Beiträge zur chemie des iodpentafluorids. Teil I. Iod(V)-verbindungen mit monofunktionellen alkoholaten
作者:Herman Josef Frohn、Wolfgang Pahlmann
DOI:10.1016/s0022-1139(00)85206-9
日期:1984.2
The behavior of iodine pentafluoride towards nucleophilic exchange of fluoride against monofunctional alcoholates in aprotic media is investigated using silylated methanol, isopropanol, tertiary butanol, phenol, alkylated phenol, and pentachlorophenol as educts. 19F-NMR-spectroscopic and preparative details are given for iodine(V)-fluoride- methanolates and fluoride-oxides. Dismutation, elimination