6,6'-Bis(2,3-epoxypropoxy)-2,2'-binaphthyl

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6,6'-Bis(2,3-epoxypropoxy)-2,2'-binaphthyl
• 英文别名: 6,6'-Bis(2,3-epoxypropoxy)-2,2 binaphthyl；2-[[6-[6-(oxiran-2-ylmethoxy)naphthalen-2-yl]naphthalen-2-yl]oxymethyl]oxirane
• 化学式: C₂₆H₂₂O₄
• 分子量: 398.458
• InChiKey: XQHHZTXCKIEIFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-溴-6-甲氧基萘 在 chloride sodium hydroxide 、 吡啶盐酸盐 、 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 生成 6,6'-Bis(2,3-epoxypropoxy)-2,2'-binaphthyl
  参考文献：
  名称：

  Liquid Crystalline Epoxy Thermosets

  摘要：

  Rigid rod epoxy compounds can be cured in liquid crystalline structure. The so obtained networks exhibit better mechanical properties with respect to the isotropic ones. The mesogenic character of the epoxy compounds appears more crucial than the molecular geometry of the curing agent in developing liquid crystallinity. The curing temperature plays an important role in affecting the state of order of the thermosets.

  DOI：

  10.1080/10587259508033628

文献信息

• Chiral agent for liquid crystal, liquid crystal composition and polymer, as well as filter for optical recording medium, optical recording medium and color filter liquid for crystal
  申请人：Yumoto Masatoshi

  公开号：US20070228325A1

  公开（公告）日：2007-10-04

  The chiral agent used for liquid crystal according to the present invention comprises a phosphoric acid amide represented by General Formula (1) below: in General Formula (1), the binaphthyl structure has an axial asymmetry of either (R) or (S); R 1 and R 2 may be identical or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkenyl group, an alkynyl group or an alkoxy group; R 3 and R 4 may be identical or different and each represents a hydrogen atom, an alkyl group or an aryl group.
• 3D PRINTABLE LQUID CRYSTALLINE ELASTOMERS WITH TUNABLE SHAPE MEMORY BEHAVIOR AND BIO-DERIVED RENDITIONS
  申请人：UT-Battelle, LLC

  公开号：US20160289491A1

  公开（公告）日：2016-10-06

  Described herein are liquid crystalline elastomer compositions comprising aromatic epoxy units crosslinked with alkylene diacid units having alkylene segments containing at least one methylene unit, and/or aromatic epoxy units crosslinked with polyphenolic units, wherein the aromatic epoxy units and alkylene diacid units and/or polyphenolic units are in a molar ratio that results in the liquid crystalline elastomer composition exhibiting a glass transition temperature (T g ) and a thermal stability of the liquid crystalline phase (T lc ) that make them particularly suitable as shape memory materials and for use in methods of additive manufacturing. Methods for producing these compositions and their use in additive manufacturing processes are also described.
• US7497970B2
  申请人：——

  公开号：US7497970B2

  公开（公告）日：2009-03-03
• Liquid Crystalline Epoxy Thermosets
  作者：M. Giamberjni、E. Amendola、C. Carfagna

  DOI：10.1080/10587259508033628

  日期：1995.6

  Rigid rod epoxy compounds can be cured in liquid crystalline structure. The so obtained networks exhibit better mechanical properties with respect to the isotropic ones. The mesogenic character of the epoxy compounds appears more crucial than the molecular geometry of the curing agent in developing liquid crystallinity. The curing temperature plays an important role in affecting the state of order of the thermosets.