Bisphenol A Ether | 158178-49-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bisphenol A Ether
• 英文别名: 4-[2-[4-[4-[2-(4-Hydroxyphenyl)propan-2-yl]phenoxy]phenyl]propan-2-yl]phenol
• CAS: 158178-49-5
• 化学式: C₃₀H₃₀O₃
• 分子量: 438.566
• InChiKey: NAZDDYIGXZNZLB-UHFFFAOYSA-N

物化性质

• 沸点：
  599.9±45.0 °C(Predicted)
• 密度：
  1.143±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  环氧乙烷 、 双酚A 、 methyloxirane 在 三氟化硼 作用下， 生成 Bisphenol A Ether
  参考文献：
  名称：

  Compositions containing esters of aromatic alkoxylated alcohols and fatty carboxylic acids

  摘要：

  提供一种个人护理或化妆品组合物，包括约0.1%至约99%的至少一种烷氧基芳香醇和脂肪羧酸酯，以及约0.1%至60%的至少一种功能性成分。组合物中的功能性成分可能包括活性成分和额外成分。特别适用的活性成分包括防晒活性成分和止汗活性成分。首选的组合物是防晒产品配方和止汗产品。在一个首选实施例中，该组合物还包括至少一种环硅烷化合物，其占组合物重量的约1%至99%。还提供了一种改善人类或动物皮肤或毛发免受辐射的保护的方法，以及一种改善人类或动物皮肤或毛发免受汗水侵害的方法。

  公开号：

  US20030161792A1

文献信息

• Cellulose Compound Film, Optical Compensation Sheet, Polarizing Plate, and Liquid Crystal Display Device
  申请人：Nozoe Yutaka

  公开号：US20070259134A1

  公开（公告）日：2007-11-08

  A cellulose compound film containing a cellulose compound having two or more substituents whose polarizability anisotropies Δα calculated by mathematical formula (1) are different from each other, wherein substitution degrees of the following substituents A and B in the cellulose compound satisfy relationship as defined by mathematical formula (A1), in which the substituent A has the lowest Δα and the substituent B has the highest Δα: Δ ⁢ ⁢ α = α ⁢ ⁢ x - α ⁢ ⁢ y + α ⁢ ⁢ z 2 Mathematical ⁢ ⁢ formula ⁢ ⁢ ( 1 ) wherein, in characteristic values obtained after diagonalization of polarizability tensor, αx is the largest component, αy is the second largest component, and αz is the smallest component; DS B 2+ DS B 3− DS B 6≧−0.1   Mathematical formula (A1) wherein DS B 2, DS B 3, and DS B 6 represent a substitution degree of the substituent B at the 2-, 3-, or 6-position of a β-glucose ring constituting unit of cellulose, respectively; and an optical compensation film, a polarizing plate, and a liquid crystal display device, using the cellulose compound film.

  一种纤维素化合物薄膜，其含有具有两个或更多取代基的纤维素化合物，其极化率各向异性Δα通过数学公式（1）计算得出，其中以下取代基A和B的取代度满足数学公式（A1）所定义的关系，其中取代基A具有最低的Δα，而取代基B具有最高的Δα：Δα = αx-αy + αz2数学公式（1）其中，在极化率张量对角化后获得的特征值中，αx是最大分量，αy是第二大分量，αz是最小分量;DSB2 + DSB3-DSB6≥-0.1数学公式（A1）其中DSB2、DSB3和DSB6分别表示取代基B在纤维素构成单位β-葡萄糖环的2-、3-或6-位置的取代度;以及使用该纤维素化合物薄膜的光学补偿膜、偏光板和液晶显示装置。
• Cellulose Acylate Film, Method of Producing the Same, Cellulose Derivative Film, Optically Compensatory Film Using the Same, Optically-Compensatory Film Incorporating Polarizing Plate, Polarizing Plate and Liquid Crystal Display Device
  申请人：Haruta Hiromoto

  公开号：US20090290100A1

  公开（公告）日：2009-11-26

  A method of producing a cellulose derivative film, the method comprising: forming a film with a solvent cast method from a dope including a cellulose derivative satisfying following conditions (a) and (b): (a) at least one among three hydroxyl groups included in a glucose unit of cellulose is substituted by a substituent of which a polarizability anisotropy Δα represented as following Expression (1) is 2.5×10 −24 cm 3 or higher: Expression (1): Δα=αx−(αy+αz)/2, wherein αx, αy and αz is as defined in the specification; and (b) when a substitution degree by a substituent of which Δα is 2.5×10 −24 cm 3 or higher is P A , and a substitution degree by a substituent of which Δα is lower than 2.5×10 −24 cm 3 is P B , the P A and P B satisfy following Expressions (3) and (4): Expression (3): 2P A +P B >3.0; and Expression (4): P A >0.2.

  一种生产纤维素衍生物薄膜的方法，该方法包括：使用包括满足以下条件（a）和（b）的纤维素衍生物的溶胶，通过溶剂浇铸法形成薄膜：（a）纤维素的葡萄糖单元中的三个羟基中的至少一个被取代为极化率各向异性Δα（以下表达式（1）表示）为2.5×10-24cm3或更高的取代基：表达式（1）：Δα=αx-（αy+αz）/ 2，其中αx，αy和αz如规范中定义的；并且（b）当Δα为2.5×10-24cm3或更高的取代基的取代度为PA时，Δα低于2.5×10-24cm3的取代基的取代度为PB，PA和PB满足以下表达式（3）和（4）：表达式（3）：2PA + PB> 3.0；表达式（4）：PA> 0.2。
• Processes for preparing hydroxyaromatic oligomers containing triazine groups and for preparing epoxy resins from the oligomers
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0143988A2

  公开（公告）日：1985-06-12

  This invention pertains to a process for preparing hydroxyaromatic oligomers containing triazine groups. The process is characterized by (1) reacting (A) a material having an average of more than one aromatic hydroxyl group per molecule such as bisphenol A with (B) a cyanogen halide such as cyanogen bromide in the presence of (C) a base and recovering a mixture of cyanate-containing products and unreacted (A) materials; (II) trimerizing the product recovered in (1) in the presence of a trimerization catalyst such as cobalt naphthenate. This invention also pertains to a process for epoxidizing the product from step II by reaction with an epihalohydrin such as epichlorohydrin, dehydrohalogenation of the resultant product with a basic-acting material such as sodium hydroxide and recovering the resultant epoxy resin containing triazine groups.

  本发明涉及一种制备含有三嗪基团的羟基芳香族低聚物的工艺。该工艺的特点是：(1)在(C)碱存在下，使(A)每分子平均具有一个以上芳香羟基（如双酚 A）的材料与(B)卤化氰（如溴化氰）反应，并回收含氰酸酯的产物和未反应的(A)材料的混合物；(2)在三聚催化剂（如环烷酸钴）存在下，对(1)中回收的产物进行三聚。本发明还涉及一种工艺，通过与环氧氯丙烷等表卤代醇反应，将步骤 II 中的产物环氧化，用氢氧化钠等碱性作用物质对所得产物进行脱氢卤化，并回收所得含三嗪基团的环氧树脂。
• A process for preparing vinyl ester resins containing triazine or both triazine and oxazoline groups
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0156959A1

  公开（公告）日：1985-10-09

  This invention pertains to a process for preparing vinyl ester resins containing triazine groups or both triazine and oxazoline groups prepared by reacting a polyepoxide with 0.75 to 1, preferably from 0.9 to 1, moles of a monounsaturated monocarboxylic acid or mixture of monounsaturated monocarboxylic acids per epoxide group in the presence of a suitable quantity of a suitable catalyst. The process is characterized in that the polyepoxide is (a) a polyepoxide containing triazine groups, or (b) a polyepoxide containing both triazine and oxazoline groups, or (c) a mixture of (a) and (b).

  本发明涉及一种制备含有三嗪基团或同时含有三嗪和噁唑啉基团的乙烯基酯树脂的工艺，其制备方法是在适量的合适催化剂存在下，将聚环氧化物与每环氧基团0.75至1摩尔，最好是0.9至1摩尔的单不饱和单羧酸或单不饱和单羧酸混合物反应。该工艺的特征在于，聚环氧化物是(a)含有三嗪基团的聚环氧化物，或(b)含有三嗪和噁唑啉基团的聚环氧化物，或(c)(a)和(b)的混合物。
• Process for preparing hydroxyaromatic oligomers containing both triazine and oxazoline groups and for preparing epoxy resins from the oligomers
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0150278A2

  公开（公告）日：1985-08-07

  This invention pertains to a process for preparing hydroxyaromatic oligomers containing triazine groups and oxazoline groups. The process is characterized by (I) reacting (A) a material having an average of more than one aromatic hydroxyl group per molecule with (B) a cyanogen halide such as cyanogen bromide in the presence of a base and recovering a mixture of cyanate-containing products and unreacted (A) materials, (II) co-oligomerizing the product resulting from (I) with an epoxy resin in the presence of a suitable co-oligomerization catalyst. This invention also pertains to a process for preparing epoxy resins containing both triazine groups and oxazoline groups by epoxidizing a hydroxyaromatic material in a conventional manner by reaction with an epihalohydrin with subsequent dehydrohalogenation with a basic-acting material and finally recovering the resultant glycidyl ether product, characterized in that the hydroxyaromatic material is the resultant co-oligomerization product from step (II) of the earlier process.

  本发明涉及一种制备含有三嗪基团和噁唑啉基团的羟基芳香族低聚物的工艺。该工艺的特点是：(I) 在碱存在下，使(A)平均每个分子具有一个以上芳香羟基的材料与(B)卤化氰，如溴化氰反应，并回收含氰酸酯产物和未反应的(A)材料的混合物；(II) 在适当的共聚合催化剂存在下，使(I)产生的产物与环氧树脂共聚合。本发明还涉及一种制备同时含有三嗪基团和噁唑啉基团的环氧树脂的工艺，其方法是以传统方式将羟基芳香族材料环氧化，与表卤代醇反应，随后与碱性作用材料进行脱氢卤化，最后回收所得缩水甘油醚产品，其特征在于羟基芳香族材料是前述工艺步骤(II)的共聚合产物。