N-[4-[[3,5-diethyl-4-(pyridin-2-ylmethylideneamino)phenyl]methyl]-2,6-diethylphenyl]-1-pyridin-2-ylmethanimine | 790224-89-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[4-[[3,5-diethyl-4-(pyridin-2-ylmethylideneamino)phenyl]methyl]-2,6-diethylphenyl]-1-pyridin-2-ylmethanimine
• CAS: 790224-89-4
• 化学式: C₃₃H₃₆N₄
• 分子量: 488.676
• InChiKey: WKPVZPWLOHWQMN-UHFFFAOYSA-N

物化性质

• 沸点：
  695.7±55.0 °C(Predicted)
• 密度：
  1.05±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  37
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  50.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-[4-[[3,5-diethyl-4-(pyridin-2-ylmethylideneamino)phenyl]methyl]-2,6-diethylphenyl]-1-pyridin-2-ylmethanimine 、 tetrakis(actonitrile)copper(I) hexafluorophosphate 以 甲醇 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  [EN] SUPRAMOLECULAR COMPOUNDS AND THEIR USE AS ANTITUMOUR AND ANTIVIRAL AGENTS
  [FR] COMPOSES SUPRAMOLECULAIRES ET LEUR UTILISATION EN TANT QU'AGENTS ANTITUMORAUX ET ANTIVIRAUX

  摘要：

  该申请披露了超分子化合物作为抗肿瘤、抗微生物（如抗菌和抗原虫）和抗病毒剂的用途。这些化合物包括在申请中定义的配体，配体与至少两个金属离子配位。此外还披露了药物配方和洗涤剂配方。

  公开号：

  WO2005033119A1

文献信息

• Bridged bis-pyridinylimino dinickel(II) complexes: Syntheses, characterization, ethylene oligomerization and polymerization
  作者：Suyun Jie、Dongheng Zhang、Tianzhu Zhang、Wen-Hua Sun、Jiutong Chen、Qing Ren、Dongbing Liu、Gang Zheng、Wei Chen

  DOI：10.1016/j.jorganchem.2005.01.029

  日期：2005.3

  A series of bridged bis(pyridinylimino) ligands were efficiently synthesized through the condensation reaction of 4,4'-methylenebis(2,6-disubstituted aniline) with 2-pyridinecarboxaldehyde or 2-benzoylpyridine. They reacted with (DME)NiBr(2) to form dinuclear Ni(II) complexes. All resultant compounds were characterized by elemental analysis, IR spectra as well as the single-crystal X-ray diffraction to confirm the structures of ligands and complexes. Activated with methylaluminoxane (MAO), these nickel complexes showed considerably good activities for ethylene oligomerization and polymerization. Their catalytic activities and the properties of PEs obtained were depended on the arched environment of ligand and reaction conditions. (c) 2005 Elsevier B.V. All rights reserved.