N-(4-tert-butylbenzyl)-4-chloropyridinium bromide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(4-tert-butylbenzyl)-4-chloropyridinium bromide
• 英文别名: 1-[(4-Tert-butylphenyl)methyl]-4-chloropyridin-1-ium;bromide
• 化学式: Br*C₁₆H₁₉ClN
• 分子量: 340.691
• InChiKey: MGVOECKVYSKCTF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.98
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  3.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-二甲氨基吡啶 、 N-(4-tert-butylbenzyl)-4-chloropyridinium bromide 以 乙腈 为溶剂， 反应 0.17h， 以59.6%的产率得到4-dimethylamino-1'-(4-tert-butylbenzyl)-1,4'-bipyridinium bromide chloride
  参考文献：
  名称：

  Terminal defined chain-growth polycondensation of 4-chloropyridine

  摘要：

  This work examines the polycondensation of 4-chloropyridine derivatives using an N-(4-tert-butylbenzyl)-4-chloropyridinium (BPymCl) initiator and ion exchange reagents NaBPh4, NaBF4, and TBABF(4). The H-1 NMR spectra demonstrate that the product quantity is proportional to the total conversion of the monomer and the initiator. The MALDI-TOF MS spectrum shows that the product contains more than 9 monomer units. The polymerization was well-terminated via the addition of dimethylaminopyridine. These results indicate that the polycondensation proceeds in a chain-growth manner. This polycondensation could be a new example of a controlled polymerization with a well-defined end group. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2014.05.052
• 作为产物：
  描述：

  4-氯吡啶 、 4-叔丁基苄溴 反应 0.5h， 以84.4%的产率得到N-(4-tert-butylbenzyl)-4-chloropyridinium bromide
  参考文献：
  名称：

  Terminal defined chain-growth polycondensation of 4-chloropyridine

  摘要：

  This work examines the polycondensation of 4-chloropyridine derivatives using an N-(4-tert-butylbenzyl)-4-chloropyridinium (BPymCl) initiator and ion exchange reagents NaBPh4, NaBF4, and TBABF(4). The H-1 NMR spectra demonstrate that the product quantity is proportional to the total conversion of the monomer and the initiator. The MALDI-TOF MS spectrum shows that the product contains more than 9 monomer units. The polymerization was well-terminated via the addition of dimethylaminopyridine. These results indicate that the polycondensation proceeds in a chain-growth manner. This polycondensation could be a new example of a controlled polymerization with a well-defined end group. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2014.05.052

文献信息

• PROCESS FOR PRODUCING POLYPYRIDINIUM
  申请人：Japan Science and Technology Agency

  公开号：EP1754738A1

  公开（公告）日：2007-02-21

  A production method for polypyridinium having a narrow molecular weight distribution and a desired molecular weight is provided. Polypyridinium 3 having a narrow molecular weight distribution and a desired molecular weight is synthesized by allowing a pyridine derivative monomer 2 to polymerize on a polymerization initiator 1 such as a specially designed 4-halopyridinium and the like in the presence of a dissolution accelerating agent, such as tetrabutyl ammonium tetrafluoroborate, that dissolves the polymer formed in a solvent as in the chemical below. where Y represents an anion that dissolves in an organic solvent, X and Z represent halogen atoms, R represents hydrocarbon groups and the like and o is about 1 to 300.

  本发明提供了一种具有窄分子量分布和所需分子量的聚吡啶鎓的生产方法。 具有窄分子量分布和所需分子量的聚吡啶鎓 3 是通过让吡啶衍生物单体 2 在聚合引发剂 1（如专门设计的 4-卤代吡啶鎓等）上聚合，并在溶解加速剂（如四氟硼酸四丁基铵）的存在下合成的，溶解加速剂可将所形成的聚合物溶解在溶剂中，如下化学式所示。 其中 Y 代表能溶于有机溶剂的阴离子，X 和 Z 代表卤素原子，R 代表烃基等，o 约为 1 至 300。
• Method for Producing Polypyridinium
  申请人：Iyoda Tomokazu

  公开号：US20080132676A1

  公开（公告）日：2008-06-05

  A production method for polypyridinium having a narrow molecular weight distribution and a desired molecular weight is provided. Polypyridinium 3 having a narrow molecular weight distribution and a desired molecular weight is synthesized by allowing a pyridine derivative monomer 2 to polymerize on a polymerization initiator 1 such as a specially designed 4-halopyridinium and the like in the presence of a dissolution accelerating agent, such as tetrabutyl ammonium tetrafluoroborate, that dissolves the polymer formed in a solvent as in the chemical below. where Y represents an anion that dissolves in an organic solvent, X and Z represent halogen atoms, R represents hydrocarbon groups and the like and o is about 1 to 300.
• US7985829B2
  申请人：——

  公开号：US7985829B2

  公开（公告）日：2011-07-26