(+/-)-sesbanine | 903635-79-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: (+/-)-sesbanine
• 英文别名: Sesbanine；Spiro(cyclopentane-1,4'(1'H)-(2,7)naphthyridine)-1',3'(2'H)-dione, 3-hydroxy-, trans-(+)-；3'-hydroxyspiro[2,7-naphthyridine-4,1'-cyclopentane]-1,3-dione
• CAS: 903635-79-0
• 化学式: C₁₂H₁₂N₂O₃
• 分子量: 232.239
• InChiKey: UETOAKFPMASNTK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  79.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  烟酸甲酯 在 氨 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 甲醇 、 苯 为溶剂， 反应 9.67h， 生成 (+/-)-sesbanine
  参考文献：
  名称：

  A facile synthesis of (±)-sesbanine via γ-addition of ketene silyl acetal with quaternized methyl nicotinate

  摘要：

  DOI：

  10.1016/s0040-4039(00)98168-1

文献信息

• Total synthesis of racemic sesbanine
  作者：Jeffrey C. Bottaro、Glenn A. Berchtold

  DOI：10.1021/jo01294a059

  日期：1980.3
• HIGH TEMPERATURE MATERIAL COMPOSITIONS FOR HIGH TEMPERATURE THERMAL CUTOFF DEVICES
  申请人：Kent Perry

  公开号：US20120121795A1

  公开（公告）日：2012-05-17

  The present disclosure provides a high-temperature thermal pellet composition that maintains structural rigidity up to a transition temperature of about 240° C. The composition comprises at least one organic compound (e.g., triptycene or 1-aminoanthroquinone). The pellet can be disposed in a housing of a thermally-actuated, current cutoff device, such as a high-temperature thermal cutoff device (HTTCO). Also provided are material systems, which include the pellet composition and a high-temperature seal that provides substantial sealing up to at least the transition temperature. Methods of making such high-temperature pellet compositions and incorporating them into a thermally-actuated, current cutoff device are also provided.
• US8961832B2
  申请人：——

  公开号：US8961832B2

  公开（公告）日：2015-02-24
• A facile synthesis of (±)-sesbanine via γ-addition of ketene silyl acetal with quaternized methyl nicotinate
  作者：Makoto Wada、Yoshihiro Nishihara、Kin-ya Akiba

  DOI：10.1016/s0040-4039(00)98168-1

  日期：——