摩熵化学
数据库官网
小程序
打开微信扫一扫
首页 分子通 化学资讯 化学百科 反应查询 关于我们
请输入关键词

potassium tetraphenyldithioimidodiphosphinate | 6588-06-3

中文名称
——
中文别名
——
英文名称
potassium tetraphenyldithioimidodiphosphinate
英文别名
N-(Diphenyl-thiophosphinyl)-imido-diphenyl-thiophosphinsaeure-K-Salz;potassium;diphenylphosphinothioylimino-diphenyl-sulfido-λ5-phosphane
potassium tetraphenyldithioimidodiphosphinate化学式
CAS
6588-06-3
化学式
C24H20NP2S2*K
mdl
——
分子量
487.607
InChiKey
KYLGCKOXAXVAEP-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    2.35
  • 重原子数:
    30
  • 可旋转键数:
    5
  • 环数:
    4.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    45.4
  • 氢给体数:
    0
  • 氢受体数:
    3

反应信息

  • 作为反应物:
    描述:
    五羰基溴铼(I)potassium tetraphenyldithioimidodiphosphinate甲苯 为溶剂, 以98%的产率得到(tetracarbonyl)(tetraphenyl-imidodithiophosphinato-κ2Se,Se')rhenium
    参考文献:
    名称:
    Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph2P(E)NP(E)Ph2]−, E=O, S, Se towards ReBr(CO)5
    摘要:
    Reaction of ReBr(CO)(5) with Li[Ph2P(O)NP(O)Ph-2] afforded the cryptate Li[Re-2(CO)(6)]{mu-Ph2P(O)NP(O)Ph-2-kappa O-2,O'}(3)]; whereas K[Ph2P(O)NP(O)Ph-2] reacted with ReBr(CO)(5) to give K[Re-2(CO)(6){mu-Ph2P(O)NP(O)Ph-2-kappa O-2,O'}{Ph2P(O)NP(O)Ph-2-kappa O-2,O'}(2)]. Other chalcogen ligands' salts M[Ph2P(E)NP(E)Ph-2], E = Se and S. M = K and Li gave dirhenium carbonyls with bromido and Ph2P(E)NP(E)Ph-2, E = Se or S bridges upon reaction with ReBr(CO)(5). (C) 2010 Elsevier Ltd. All rights reserved.
    DOI:
    10.1016/j.poly.2010.08.011
  • 作为产物:
    描述:
    bis(diphenylthiophosphinoyl)amine 在 potassium hydroxide 作用下, 以 甲醇 为溶剂, 以1.80 g的产率得到potassium tetraphenyldithioimidodiphosphinate
    参考文献:
    名称:
    具有双(二苯基硫代甲酰基)酰胺配体的 铱(iii)荧光粉,用于EQE接近28%的高效绿色和天蓝色OLED †
    摘要:
    在这项研究中,合成了一种新的配体,含磷-硫(PS )键的双(二苯基氟硫基)酰胺(Stpip)作为辅助配体。四种铱(III)配合物(Ir(ppy)2(Stpip),Ir(tfppy)2(Stpip),Ir(ttppy)2(Stpip)和Ir(tntppy)2(Stpip)与苯基吡啶衍生物(ppy = 2-苯基吡啶); tfppy = 2- [4-(三氟甲基)苯基]吡啶;ttppy = 2- [3,5-双(三氟甲基)苯基]吡啶; 研究了tntppy = 2- [2,6-双(三氟甲基)-4-吡啶基]吡啶)作为主要配体的情况。由于稳定的S-铱键,这些络合物发出的绿色或天蓝色的光致发光具有高量子产率(的Ir(ppy)2(Stpip) :λ最大= 490纳米,Φ = 44.7%;的Ir(tfppy)2(Stpip ):λ最大= 495纳米,Φ = 85.4%;的Ir(ttppy)2(Stpip) :λ最大=
    DOI:
    10.1039/c8tc02265h
点击查看最新优质反应信息

文献信息

  • Ruthenium chalcogenonitrosyl and bridged nitrido complexes containing chelating sulfur and oxygen ligands
    作者:Ho-Yuen Ng、Wai-Man Cheung、Enrique Kwan Huang、Kang-Long Wong、Herman H.-Y. Sung、Ian D. Williams、Wa-Hung Leung
    DOI:10.1039/c5dt02513c
    日期:——
    afforded trans-[Ru(NS)ClN(R2PS)2}2] [R = Ph (3), Pri (4), But (5)]. Alternatively, the thionitrosyl complex 5 was obtained from [Bun4N][Ru(N)Cl4] and KN(But2PS)2, presumably via sulfur atom transfer from [N(But2PS)2] to the nitride. Reactions of 1 and 2 with NaLOEt (LOEt− = [Co(η5-C5H5)P(O)(LOEt)2}3]) gave [Ru(NX)LOEtCl2] (X = S (8), Se (9)). Treatment of [Bun4N][Ru(N)Cl4] with KN(R2PS)2 produced RuIV–RuIV
    合成了含有螯合和氧配体代和代亚硝酰配合物,并对其脱反应进行了研究。的反应聚体-的[Ru(N)3(ASPH 3)2 ]在回流元素四氢呋喃,得到chalcogenonitrosyl络合物聚体-的[Ru(NX)3(ASPH 3)2 ] [X = S (1),Se(2)]。用KN(R 2 PS)2处理1得到反式-[Ru(NS)Cl N(R 2 PS)2 }2 ] [R = Ph(上3),我( 4),卜吨( 5)]。或者,大概是通过从[N(Bu t 2 PS) 2 ] -转移原子,从[Bu n 4 N] [Ru(N)Cl 4 ]和KN(Bu t 2 PS) 2获得代亚硝酰基配合物5-氮化物。的反应1和2与NAL OET(L OET - = [CO(η 5 -C 5 H ^5)P(O)(L OEt) 2 } 3 ] -)给出[Ru(NX)L OEt Cl 2 ](X
  • An unsaturated half-sandwich ruthenium(II) complex containing a dithioimidodiphosphinate ligand
    作者:Wai-Man Cheung、Qian-Feng Zhang、Ian D. Wiliams、Wa-Hung Leung
    DOI:10.1016/j.ica.2005.04.031
    日期:2006.2
    of 1 with Li[BEt3H] gave the 16-electron half-sandwich Ru(II) complex [Cp*RuN(Ph2PS)2}] (2). Complexes 1 and 2 have been characterized by X-ray crystallography. The Ru–Cp*(centroid) and average Ru–S distances in 1 are 1.827 and 2.3833(5) A, respectively. The corresponding bond distances in 2 are 1.739 and 2.379(1) A. Treatment of 2 with 2-electron ligands L afforded the adducts [Cp*RuN(Ph2PS)2}L]
    用K [N(Ph2PS)2]处理[Cp * RuCl2] x(Cp * =η5-C5Me5),得到[Cp * Ru N(Ph2PS)2} Cl](1)。用Li [BEt3H]还原1得到16电子半三明治Ru(II)络合物[Cp * Ru N(Ph2PS)2}](2)。配合物1和2已经通过X射线晶体学表征。Ru–Cp *(质心)和1中的平均Ru–S距离分别为1.827和2.3833(5)A。2中相应的键距为1.739和2.379(1)A。用2电子配体L处理2得到加合物[Cp * Ru N(Ph2PS)2} L](L = CO(3),2, 6-Me2C6H4NC(4),MeCO2C CCO2Me(5))。用四甲基秋兰姆硫化物氧化2得到Ru(IV)络合物[Cp * Ru S2CNMe2} 2] [N(Ph2PS)2](6)。Ru–Cp *(质心)和6中的平均Ru–S距离分别为1.897和2
  • Synthesis, Structure and Optical Refractive Effect of Dibutyltin(IV) Complex of [Ph<sub>2</sub>P(S)NP(S)Ph<sub>2</sub>]<sup>−</sup>
    作者:Yunyin Niu、Yuxiao Wang、Yinglin Song、Shixiong Liu、Hegen Zheng、Xinquan Xin
    DOI:10.1246/cl.2001.1004
    日期:2001.10
    Reaction of n-Bu2SnCl2 with K[Ph2P(S)NP(S)Ph2] in CH3CN gives the spirobimetallocyclic complex bis(tetraphenyldithioimidodiphosphinato)dibutyltin (IV), n-Bu2Sn[Ph2P(S)NP(S)Ph2]2} in which π–π stacking interactions by the phenyl rings of the ligands exist. The nonlinear optical (NLO) properties were studied with an 8 ns-pulsed laser at 532 nm. Its optical responses to the incident light exhibit strong refractive effect with n2 = 5.4 × 10−18 m2 W−1 in a 1.2 × 10−4 mol dm−3 DMF solution.
    在CH3CN中,n-Bu2SnCl2与K[Ph2P(S)NP(S)Ph2]反应生成螺双属环状配合物双(四苯二咪唑烯)二丁基锡(IV),n-Bu2Sn[Ph2P(S)NP(S)Ph2]2},其中配体的苯环之间存在π-π堆积相互作用。利用8纳秒脉冲激光在532 nm处研究了其非线性光学(NLO)性质。其在1.2 × 10−4 mol dm−3 DMF溶液中对入射光的响应表现出强烈的折射效应,n2 = 5.4 × 10−18 m2 W−1。
  • Dichloro and alkylchloro gallium derivatives of dichalcogenoimidodiphosphinate ligands: isolation of a spirogallium cation
    作者:Miguel-Ángel Muñoz-Hernández、Virginia Montiel-Palma、Estefanía Huitrón-Rattinger、Sara Cortés-Llamas、Norma Tiempos-Flores、Jean-Michel Grevy、Cristian Silvestru、Philip Power
    DOI:10.1039/b412874e
    日期:——
    Dichloro and chloromethyl Ga(III) complexes of general formulae [XClGa-η2-R2P(E)NP(E′)R′2-E,E′}] (X = Cl, R, R′ = Ph, E, E′ = O (1), S (2), Se (3); R = Ph, R′ = OEt, E = O, E′ = S (4); R = Me, R′ = Ph, E, E′ = S (5) and X = Me, E, E′ = O (6), S (7), Se (8)) were synthesised by either metathesis reactions between GaCl3 and the potassium salt of the ligand (X = Cl) or by methane eliminations from in situ prepared GaMe2Cl and the protonated ligands LH (X = Me). Redistribution reaction of 3 in either CDCl3 or THF afforded the solvent-free tetracoordinate gallium spirocycle cation [Ga-η2-Ph2P(Se)NP(Se)Ph2-Se,Se′})2]+ (9+). The molecular structures of complexes 2, 4, 5, 7 and 9+ show non-planar gallacycle rings.
    甲基Ga(III)配合物,通式为[XClGa-η2-R2P(E)NP(E′)R′2-E,E′}] (X = Cl, R, R′ = Ph, E, E′ = O (1), S (2), Se (3); R = Ph, R′ =OEt, E = O, E′ = S (4); R = Me, R′ = Ph, E, E′ = S (5) 和 X = Me, E, E′ = O (6), S (7), Se (8)),通过GaCl3与配体盐的复分解反应(X = Cl)或从原位制备的GaMe2Cl与质子化配体LH的甲烷消除反应(X = Me)合成。3的再分配反应在CDCl3或THF中进行,形成了不含溶剂的四配位螺环阳离子[Ga-η2-Ph2P(Se)NP(Se)Ph2-Se,Se′})2]+ (9+)。配合物2, 4, 5, 7和9+的分子结构显示非平面环。
  • Coordination chemistry of the tetraphenyldithioimidodiphosphinate ligand [Ph2P(S)NP(S)Ph2]− and Ph2P(CH2)nPPh2, n = 1, 2, 3 toward ReBr(CO)5
    作者:María Obdulia Sánchez-Guadarrama、David Martínez-Velázquez、Noé Zúñiga-Villarreal
    DOI:10.1016/j.ica.2018.12.024
    日期:2019.3
    coordination chemistry of diphosphines dppe, dppm, and dppp towards [Re(CO)4κ2-S,S′-Ph2P(S)NP(S)Ph2}] was explored. The four types of new complexes prepared depicted monocoordination of the diphosphine or the Ph2P(S)NP(S)Ph2 ligands, bridging diphosphine ligands, and dicoordination to afford the spiro complexes. Characterizations were achieved by IR, mass, NMR (1H, 13C, 31P) spectroscopies, and single-crystal
    摘要探讨了二膦类化合物dppe,dppm和dppp对[Re(CO)4 κ2-S,S'-Ph2P(S)NP(S)Ph2}]的配位化学。制备的四种新型复合物描述了二膦或Ph2P(S)NP(S)Ph2配体的单配位,桥接二膦配体和二配位以提供螺环配合物。通过IR,质谱,NMR(1H,13C,31P)光谱学和单晶X射线衍射进行表征。
查看更多

同类化合物

(βS)-β-氨基-4-(4-羟基苯氧基)-3,5-二碘苯甲丙醇 (S,S)-邻甲苯基-DIPAMP (S)-(-)-7'-〔4(S)-(苄基)恶唑-2-基]-7-二(3,5-二-叔丁基苯基)膦基-2,2',3,3'-四氢-1,1-螺二氢茚 (S)-盐酸沙丁胺醇 (S)-3-(叔丁基)-4-(2,6-二甲氧基苯基)-2,3-二氢苯并[d][1,3]氧磷杂环戊二烯 (S)-2,2'-双[双(3,5-三氟甲基苯基)膦基]-4,4',6,6'-四甲氧基联苯 (S)-1-[3,5-双(三氟甲基)苯基]-3-[1-(二甲基氨基)-3-甲基丁烷-2-基]硫脲 (R)富马酸托特罗定 (R)-(-)-盐酸尼古地平 (R)-(-)-4,12-双(二苯基膦基)[2.2]对环芳烷(1,5环辛二烯)铑(I)四氟硼酸盐 (R)-(+)-7-双(3,5-二叔丁基苯基)膦基7''-[((6-甲基吡啶-2-基甲基)氨基]-2,2'',3,3''-四氢-1,1''-螺双茚满 (R)-(+)-7-双(3,5-二叔丁基苯基)膦基7''-[(4-叔丁基吡啶-2-基甲基)氨基]-2,2'',3,3''-四氢-1,1''-螺双茚满 (R)-(+)-7-双(3,5-二叔丁基苯基)膦基7''-[(3-甲基吡啶-2-基甲基)氨基]-2,2'',3,3''-四氢-1,1''-螺双茚满 (R)-(+)-4,7-双(3,5-二-叔丁基苯基)膦基-7“-[(吡啶-2-基甲基)氨基]-2,2”,3,3'-四氢1,1'-螺二茚满 (R)-3-(叔丁基)-4-(2,6-二苯氧基苯基)-2,3-二氢苯并[d][1,3]氧杂磷杂环戊烯 (R)-2-[((二苯基膦基)甲基]吡咯烷 (R)-1-[3,5-双(三氟甲基)苯基]-3-[1-(二甲基氨基)-3-甲基丁烷-2-基]硫脲 (N-(4-甲氧基苯基)-N-甲基-3-(1-哌啶基)丙-2-烯酰胺) (5-溴-2-羟基苯基)-4-氯苯甲酮 (5-溴-2-氯苯基)(4-羟基苯基)甲酮 (5-氧代-3-苯基-2,5-二氢-1,2,3,4-oxatriazol-3-鎓) (4S,5R)-4-甲基-5-苯基-1,2,3-氧代噻唑烷-2,2-二氧化物-3-羧酸叔丁酯 (4S,4''S)-2,2''-亚环戊基双[4,5-二氢-4-(苯甲基)恶唑] (4-溴苯基)-[2-氟-4-[6-[甲基(丙-2-烯基)氨基]己氧基]苯基]甲酮 (4-丁氧基苯甲基)三苯基溴化磷 (3aR,8aR)-(-)-4,4,8,8-四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧戊环[4,5-e]二恶唑磷 (3aR,6aS)-5-氧代六氢环戊基[c]吡咯-2(1H)-羧酸酯 (2Z)-3-[[(4-氯苯基)氨基]-2-氰基丙烯酸乙酯 (2S,3S,5S)-5-(叔丁氧基甲酰氨基)-2-(N-5-噻唑基-甲氧羰基)氨基-1,6-二苯基-3-羟基己烷 (2S,2''S,3S,3''S)-3,3''-二叔丁基-4,4''-双(2,6-二甲氧基苯基)-2,2'',3,3''-四氢-2,2''-联苯并[d][1,3]氧杂磷杂戊环 (2S)-(-)-2-{[[[[3,5-双(氟代甲基)苯基]氨基]硫代甲基]氨基}-N-(二苯基甲基)-N,3,3-三甲基丁酰胺 (2S)-2-[[[[[((1S,2S)-2-氨基环己基]氨基]硫代甲基]氨基]-N-(二苯甲基)-N,3,3-三甲基丁酰胺 (2S)-2-[[[[[[((1R,2R)-2-氨基环己基]氨基]硫代甲基]氨基]-N-(二苯甲基)-N,3,3-三甲基丁酰胺 (2-硝基苯基)磷酸三酰胺 (2,6-二氯苯基)乙酰氯 (2,3-二甲氧基-5-甲基苯基)硼酸 (1S,2S,3S,5S)-5-叠氮基-3-(苯基甲氧基)-2-[(苯基甲氧基)甲基]环戊醇 (1S,2S,3R,5R)-2-(苄氧基)甲基-6-氧杂双环[3.1.0]己-3-醇 (1-(4-氟苯基)环丙基)甲胺盐酸盐 (1-(3-溴苯基)环丁基)甲胺盐酸盐 (1-(2-氯苯基)环丁基)甲胺盐酸盐 (1-(2-氟苯基)环丙基)甲胺盐酸盐 (1-(2,6-二氟苯基)环丙基)甲胺盐酸盐 (-)-去甲基西布曲明 龙蒿油 龙胆酸钠 龙胆酸叔丁酯 龙胆酸 龙胆紫-d6 龙胆紫