1-乙烯氧基-4-[2-(4-乙烯氧基苯基)丙-2-基]苯 | 3754-60-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-乙烯氧基-4-[2-(4-乙烯氧基苯基)丙-2-基]苯
• 中文别名: 苯,1,1'-(1-甲基乙亚基)双[4-(乙烯基OXY)-
• 英文名称: 1,1'-propane-2,2-diylbis[4-(vinyloxy)benzene]
• 英文别名: bisphenol-A divinyl ether；1,1'-isopropylidenebis[4-(vinyloxy)benzene]；2,2-Bis-<4-vinyloxy-phenyl>-propan；2.2-Bis-<4-vinyloxy-phenyl>-propan；2,2-Bis-(4-hydroxyphenyl)-propan-divinylaether；Bisphenol A divinyl ether；1-ethenoxy-4-[2-(4-ethenoxyphenyl)propan-2-yl]benzene
• CAS: 3754-60-7
• 化学式: C₁₉H₂₀O₂
• 分子量: 280.367
• InChiKey: YOTSWLOWHSUGIM-UHFFFAOYSA-N

物化性质

• 沸点：
  374.9±35.0 °C(Predicted)
• 密度：
  1.023±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2909309090

反应信息

• 作为产物：
  描述：

  双酚A 、 乙炔 在 potassium hydroxide semihydrate 作用下， 以 二甲基亚砜 为溶剂， 120.0 ℃ 、1.57 MPa 条件下， 反应 3.0h， 以63%的产率得到1-乙烯氧基-4-[2-(4-乙烯氧基苯基)丙-2-基]苯
  参考文献：
  名称：

  Nucleophilic addition to acetylenes in superbasic catalytic systems: XVIII. Vinylation of phenols and naphthols with acetylene

  摘要：

  Phenols and naphthols react with acetylene in a superbasic system KOH-DMSO forming the corresponding aryl vinyl ethers in up to 80% yields.

  DOI：

  10.1134/s1070428015020086

文献信息

• Development of a Highly Efficient Catalytic Method for Synthesis of Vinyl Ethers
  作者：Yoshio Okimoto、Satoshi Sakaguchi、Yasutaka Ishii

  DOI：10.1021/ja0173932

  日期：2002.2.1

  A new method for the preparation of alkyl vinyl ethers has been developed. Thus, various types of alkyl vinyl ethers were synthesized by the reaction of alcohols with vinyl acetate under the influence of a catalytic amount of [Ir(cod)Cl]2 combined with Na2CO3 in good to excellent yields.

  开发了一种制备烷基乙烯基醚的新方法。因此，在催化量的 [Ir(cod)Cl]2 与 Na2CO3 结合的影响下，通过醇与乙酸乙烯酯的反应合成了各种类型的烷基乙烯基醚，收率良好至极好。
• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• DEVELOPING SOLUTION FOR LITHOGRAPHIC PRINTING PLATES AND PRODUCTION METHOD OF LITHOGRAPHIC PRINTING PLATE
  申请人：ADACHI Keiichi

  公开号：US20080081295A1

  公开（公告）日：2008-04-03

  A developing solution containing at least one of compounds represented by the formulae <1>, <2> and <3> as defined herein, and having a pH of from 2 to 10; and a method for producing a lithographic printing plate, including imagewise exposing a lithographic printing plate precursor including an image recording layer and a support to cure the image recording layer in the exposed area, and developing the exposed lithographic printing plate precursor with an aqueous solution containing at least one of the compounds represented by the formulae <1>, <2> and <3> as defined herein and having a pH of 2 to 10 are provided.

  本发明提供了一种含有以下式子<1>、<2>和<3>中至少一种化合物的发展溶液，其定义如下，并且具有pH值在2至10之间；以及一种生产平版印刷版的方法，包括图像曝光平版印刷版前体，其中包括图像记录层和支撑层，以治愈所曝光区域的图像记录层，并用含有至少一种以下式子<1>、<2>和<3>中定义的化合物的水溶液，其pH值为2至10，来开发所曝光的平版印刷版前体。
• COMPOSITION FOR OPTICAL MATERIAL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1319966A1

  公开（公告）日：2003-06-18

  The composition for optical materials of the present invention contains at least one compound represented by the following Formula 1: wherein R1, R2 and R3 are each independently C1-C10 hydrocarbyl or hydrogen; X1, X2 and X3 are each independently S, Se or Te; Y1, Y2 and Y3 are each independently -Sa-[(CH2)bS]cH, a is an integer from 0 to 2, b is an integer from 0 to 4, and c is an integer from 0 to 2, and a compound reactive to the compound of Formula 1. A resin produced by curing a composition containing the compound of Formula 1 by polymerization has a high refractive index, and suitable as various optical materials.

  本发明的光学材料组合物含有至少一种由下式 1 表示的化合物： 其中R1、R2和R3各自独立地为C1-C10烃基或氢；X1、X2和X3各自独立地为S、Se或Te；Y1、Y2和Y3各自独立地为-Sa-[(CH2)bS]cH，a为0至2的整数，b为0至4的整数，c为0至2的整数，以及与式1化合物反应的化合物。通过聚合固化含有式 1 化合物的组合物而产生的树脂具有高折射率，适合用作各种光学材料。
• POLYMERIZABLE COMPOSITION, OPTICAL MATERIAL COMPRISING THE COMPOSITION AND METHOD FOR PRODUCING THE MATERIAL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1524289A1

  公开（公告）日：2005-04-20

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98 % or more. A reduction in a chlorine content of the sulfur compound described above to 0.1 % by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100°C for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化包含分子中至少含有一种表硫化物的化合物的可聚合组合物而获得的固化物，可通过向包含分子中至少含有一种表硫化物的化合物的可聚合组合物中添加香料来减少气味。 将硫的纯度提高到 98% 或更高，可消除镜片的浑浊度。 将上述硫化合物的氯含量降低到 0.1%（重量百分比）或更低，可提高高折射率光学材料的抗氧化性和耐光性，并改善其色调。 在 0.001 至 50 托的减压条件下，将组合物预先在 0 至 100°C 的温度下进行 1 分钟至 24 小时的脱气处理，可获得具有高折射率和高透明度的光学产品。