N1,N4-bis(4-tert-butylphenyl)benzene-1,4-diamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N1,N4-bis(4-tert-butylphenyl)benzene-1,4-diamine
• 英文别名: N,N'-bis-(4-tert-butyl-phenyl)-p-phenylenediamine；N,N'-Bis-(4-tert-butyl-phenyl)-p-phenylendiamin；1-N,4-N-bis(4-tert-butylphenyl)benzene-1,4-diamine
• 化学式: C₂₆H₃₂N₂
• 分子量: 372.553
• InChiKey: RHAQEUSTCCHDAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N1,N4-bis(4-tert-butylphenyl)benzene-1,4-diamine 在 sodium dithionite 、 碘 、 sulfur 、 甲基三丁基氯化铵 、 sodium hydroxide 作用下， 以 水 、 邻二氯苯 、 乙腈 为溶剂， 反应 123.0h， 生成 C₄₆H₇₂N₄S₂⁽²⁺⁾*2Br^(1-)
  参考文献：
  名称：

  [EN] NEAR-IR ABSORPTIVE COMPOUNDS AND DEVICES INCORPORATING THE SAME
  [FR] COMPOSÉS ABSORBANTS PROCHES DE L'IR ET DISPOSITIFS INCORPORANT CEUX-CI

  摘要：

  一种电致变色器件包括化合物Formula（I）：其中。R1和R2分别是烷基、烷氧基或芳基；R3、R4、R5、R6、R7、R8分别是H、烷氧基或芳氧基；R9和R10分别是烷氧基或芳氧基，或者当R1和R2是烷基时，R9和R10分别是H、烷氧基或芳氧基；R11和R12分别是烷基或-(CH2)nN+(R20)3 [X]，其中n为1至20；每个R20分别是烷基；X是阴离子。

  公开号：

  WO2018075533A1
• 作为产物：
  描述：

  4-叔丁基苯胺 在 盐酸 、 对苯二酚 作用下， 生成 N1,N4-bis(4-tert-butylphenyl)benzene-1,4-diamine
  参考文献：
  名称：

  The Nitro and Amino Derivatives of t-Butylbenzene

  摘要：

  DOI：

  10.1021/ja01304a052

文献信息

• <i>meta</i> ‐ and <i>para</i> ‐Phenylenediamine‐Fused Porphyrin Dimers: Synthesis and Magnetic Interactions of Their Dication Diradicals
  作者：Kenichi Kato、Atsuhiro Osuka

  DOI：10.1002/anie.201901939

  日期：2019.6.17

  meta‐ and para‐Phenylenediamine‐fused nickel(II) porphyrin dimers were synthesized by SNAr reaction of meso,β,β‐trichloro nickel(II) porphyrin with meta‐ and para‐phenylenediamines and subsequent Pd‐catalyzed intramolecular C−H arylation. Their tetrachlorinated dication diradicals are very stable, allowing SQUID magnetometry and revealing clear open‐shell characters for both meta and para isomers with

  元-和对位-苯稠合镍（II）卟啉二聚体的S合成Ñ的氩反应内消旋，β，β-三氯镍（II）卟啉与间位-和对位苯二胺类和随后的Pd催化的分子内C-H芳基化。他们四氯二价阳离子双自由基很稳定，让SQUID磁强计，揭示明确开壳层字符既元和对具有铁磁和反铁磁相互作用的异构体。Thiele碳氢化合物的氮类似物通常表现出显着的闭壳性质，但其扭曲的构象或插入其他亚苯基间隔基后，其隐藏的双自由基特征会增加。观察到的对同族的明显的双自由基性质表明，有效的自旋离域作用也可以增强双自由基性质。
• POLYMER CONTAINING SULFO GROUP AND ORGANIC ELECTROLUMINESCENT ELEMENT CONTAINING THE POLYMER
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1935919A1

  公开（公告）日：2008-06-25

  A polymer compound suitable for use in organic electroluminescent elements; a process for producing the compound; and an organic electroluminescent element employing the compound. The polymer is a sulfo-containing polymer characterized by having a structure formed by introducing sulfo groups into a polymer comprising repeating units represented by the general formula (1): wherein, in the formula, Ar1 and Ar2 each represents a monovalent aromatic group; Y represents a divalent group comprising an aromatic group; and W represents a divalent aromatic group having 4 to 30 carbon atoms.

  一种适用于有机电致发光元件的聚合物化合物；一种生产该化合物的工艺；以及一种采用该化合物的有机电致发光元件。该聚合物是一种含磺基聚合物，其特征是具有一种通过在包含通式（1）所代表的重复单元的聚合物中引入磺基而形成的结构： 式中，Ar1 和 Ar2 分别代表一价芳香族基团；Y 代表包含芳香族基团的二价基团；W 代表具有 4 至 30 个碳原子的二价芳香族基团。
• Near-IR absorptive compounds and devices incorporating the same
  申请人：Gentex Corporation

  公开号：US10745613B2

  公开（公告）日：2020-08-18

  An electrochromic device includes a compound of Formula (I): wherein: R1 and R2 are individually alkyl, alkoxy, or aryloxy; R3, R4, R5, R6, R7, R8 are individually H, alkoxy, or aryloxy; R9 and R10 are individually alkoxy, or aryloxy, or where R1 and R2 are alkyl, R9 and R10 are individually H, alkoxy, or aryloxy; and R11 and R12 are individually alkyl or —(CH2)nN+(R20)3 [X], wherein n is from 1 to 20; each R20 is individually alkyl; and X is an anion.

  电致变色装置包括式 (I) 的化合物： 其中R1 和 R2 分别为烷基、烷氧基或芳基氧基；R3、R4、R5、R6、R7、R8 分别为 H、烷氧基或芳基氧基；R9 和 R10 分别为烷氧基或芳基氧基，或 R1 和 R2 为烷基时，R9 和 R10 分别为 H、烷氧基或芳基氧基；以及 R11 和 R12 分别为烷基或-(CH2)nN+(R20)3 [X]，其中 n 为 1 至 20；每个 R20 分别为烷基；以及 X 为阴离子。
• Polymer Containing Sulfo Group and Organic Electroluminescent Element Containing the Polymer
  申请人：Togashi Kazuhiko

  公开号：US20090230851A1

  公开（公告）日：2009-09-17

  A polymer compound suitable for use in organic electroluminescent elements; a process for producing the compound; and an organic electroluminescent element employing the compound. The polymer is a sulfo-containing polymer characterized by having a structure formed by introducing sulfo groups into a polymer comprising repeating units represented by the general formula (1): wherein, in the formula, Ar 1 and Ar 2 each represents a monovalent aromatic group; Y represents a divalent group comprising an aromatic group; and W represents a divalent aromatic group having 4 to 30 carbon atoms.
• NEAR-IR ABSORPTIVE COMPOUNDS AND DEVICES INCORPORATING THE SAME
  申请人：Gentex Corporation

  公开号：US20180105738A1

  公开（公告）日：2018-04-19

  An electrochromic device includes a compound of Formula (I): wherein: R 1 and R 2 are individually alkyl, alkoxy, or aryloxy; R 3 , R 4 , R 5 , R 6 , R 7 , R 8 are individually H, alkoxy, or aryloxy; R 9 and R 10 are individually alkoxy, or aryloxy, or where R 1 and R 2 are alkyl, R 9 and R 10 are individually H, alkoxy, or aryloxy; and R 11 and R 12 are individually alkyl or —(CH 2 ) n N + (R 20 ) 3 [X], wherein n is from 1 to 20; each R 20 is individually alkyl; and X is an anion.