Vacuum ultraviolet photoelectron spectroscopic study of the NH2O and HNO molecules
作者:Jacob Baker、Vivienne Butcher、John M. Dyke、Alan Morris
DOI:10.1039/ft9908603843
日期:——
UV photoelectron spectra have been recorded for the F + NH2OH reaction at different reaction times. At short reaction times three bands associated with NH2O were observed, whereas at longer reaction times one band associated with NHO was seen.
chemiluminescence in the reactions of H + NO and D + NO were observed using the crossed diverging-beam method. In either case of HNO or DNO the electronically excited state (Ã1 A″) is preferentially, populated in the (000) vibrational state. As for the rotational distribution of the (000) vibrational state, the spectral simulation on the present data indicated a room-temperature distribution.
H + NO和D + NO反应中的化学发光采用交叉发束法观察。在HNO或DNO的两种情况下,电子激发状态(A 1 A“)优选是,填充在(000)的振动状态。至于(000)振动状态的旋转分布,对当前数据的光谱模拟表明是室温分布。
Milligan, D. E.; Jacox, M. E., Journal of Chemical Physics, 1962, vol. 37, p. 2302 - 2310