三(甲硫基)膦 | 816-80-8

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 中文名称: 三(甲硫基)膦
• 英文名称: trithiophosphorous acid trimethyl ester
• 英文别名: Trimethyl-trithiophosphit；trimethyl trithiophosphite；trimethyl phosphorotrithioite；Tris-(methylmercapto)-phosphin；Trimethylthiophosphit；Phosphorotrithious acid, trimethyl ester；tris(methylsulfanyl)phosphane
• CAS: 816-80-8
• 化学式: C₃H₉PS₃
• 分子量: 172.276
• InChiKey: FVTIMWPYAZCZQB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险类别码：
  R24/25
• 危险品运输编号：
  UN3278 6.1/PG 3

反应信息

• 作为反应物：
  描述：

  三(甲硫基)膦 在 三溴化磷 作用下， 反应 3.0h， 以42%的产率得到methyl thiodibromophosphite
  参考文献：
  名称：

  Molecular structure of methyl thiodichlorophosphite and methyl thiodibromophosphite

  摘要：

  DOI：

  10.1007/bf00749333
• 作为产物：
  描述：

  二甲基二硫 在 1-庚烯 、 磷化氢 作用下， 生成 三(甲硫基)膦
  参考文献：
  名称：

  Preparation of trialkyl trithiophosphites

  摘要：

  公开号：

  US02768194A1

文献信息

• Reactions of tetraphosphorus trisulphide with organic disulphides under ultraviolet irradiation, and with sulphuryl chloride
  作者：Faleh H. Musa、Bruce W. Tattershall

  DOI：10.1039/dt9840001517

  日期：——

  P4S3 under glass-filtered u.v. irradiation is rapidly cleaved by alkyl and aryl disulphides to give tetrathiophosphate esters, SP(SR)3, and trithiophosphite esters, P(SR)3(R = Me or Ph), in quantitative yield, as measured in the product mixture by 31P and 1H n.m.r. spectroscopy. No sulphurisation of P4S3 was found. In a competition reaction, MeSSMe and PhSSPh reacted to a similar extent with P4S3 to

  玻璃过滤的uv辐射下的P 4 S 3被烷基和芳基二硫化物快速裂解，得到定量的四硫代磷酸酯SP（SR）3和三硫代亚磷酸酯P（SR）3（R = Me或Ph），通过31 P和1 H nmr光谱在产物混合物中测得。没有发现P 4 S 3的硫化。在竞争反应中，MeSSMe和PhSSPh与P 4 S 3反应的程度相似，从而给出所有八种可能的乘积S x P（SPh）n（SMe）3 – n（x = 0或1，n = 0–3）在每个氧化态内的相对数量接近配体的统计分布，但是磷（V）产物有更多的MeS取代，磷（III）产物有更多的PhS取代。MeSSPh与P 4 S 3的反应给出了相似的结果。配体的再分配发生时P（SME）的混合物3和P（SPH）3被光解，和P（SME）的混合物的光解3和MeSSPh引起三硫代亚磷酸酯和二硫位点之间要被分发的PHS基。P（SMe）3和P（SPh）3分别没有被MeSSMe和PhSS
• Sinyashin, O. G.; Gorshunov, I. Yu.; Batyeva, E. S., Journal of general chemistry of the USSR, 1985, vol. 55, p. 1951 - 1955
  作者：Sinyashin, O. G.、Gorshunov, I. Yu.、Batyeva, E. S.、Pudovik, A. N.

  DOI：——

  日期：——
• The preparation, properties and X-ray structures of gold(I) trithiophosphite complexes
  作者：Christoph E. Strasser、Stephanie Cronje、Hubert Schmidbaur、Helgard G. Raubenheimer

  DOI：10.1016/j.jorganchem.2006.07.034

  日期：2006.11

  The first gold(I) trithiophosphite complexes were synthesised and fully characterised. Reaction of (tht)AuX (X = Cl, C6F5; tht = tetrahydrothiophene) with trithiophosphites (RS)(3)P (R = Me, Ph) and the bicyclic [(SCH2CH2S)PSCH2](2) (L-2) afforded the corresponding molecular complexes (RS)(3)PAuX [R = Me, X = Cl (1); R = Me, X = C6F5 (2); R = Ph, X = Cl (3); R = Ph, X = C6F5 (4)], and L-2(AuX)(2) [X = Cl (5), X = C6F5 (6)]. Reacting (tht)AuCl consecutively with two mole equivalents of (MeS)(3)P and then AgOTf, gave the ionic compound [(MeS)(3)P](2)Au}OTf (7). The compounds were characterised by multinuclear NMR spectroscopy, IR measurements and mass spectrometry, and the crystal and molecular structures of 1, 3, 6, two polymorphs of 2 as well as the known (MeO)(3)PAuCl (8) were determined by X-ray diffraction. The halide complexes 1 and 8 are isostructural and exhibit infinite chains of "crossed-sword"-type aurophilic interactions with Au center dot center dot center dot Au contact distances of 3.2942(3) and 3.1635(4) angstrom, respectively. Complex 6 exhibits a long Au center dot center dot center dot Au contact of 3.4671(9) angstrom. Au center dot center dot center dot S interactions between 3.3455(7) and 3.520(2) angstrom are present in the structures of 1 and one polymorph of 2. (c) 2006 Elsevier B.V. All rights reserved.
• Sinyashin, O. G.; Karimullin, Sh. A.; Pudovik, D. A., Journal of general chemistry of the USSR, 1984, vol. 54, # 11, p. 2195 - 2199
  作者：Sinyashin, O. G.、Karimullin, Sh. A.、Pudovik, D. A.、Batyeva, E. S.、Pudovik, A. N.

  DOI：——

  日期：——
• SINYASHIN, O. G.;GORSHUNOV, I. YU.;BATYEVA, EH. S.;PUDOVIK, A. N., ZH. OBSHCH. XIMII, 1985, 55, N 10, 2198-2203
  作者：SINYASHIN, O. G.、GORSHUNOV, I. YU.、BATYEVA, EH. S.、PUDOVIK, A. N.

  DOI：——

  日期：——