Cr(piperidyl dithiocarbamate)3 | 38532-20-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Cr(piperidyl dithiocarbamate)3
• 英文别名: chromium(3+);piperidine-1-carbodithioate
• CAS: 38532-20-6
• 化学式: C₁₈H₃₀CrN₃S₆
• 分子量: 532.848
• InChiKey: JDMFZYUFGMFUHL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  5.86
• 重原子数：
  28.0
• 可旋转键数：
  0.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  9.72
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  联铬酸盐 、 sodium piperidinedithiocarbamate 以 水 为溶剂， 生成 Cr(piperidyl dithiocarbamate)3
  参考文献：
  名称：

  Soundararajan, G.; Subbaiyan, M., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1983, vol. 22, # 12, p. 1058 - 1061

  摘要：

  DOI：

文献信息

• Thermal and magnetic studies of mixed ligand complexes of chromium(III) containing dithiocarbamate and acetylacetone/oxine/glycine moieties
  作者：B. S. Garg、R. Dixit、A. L. Singh、R. K. Sharma

  DOI：10.1007/bf01912799

  日期：1991.11

  Chromium(III) complexes of the type Cr(A)(A')2, Cr(A)2(A') and Cr(A)3 have been prepared (where A is either piperidyldithiocarbamate or morpholyldithiocarbamate and A' is glycine or oxine or acetylacetone moiety). The mixed ligand complexes have been characterized by elemental analyses, magnetic susceptibility measurements and thermal studies. The complexes show magnetic moment in the range of 3.5 - 4.3 B.M. which corresponds to three unpaired electrons. TG studies have also been carried out, in order to study the mode of decomposition of the complexes and to evaluate various kinetic parameters.