1,2,3,4-四氯-1,2,3,4-四氢萘 | 605-36-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 中文名称: 1,2,3,4-四氯-1,2,3,4-四氢萘
• 英文名称: 1,2,3,4-tetrahydro-1,2,3,4-tetrachloronaphthalene
• 英文别名: 1,2,3,4-tetrachloro-1,2,3,4-tetrahydro-naphthalene；1,2,3,4-Tetrachlor-1,2,3,4-tetrahydro-naphthalin；1,2,3,4-Tetrachloro-1,2,3,4-tetrahydronaphthalin；1,2,3,4-Tetrachlor-1,2,3,4-tetrahydronaphthalin；α-Naphthalin-1,2,3,4-tetrachlorid；ε-1,2,3,4-Tetrachlor-tetralin；Naphthalene, 1,2,3,4-tetrachloro-1,2,3,4-tetrahydro-；1,2,3,4-tetrachloro-1,2,3,4-tetrahydronaphthalene
• CAS: 605-36-7
• 化学式: C₁₀H₈Cl₄
• 分子量: 269.986
• InChiKey: SLKHRJWWFSTBJC-UHFFFAOYSA-N

物化性质

• 熔点：
  131-132 °C(Solv: ethanol, 92% (64-17-5))
• 沸点：
  364.4±42.0 °C(Predicted)
• 密度：
  1.67 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2,3,4-四氯-1,2,3,4-四氢萘 在 硝酸 作用下， 生成 1,4-二氯-5-硝基萘
  参考文献：
  名称：

  DE317755

  摘要：

  公开号：
• 作为产物：
  描述：

  萘 在 磺酰氯 、 苯 作用下， 生成 1,2,3,4-四氯-1,2,3,4-四氢萘
  参考文献：
  名称：

  Pongratz; Eichler, Chemische Berichte, 1936, vol. 69, p. 1292,1295

  摘要：

  DOI：

文献信息

• Method for producing organic compounds by substituting halogen atoms
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1486479A1

  公开（公告）日：2004-12-15

  The invention pertains to a method in which a halogen atom of an organic compound is replaced with a group derived from a nucleophilic agent, at high yield and high efficiency, by the following method which includes a step of reacting the nucleophilic agent with an organic material having a halogen atom bonded to a carbon atom having four σ bonds, more specifically: a method for producing an organic compound having Q, the method including a step of reacting a compound represented by general formula (2) with an organic starting material having at least one halogen atom bonded to a carbon atom having four σ bonds so as to replace the halogen atom in the organic starting material with Q:         MQa     (2) (wherein M represents an alkali metal atom, an alkali earth metal atom, or a rare earth metal atom; Q represents a moiety of an inorganic acid or an active hydrogen compound derived by eliminating a proton, wherein Q is a halogen atom different from the halogen atom in the organic starting material having the halogen atom bonded to the carbon atom having the four σ bonds; and a represents an integer of 1 to 3) in the presence of a compound represented by general formula (1) (wherein Z- represents an anion derived by eliminating a proton from an inorganic acid or an active hydrogen compound; R2 is the same or different; R2 each independently represent a C1-C10 hydrocarbon group or two R2 on the same nitrogen atom may be bonded with each other to form a ring with the nitrogen atom).

  这项发明涉及一种方法，其中有机化合物中的卤素原子被来自亲核试剂的基团取代，且产率高效率高，通过以下方法实现，包括以下步骤：将亲核试剂与具有与碳原子形成四个σ键的卤素原子相结合的有机材料反应的步骤，更具体地说：一种用于生产具有Q的有机化合物的方法，包括以下步骤：将由通式（2）表示的化合物与至少一个卤素原子与碳原子形成四个σ键的有机起始材料反应，以将有机起始材料中的卤素原子替换为Q：         MQa     (2) （其中M代表碱金属原子、碱土金属原子或稀土金属原子；Q代表由消除质子衍生的无机酸或活性氢化合物的基团，其中Q是不同于有机起始材料中卤素原子的卤素原子，该卤素原子与具有四个σ键的碳原子相结合；a表示1到3的整数），在通式（1）表示的化合物的存在下 （其中Z-代表由无机酸或活性氢化合物中消除质子衍生的阴离子；R2相同或不同；R2各自独立地表示C1-C10烃基，或者两个R2在同一氮原子上可能与彼此结合形成与氮原子的环）。
• METHOD OF PRODUCING CATALYST COMPONENT FOR OLEFIN POLYMERIZATION
  申请人：Tonen Corporation

  公开号：EP0440813A1

  公开（公告）日：1991-08-14

  A method of effectively producing an olefin polymerization catalyst component which exhibits a high activity of polymerizing an olefin to give a polymer having a reduced content of low molecular components, said method comprising bringing into contact with one another (a) metallic magnesium, (b) a halogenated hydrocarbon represented by a general formula RX, wherein R represents C₁ to C₂₀ alkyl, aryl or cycloalkyl, and X represents halogen, and (c) a compound of a general formula X¹nM(OR¹)m-n, wherein X¹ represents hydrogen, halogen or C₁ to C₂₀ hydrocarbyl, M represents boron, carbon, aluminum, silicon or phosphorus, R¹ represents C₁ to C₂₀ hydrocarbyl, m is a valence of M, and m > n ≧ 0, to give a magnesium-containing solid; bringing the solid into contact with a halogenated alcohol; and bringing the product of contact further into contact with a titanium compound and a solid halogenated hydrocarbon.

  一种有效生产烯烃聚合催化剂组分的方法，该组分具有聚合烯烃的高活性，从而得到低分子组分含量降低的聚合物，所述方法包括使以下物质相互接触：(a)金属镁；(b)通式 RX.代表的卤代烃，其中 R 代表 C₁至 C₂₀烷基、芳基或环烷基；以及 X 代表卤素、其中 R 代表 C₁ 至 C₂₀ 烷基、芳基或环烷基，X 代表卤素，以及 (c) 通式 X¹nM(OR¹)m-n 的化合物，其中 X¹ 代表氢、卤素或 C₁ 至 C₂₀ 烃基、M 代表硼、碳、铝、硅或磷，R¹ 代表 C₁ 至 C₂₀烃基，m 是 M 的化合价，且 m > n ≧ 0，从而得到含镁固体；使固体与卤代醇接触；以及使接触产物进一步与钛化合物和固体卤代烃接触。
• Ink for ink jet and ink jet recording apparatus
  申请人：Toshiba Tec Kabushiki Kaisha

  公开号：EP1514911A1

  公开（公告）日：2005-03-16

  There is disclosed an ink jet recording apparatus (1) comprising a color ink container (5) having a capacity V1 accommodating therein a solvent polymerizable in the presence of an acid and a colorant, a reaction liquid container (3) having a capacity V2 (V2

  本发明公开了一种喷墨记录装置 (1)，包括一个容量为 V1 的彩色墨水容器 (5)，其中装有可在酸和着色剂存在下聚合的溶剂；一个容量为 V2 (V2水输送到记录头的供应管。
• Inkjet ink
  申请人：Toshiba Tec Kabushiki Kaisha

  公开号：EP1528088A1

  公开（公告）日：2005-05-04

  There is provided an inkjet ink comprising a photo-acid generating agent which is capable of generating an acid as it is irradiated with light, a color component, and an acid-polymerizable compound which can be polymerized in the presence of an acid, wherein at least 40% of the acid-polymerizable solvent is a vinyl ether compound represented by the following general formula (1):         R13-R14-(R13)p     (1)    (Wherein R13(s) is a group selected from the group consisting of a vinyl ether group, a group having a vinyl ether skeleton, an alkoxy group, substituted hydroxyl group and hydroxyl group wherein at least one of R13(s) is vinyl ether group or a group having a vinyl ether skeleton, R14 is a group comprising a substituted or unsubstituted cyclic skeleton and having a valence of (p+1), and p is a positive integer including zero).

  本发明提供了一种喷墨墨水，该墨水包含一种在光照射下能产生酸的光酸生成剂、一种颜色成分和一种可在酸存在下聚合的可酸聚合化合物，其中至少 40% 的可酸聚合溶剂是由下式（1）表示的乙烯基醚化合物： R13-R14-(R13)p (1) (其中，R13(s)是从乙烯基醚基、具有乙烯基醚骨架的基团、烷氧基、取代羟基和羟基组成的组中选出的基团，其中 R13(s) 中至少有一个是乙烯基醚基或具有乙烯基醚骨架的基团，R14 是由取代或未取代的环状骨架组成且价数为 (p+1) 的基团，p 是包括零在内的正整数）。
• Inkjet-ink
  申请人：Toshiba TEC Kabushiki Kaisha

  公开号：EP1705230A1

  公开（公告）日：2006-09-27

  There is provided an inkjet ink comprising a photo-acid generating agent which is capable of generating an acid as it is irradiated with light, a color component, and an acid-polymerizable compound which can be polymerized in the presence of an acid, wherein at least 40% of the acid-polymerizable solvent is a vinyl ether compound represented by the following general formula (1):          R13-R14-(R13)p ...     (1) (Wherein R13(s) is a group selected from the group consisting of a vinyl ether group, a group having a vinyl ether skeleton, an alkoxy group, substituted hydroxyl group and hydroxyl group wherein at least one of R13(s) is vinyl ether group or a group having a vinyl ether skeleton, R14 is a group comprising a substituted or unsubstituted cyclic skeleton and having a valence of (p+1), and p is a positive integer including zero).

  本发明提供了一种喷墨墨水，该墨水包含一种在光照射下能产生酸的光酸生成剂、一种颜色成分和一种可在酸存在下聚合的可酸聚合化合物，其中至少 40% 的可酸聚合溶剂是由下式（1）表示的乙烯基醚化合物： R13-R14-(R13)p ...... (1) (其中，R13(s)是选自乙烯基醚基、具有乙烯基醚骨架的基团、烷氧基、取代羟基和羟基组成的基团，其中 R13(s) 中至少有一个是乙烯基醚基或具有乙烯基醚骨架的基团；R14 是由取代或未取代的环状骨架组成的基团，其价数为 (p+1)；p 是包括零在内的正整数）。