氯-(2-羟基-5-甲基苯基)汞 | 23068-68-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 氯-(2-羟基-5-甲基苯基)汞
• 英文名称: 2-Chlormercuri-4-methyl-phenol
• 英文别名: Mercury, chloro(2-hydroxy-5-methylphenyl)-；chloro-(2-hydroxy-5-methylphenyl)mercury
• CAS: 23068-68-0
• 化学式: C₇H₇ClHgO
• 分子量: 343.175
• InChiKey: QZZKGGRUMRHLAS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.56
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  氯-(2-羟基-5-甲基苯基)汞 在 四氯化碲 作用下， 以 1,4-二氧六环 为溶剂， 反应 6.0h， 以78%的产率得到5-methyl-2-hydroxy-phenyltellurium(IV) chloride
  参考文献：
  名称：

  FUNCTIONALIZED DIORGANOTELLURIDE AND DIORGANODITELLURIDE: COMPLEXATION BEHAVIOUR AS A HYBRID (Te, O) LIGAND

  摘要：

  The ligation of asymmetric diorganotelluride aryltelluroacetic acid (I) with Pd(II) and Pt(II) and bis(5-methyl-2-hydroxyphenyl)ditelluride (2) with Hg(LI) and Cu(II) have been studied. In square planar complexes of stoichiometry [MCl(1-H)](2)(M= Pd or Pt) the bidentate uninegative behaviour of 1 has been inferred on the basis of IR H-1 and C-13{H-1} NMR, data in conjunction with elemental analysis. The presence of an M-Cl(bridging) vibration band in the IR spectra around 260-270 cm(-1) supports the dimeric formulation of these complexes. In DMSO these chloro bridges are broken which result in lower Values for molecular weights in comparison to those calculated on the basis of dimeric stoichiometry. The reaction of 2 with CuCl2 results in an unusually stable aryltellurenyl chloride. The Te <-- O secondary interaction seems to be responsible for its stability. The reaction of HgCl2 with 2 gives an intricate material of composition ArTeHgCl2. It seems to be aryltellurenyl chloride which is mercurated at a position ortho to the OH group.

  DOI：

  10.1080/10426509708043568
• 作为产物：
  描述：

  对甲酚 、 mercury(II) diacetate 、 sodium chloride 在 溶剂黄146 作用下， 以 甲醇 、 水 、 溶剂黄146 为溶剂， 生成 sodium acetate 、 氯-(2-羟基-5-甲基苯基)汞
  参考文献：
  名称：

  Synthesis and Characterization of Complexes of Some Hydroxyaryltellurium Trichlorides with N-Donor Ugands

  摘要：

  DOI：

  10.1080/00945719909349509

文献信息

• Heteroannulation via intramolecular (.pi.-allyl)palladium displacement
  作者：R. C. Larock、L. W. Harrison、M. H. Hsu

  DOI：10.1021/jo00193a047

  日期：1984.9
• LAROCK, R. C.;HARRISON, L. W.;HSU, M. H., J. ORG. CHEM., 1984, 49, N 19, 3662-3664
  作者：LAROCK, R. C.、HARRISON, L. W.、HSU, M. H.

  DOI：——

  日期：——