2,9-二癸基萘并[2,3-b]萘并[2',3':4,5]噻吩并[2,3-d]噻吩 | 1169932-40-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2,9-二癸基萘并[2,3-b]萘并[2',3':4,5]噻吩并[2,3-d]噻吩
• 英文名称: 2,9-didecyldinaphtho[2,3-b:2',3'-f]thieno[2,3-b]thiophene
• 英文别名: 2,9-didecyldinaphtho[2,3-b:2′,3′-f ]thieno[3,2-b]thiophene；2,9-didecyldinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thiophene；6,6'-didecyldinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thiophene；Dntt-2,9-C10；7,19-didecyl-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2(11),3,5,7,9,14(23),15,17,19,21-undecaene
• CAS: 1169932-40-4
• 化学式: C₄₂H₅₂S₂
• 分子量: 621.007
• InChiKey: LNWJGRPGRSTXTD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.1
• 重原子数：
  44
• 可旋转键数：
  18
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-溴-6-甲氧基萘 在 吡啶 、 四(三苯基膦)钯 、 正丁基锂 、 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 、 碘 、 三溴化硼 作用下， 以 四氢呋喃 、 正己烷 、 二氯甲烷 、 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 113.0h， 生成 2,9-二癸基萘并[2,3-b]萘并[2',3':4,5]噻吩并[2,3-d]噻吩
  参考文献：
  名称：

  Dinaphtho [2,3- b：2'，3'- f ] thieno [3,2- b ]噻吩（DNTT）衍生物的一般合成

  摘要：

  描述了一种由容易获得的2-甲氧基萘直接合成二萘并[2,3- b：2'，3'- f ]噻吩并[3,2- b ]噻吩（DNTT）衍生物的方法。因此，新开发的DNTT衍生物在蒸汽处理的场效应晶体管中显示出非常高的场效应迁移率，最高可达8 cm 2 V –1 s –1。

  DOI：

  10.1021/ol2010837

文献信息

• [EN] HETEROACENE COMPOUNDS FOR ORGANIC ELECTRONICS<br/>[FR] COMPOSÉS D'HÉTÉROACÈNE POUR L'ÉLECTRONIQUE ORGANIQUE
  申请人：BASF SE

  公开号：WO2014087300A1

  公开（公告）日：2014-06-12

  The present invention provides compounds of formula (1) wherein o is 1, 2 or 3, p is 0, 1 or 2, n is 0, 1 or 2, m is 0, 1 or 2, and A is a mono-or polycyclic ring system, which may contain at least one heteroatom, and an electronic device comprising the compounds as semiconducting material.

  本发明提供了化合物的公式（1），其中o为1、2或3，p为0、1或2，n为0、1或2，m为0、1或2，而A为单环或多环环系统，可能包含至少一个杂原子，并且包含该化合物作为半导体材料的电子设备。
• COMPOSITION FOR FORMING ORGANIC SEMICONDUCTOR FILM, ORGANIC SEMICONDUCTOR FILM AND METHOD FOR MANUFACTURING SAME, AND ORGANIC SEMICONDUCTOR COMPOUND
  申请人：Fujifilm Corporation

  公开号：EP3193383A1

  公开（公告）日：2017-07-19

  Objects of the present invention are to provide a composition for forming an organic semiconductor film that has excellent preservation stability and makes the obtained organic semiconductor element exhibit excellent driving stability in the atmosphere, to provide an organic semiconductor film using the composition for forming an organic semiconductor film, a method for manufacturing the organic semiconductor film, an organic semiconductor element, a method for manufacturing the organic semiconductor element, and to provide a novel organic semiconductor compound. A composition for forming an organic semiconductor film of the present invention contains a specific organic semiconductor having an alkoxyalkyl group as a component A and a solvent as a component B, in which a content of a non-halogen-based solvent is equal to or greater than 50% by mass with respect to a total content of the component B, and a content of the component A is equal to or greater than 0.7% by mass and less than 15% by mass.

  本发明的目的是提供一种用于形成有机半导体薄膜的组合物，该组合物具有优异的保存稳定性，并使获得的有机半导体元件在大气中表现出优异的驱动稳定性；提供一种使用该用于形成有机半导体薄膜的组合物的有机半导体薄膜、一种制造该有机半导体薄膜的方法、一种有机半导体元件、一种制造该有机半导体元件的方法，以及提供一种新型有机半导体化合物。 本发明的一种用于形成有机半导体薄膜的组合物含有一种特定的有机半导体，该半导体具有作为组分 A 的烷氧基烷基和作为组分 B 的溶剂，其中非卤基溶剂的含量相对于组分 B 的总含量等于或大于 50%（按质量计），而组分 A 的含量等于或大于 0.7%（按质量计）且小于 15%（按质量计）。
• NOVEL HETEROCYCLIC COMPOUND, METHOD FOR PRODUCING INTERMEDIATE THEREFOR, AND USE THEREOF
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP2679592B1

  公开（公告）日：2018-10-03
• LEAVING SUBSTITUENT-CONTAINING COMPOUND, ORGANIC SEMICONDUCTOR MATERIAL, ORGANIC SEMICONDUCTOR FILM CONTAINING THE MATERIAL, ORGANIC ELECTRONIC DEVICE CONTAINING THE FILM, METHOD FOR PRODUCING FILM-LIKE PRODUCT, PI-ELECTRON CONJUGATED COMPOUND AND METHOD FOR PRODUCING THE PI-ELECTRON CONJUGATED COMPOUND
  申请人：Goto Daisuke

  公开号：US20120153271A1

  公开（公告）日：2012-06-21

  A leaving substituent-containing compound including a partial structure represented by the following General Formula (I): where a pair of X 1 and X 2 or a pair of Y 1 and Y 2 each represent a hydrogen atom; the other pair each represent a group selected from the group consisting of a halogen atom and a substituted or unsubstituted acyloxy group having one or more carbon atoms; a pair of the acyloxy groups represented by the pair of X 1 and X 2 or the pair of Y 1 and Y 2 may be identical or different, or may be bonded together to form a ring; R 1 to R 4 each represent a hydrogen atom or a substituent; and Q 1 and Q 2 each represent a hydrogen atom, a halogen atom or a monovalent organic group, and may be bonded together to form a ring.
• LEAVING SUBSTITUENT-CONTAINING COMPOUND, ORGANIC SEMICONDUCTOR MATERIAL FORMED THEREFROM, ORGANIC ELECTRONIC DEVICE, ORGANIC THIN-FILM TRANSISTOR AND DISPLAY DEVICE USING THE ORGANIC SEMICONDUCTOR MATERIAL, METHOD FOR PRODUCING FILM-LIKE PRODUCT, PI-ELECTRON CONJUGATED COMPOUND AND METHOD FOR PRODUCING THE PI ELECTRON CONJUGATED COMPOUND
  申请人：Goto Daisuke

  公开号：US20130095605A1

  公开（公告）日：2013-04-18

  A leaving substituent-containing compound represented by General Formula (I), wherein the leaving substituent-containing compound can be converted to a compound represented by General Formula (Ia) and a compound represented by General Formula (II), by applying energy to the leaving substituent-containing compound, in General Formulas (I), (Ia) and (II), X and Y each represent a hydrogen atom or a leaving substituent, where one of X and Y is the leaving substituent and the other is the hydrogen atom; Q 2 to Q 5 each represent a hydrogen atom, a halogen atom or a monovalent organic group; Q 1 and Q 6 each represent a hydrogen atom or a monovalent organic group other than the leaving substituent; and among the monovalent organic groups represented by Q 1 to Q 6 , adjacent monovalent organic groups may be linked together to form a ring.