3-nitrobenzenediazonium | 16278-29-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-nitrobenzenediazonium
• 英文别名: 3-Nitro-benzoldiazonium；m-Nitrobenzoldiazonium；3-Nitro-benzoldiazonium-ion；m-Nitrophenyldiazonium；3-Nitro-phenyldiazonium；3-Nitro-benzoldiazonium-(1)；m-Nitro-benzoldiazonium-ion
• CAS: 16278-29-8
• 化学式: C₆H₄N₃O₂
• 分子量: 150.117
• InChiKey: PTZGBPAXEKEBSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2927000090

反应信息

• 作为反应物：
  描述：

  3-nitrobenzenediazonium 生成 4-[(3-硝基苯基)偶氮]苯胺
  参考文献：
  名称：

  v.Mechel; Stauffer, Helvetica Chimica Acta, 1941, vol. 24, p. 151 E,152 E,153 E

  摘要：

  DOI：
• 作为产物：
  描述：

  E 3-nitrobenzenediazotate anion 生成 3-nitrobenzenediazonium
  参考文献：
  名称：

  Luchkevich, E. R.; Mileiko, V. E.; Bagal, I. L., Journal of general chemistry of the USSR, 1986, vol. 56, p. 1397 - 1411

  摘要：

  DOI：

文献信息

• Oxidative cyclisation of diphenyl-2 carboxylic acid
  作者：G.W. Kenner、M.A. Murray、C.M.B. Tylor

  DOI：10.1016/0040-4020(57)88048-x

  日期：1957.1

  carboxylic acid to the lactone (II; R = H) has been accomplished by oxidation with chromic acid or hydrogen peroxide and its derivatives, by decomposition of the diacyl peroxide derived from this acid, and by electrolysis of its sodium salts. From the effects of several 3′-substituents (R = OMe, NHCOCH3, CH, NO2) on these reactions it has been concluded that the oxidations with chromic acid and hydrogen

  通过用铬酸或过氧化氢及其衍生物氧化，分解由该酸衍生的二酰基过氧化物并对其钠进行电解，可以完成二苯基-2羧酸脱氢成内酯（II； R = H）的反应。盐。从几种3'取代基（R = OMe，NHCOCH 3，CH，NO 2）对这些反应的影响，可以得出结论，铬酸和过氧化氢等的氧化是通过氧化剂与羧酸的连接而进行的。基团和相邻环中随后的阳离子类化合物取代。自由基（III）被认为是另外两个环化中的中间体。
• Coupling Kinetics of 4-Sulfobenzenediazonium Ion with 2,4-Thiazolidinedione, Its 3-Methyl Derivative and 3-Methyl-5-isoxazolone
  作者：Jaromír Kaválek、Vladimír Macháček、Vojeslav Štěrba

  DOI：10.1135/cccc19942022

  日期：——

  3- and 4-substituted 5-phenylazo derivatives of 2,4-thiazolidinedione were prepared as potential biologically active fungicides. The kinetics of coupling of 4-sulfobenzenediazonium salt with 2,4-thiazolidinedione and 3-methyl-2,4-thiazolidinedione have been studied and the results have been compared with kinetic data of coupling reaction of 3-methyl-5-isoxazolone.

  2,4-噻唑烷二酮的3-和4-取代的5-苯基偶氮衍生物被制备为潜在的生物活性杀真菌剂。已研究了4-磺基苯二氮盐与2,4-噻唑烷二酮和3-甲基-2,4-噻唑烷二酮的偶联动力学，并将结果与3-甲基-5-异噁唑酮的偶联反应动力学数据进行了比较。
• Studies on the Electrochemical Behavior of Thiadiazole Derivatives. Electroreduction of 2-Benzoylamino-5-[cyanoarylhydrazonomethyl]-1,3,4-thiadiazoles
  作者：H. M. Fahmy、M. Abdel Azzem、M. Abdul Wahab、N. Abdel Fattah、M. A. Aboutabl

  DOI：10.1246/bcsj.62.2650

  日期：1989.8

  The electrochemical behavior of some 1,3,4-thiadiazole derivatives substituted at C5 (carbon number five in thiadiazole ring) with a hydrazono group has been studied at a dropping mercury electrode (DME) in different pH values. Controlled potential electrolysis (CPE) in alkaline medium, cyclic voltammetry (CV), ultraviolet spectra (UV) and pKa studies confirmed the proposed mechanism.

  一些 1,3,4-噻二唑衍生物在 C5（噻二唑环中的碳数 5）处被腙基团取代，在不同 pH 值的滴汞电极 (DME) 上进行了电化学行为研究。碱性介质中的受控电位电解 (CPE)、循环伏安法 (CV)、紫外光谱 (UV) 和 pKa 研究证实了所提出的机制。
• Microstructures and Mechanical Behavior of Bulk Nanocrystalline γ–Ni–Fe Produced by a Mechanochemical Method
  作者：X. Y. Qin、J. S. Lee、C. S. Lee

  DOI：10.1557/jmr.2002.0147

  日期：2002.5

  The microstructures and mechanical behavior of bulk nanocrystalline γ–Ni–xFe (n-Ni–Fe) with x = ∼19–21 wt%, synthesized by a mechanochemical method plus hot-isostatic pressing, were investigated using microstructural analysis [x-ray diffraction, energy-dispersive spectroscopy, light emission spectrum, atomic force microscopy (AFM), and optical microscopy (OM)], and mechanical (indentation and compression) tests, respectively. The results indicated that the yield strength (σ_0.2) of n-Ni–Fe (d ∼ 33 nm) is about 13 times greater than that of conventional counterpart. The change of yield strength with grain size was basically in agreement with Hall–Petch relation in the size range (33–100 nm) investigated. OM observations demonstrated the existence of two sets of macroscopic bandlike deformation traces mostly orienting at 45–55° to the compression axis, while AFM observations revealed that these bandlike traces consist of ultrafine lines. The cause for high strength and the possible deformation mechanisms were discussed based on the characteristics of microstructures and deformation morphology of n-Ni–Fe.

  分别采用微结构分析[X 射线衍射、能量色散光谱、光发射光谱、原子力显微镜 (AFM) 和光学显微镜 (OM)]和力学（压痕和压缩）测试，研究了用机械化学方法加热等静压合成的 x = ∼ 19-21 wt% 的块状纳米晶 γ-Ni-x-Fe（n-Ni-Fe）的微结构和力学行为。结果表明，n-Ni-Fe（d ∼ 33 nm）的屈服强度（σ0.2）约为传统材料的 13 倍。在所研究的晶粒尺寸范围（33-100 nm）内，屈服强度随晶粒尺寸的变化与霍尔-佩奇关系基本一致。光学显微镜观察表明存在两组宏观带状变形痕迹，其方向大多与压缩轴成 45-55° 角，而原子力显微镜观察则发现这些带状痕迹由超细线组成。根据 n-Ni-Fe 的微观结构和变形形态特征，讨论了高强度的原因和可能的变形机制。
• Empowering strategies of electrochemical N–N bond forming reactions: direct access to previously neglected 1,2,3-triazole 1-oxides
  作者：Kseniia Titenkova、Alexander D. Shuvaev、Fedor E. Teslenko、Egor S. Zhilin、Leonid L. Fershtat

  DOI：10.1039/d3gc01601c

  日期：——

  heterocycles, 1,2,3-triazole 1-oxides, were prepared through a sustainable transition-metal- and exogenous oxidant-free strategy with broad generality. Based on the obtained cyclic voltammograms and DFT calculations, a plausible mechanism for the oxidation of oximinohydrazones was proposed. According to differential scanning calorimetry (DSC) data, the prepared 1,2,3-triazole 1-oxides may be classified as

  电化学合成已成为新兴的强大工具之一，为复杂有机分子的组装创造新颖的最先进的策略。然而，由于氮的电负性相对较高以及与 N-H 键氧化相关的各种副反应，电化学诱导的 N-N 键形成反应仍然具有挑战性。在此，我们提出了一种新颖的绿色电化学方法，通过容易获得的肟基腙的氧化。因此，以前被忽视的氮杂环，1,2,3-三唑1-氧化物，是通过可持续的无过渡金属和外源氧化剂的策略制备的，具有广泛的通用性。基于获得的循环伏安图和DFT计算，提出了肟基腙氧化的合理机制。根据差示扫描量热法（DSC）数据，所制备的1,2,3-三唑1-氧化物可归类为热稳定物质（T d：151–242 °C），这对于功能有机材料的进一步开发具有很高的价值。此外，1,2,3-三唑 1-氧化物被发现在生理条件下表现出良好的 NO 释放特性，为以环境友好的方式创造新的药物成分提供了广阔的机会。