 沸点：
  502.8±33.0 °C(Predicted)
• 密度：
  1.381±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(3-bromophenyl)-N-phenylnaphthalen-1-amine 在 碘 、 sodium carbonate 作用下， 以 氯仿 、 甲苯 为溶剂， 反应 36.0h， 生成
  参考文献：
  名称：

  CN114773370

  摘要：

  公开号：
• 作为产物：
  描述：

  1-溴-3-碘苯 、 N-苯基-1-萘胺 在 palladium diacetate 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以97%的产率得到N-(3-bromophenyl)-N-phenylnaphthalen-1-amine
  参考文献：
  名称：

  Chemoselective amination of bromoiodobenzenes with diarylamines by palladium/Xantphos or ligand-free copper catalysts

  摘要：

  We report the chemoselective amination of bromoiodobenzenes with diarylamines by palladium/Xantphos or a ligand-free copper catalyst. The reactions by these two types of catalysts proceeded with a high chemoselectivity and afforded monobrominated triarylamines in good yields. These products are useful intermediates for the synthesis of unsymmetrical bistriarylamines. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.01.028

文献信息

• COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT COMPRISING THE SAME, AND ELECTRONIC DEVICE THEREOF
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US20170288148A1

  公开（公告）日：2017-10-05

  Provided are a compound of Formula 1 and an organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode, and electronic device comprising the organic electric element, wherein the driving voltage of the organic electronic device can be lowered, and the luminous efficiency and life span can be improved by comprising the compound represented by Formula 1 in the organic material layer.

  提供的是一种由化合物Formula 1和有机电元素组成的复合物，包括第一电极、第二电极和形成在第一电极和第二电极之间的有机材料层，以及包括该有机电元素的电子器件，其中通过在有机材料层中包含Formula 1代表的化合物，可以降低有机电子器件的驱动电压，并提高发光效率和使用寿命。
• ORGANIC COMPOUND AND ORGANIC LIGHT EMITTING DIODE USING THE SAME
  申请人：LG Display Co., Ltd.

  公开号：US20150162537A1

  公开（公告）日：2015-06-11

  Discussed is an organic electroluminescent device including a first charge carrying layer being disposed adjacent to a first electrode; and a second charge carrying layer disposed adjacent to a second electrode, wherein the first charge carrying layer includes an emitting part, a hole injection part and a hole transporting part between the hole injection part and the emitting part, wherein at least one of the hole injection part, the hole transporting part and the emitting part includes a host material having an organic compound of Formula: wherein R is substituted or non-substituted C1 to C12 alkyl, and A and B are symmetrically or asymmetrically positioned in 2-position or 7-position of the fluorene core, and wherein each of A and B is independently selected from substituted or non-substituted aromatic group or substituted or non-substituted heterocyclic group.

  讨论的是一种有机电致发光装置，包括第一电极旁边放置的第一载荷层；以及放置在第二电极旁边的第二载荷层，其中第一载荷层包括一个发光部分，一个空穴注入部分和一个空穴传输部分，该空穴传输部分位于空穴注入部分和发光部分之间，在空穴注入部分、空穴传输部分和发光部分中的至少一个包含有机化合物的主体材料，该有机化合物的化学式为：其中R是取代或未取代的C1到C12烷基，A和B在芴核心的2-位置或7-位置对称或不对称地定位，并且A和B各自独立地选择取代或未取代的芳香基或取代或未取代的杂环基。
• Organic compound and organic light emitting diode using the same
  申请人：LG Display Co., Ltd.

  公开号：EP2881446A2

  公开（公告）日：2015-06-10

  Discussed is an organic compound of Formula: wherein R is substituted or non-substituted C1 to C12 alkyl, and A and B are symmetrically or asymmetrically positioned in 2-position or 7-position of the fluorene core, and wherein each of A and B is independently selected from substituted or non-substituted aromatic group or substituted or non-substituted heterocyclic group.

  所讨论的是一种有机化合物，其化学式为 其中 R 是取代或非取代的 C1 至 C12 烷基，A 和 B 对称或不对称地位于芴核的 2 位或 7 位，且 A 和 B 各自独立地选自取代或非取代的芳香基团或取代或非取代的杂环基团。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：LG Display Co., Ltd.

  公开号：EP3489325A1

  公开（公告）日：2019-05-29

  Discussed is an organic electroluminescent device, comprising: a first electrode; a second electrode facing the first electrode; an emitting material layer between the first and second electrodes; a hole injection layer between the first electrode and the emitting material layer; and a hole transporting layer between the hole injection layer and the emitting material layer, wherein at least one of the hole injection layer, the hole transporting layer and the emitting material layer includes an organic compound of Formula: and wherein X is selected from carbon, nitrogen, oxygen and sulfur, and Y is selected from aryl and arylamine.

  本文讨论的是一种有机电致发光器件，包括：第一电极；面向第一电极的第二电极；位于第一电极和第二电极之间的发光材料层；位于第一电极和发光材料层之间的空穴注入层；以及位于空穴注入层和发光材料层之间的空穴传输层，其中空穴注入层、空穴传输层和发光材料层中的至少一个包括式中的有机化合物： 和 其中 X 选自碳、氮、氧和硫，Y 选自芳基和芳基胺。
• Synthesis and Characterization of a New Series of Blue Fluorescent 2,6-Linked 9,10-Diphenylanthrylenephenylene Copolymers and Their Application for Polymer Light-Emitting Diodes
  作者：Hung-Yang Chen、Chin-Ti Chen、Chao-Tsen Chen

  DOI：10.1021/ma100195m

  日期：2010.4.27

  A series of new 9,10-diphenylanthracene-based, 2,6-linked blue-light-emitting copolymers bearing hole- or electron-transporter as well as bulky substituent were successfully synthesized. Photo-physical, thermal, electrochemical, and electroluminescence (EL) properties of these copolymers were studied and characterized. Bright and efficient blue fluorescence in the solid state was achieved by incorporating bulky substituent into the copolymer backbone. Both hole- and electron-transport-substituted copolymers apparently enhanced the electroluminescent performance of their polymeric light-emitting diodes (PLEDs). A diphenylvinyl-bearing copolymer (pDPV) PLED exhibited sky-blue EL (lambda(EL)(max) = 473 nm, CIEx,y = 0.16, 0.28) with peak luminous efficiency of 2.21 cd/A; a N-carbazole bearing copolymer (pCBZ) PLED displayed a blue EL (lambda(EL)(max) = 469 nm, CIEx,y = 0.15, 0.22) with peak luminous efficiency of 2.15 cd/A. OXD-7 (1,3-bis(2-(4-tert-butylphenyl)-1,3,4-oxadiazol-5-yl)benzene) as an electron-transporting dopant was found to improve the performance of PLED significantly. A better balanced hole/electron charge carrier was ascribed to electron-transporting, 1,3,4-oxadiazole-bearing copolymer (pOXD) PLED. It showed a very mild efficiency rolls off: only 0.13 cd/A luminous efficiency drops from current densities of 10-100 mA/cm(2), corresponding to EL brightness of 169-1558 cd/m(2).