1,4,5,8-萘四醇 | 5690-27-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1,4,5,8-萘四醇
• 英文名称: 1,4,5,8-Tetrahydroxynaphthalene
• 英文别名: 1,4,5,8-Naphthalenetetrol；naphthazarin hydroquinone；naphthazarin；naphthalene-1,4,5,8-tetraol；Naphthalin-1,4,5,8-tetraol；1.4.5.8-Tetrahydroxy-naphthalin；naphthalene-1,4,5,8-tetrol
• CAS: 5690-27-7
• 化学式: C₁₀H₈O₄
• 分子量: 192.171
• InChiKey: OVALYCIUDYJCCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4,5,8-萘四醇 在 三氯化铝 、 溶剂黄146 、 sodium chloride 作用下， 生成 1,4,6,11-tetrahydroxy-naphthacene-5,12-dione
  参考文献：
  名称：

  Zahn; Ochwat, Justus Liebigs Annalen der Chemie, 1928, vol. 462, p. 88

  摘要：

  DOI：
• 作为产物：
  描述：

  5,8-diacetoxy-2,3-dihydro-[1,4]naphthoquinone 在 哌啶 作用下， 生成 1,4,5,8-萘四醇
  参考文献：
  名称：

  Zahn; Ochwat, Justus Liebigs Annalen der Chemie, 1928, vol. 462, p. 88

  摘要：

  DOI：

文献信息

• ORGANIC ELECTROLUMINESCENT DEVICE AND BORIC ACID AND BORINIC ACID DERIVATIVES USED THEREIN
  申请人：Merck Patent GmbH

  公开号：US20150322091A1

  公开（公告）日：2015-11-12

  The present invention relates to the use of aromatic boronic acid or borinic acid derivatives in organic electronic devices, in particular electroluminescent devices.

  本发明涉及芳香硼酸或硼酸衍生物在有机电子器件中的应用，特别是电致发光器件。
• Total syntheses of (+)-nogarene and (+)-7,8-dihydronogarene
  作者：Motoji Kawasaki、Fuyuhiko Matsuda、Shiro Terashima

  DOI：10.1016/s0040-4039(00)84471-8

  日期：1986.1

  Total syntheses of the title compounds, the simplest and the hitherto unknown novel nogalamycin congeners, were first accomplished by elaborating the CDEF-ring system () from the methyl ketone () and subjecting to regioselective Diels-Alder reaction with the bistrimethylsilyl keteneacetal ().

  标题化合物的总合成是最简单的，迄今未知的新型Nogalamycin同源物，首先是通过从甲基酮（）制备CDEF环系统（）并使其与双三甲基甲硅烷基烯酮缩醛（）进行区域选择性Diels-Alder反应来完成的。
• NAPHTHOBISCHALCOGENADIAZOLE DERIVATIVE AND PRODUCTION METHOD THEREFOR
  申请人：OSAKA UNIVERSITY

  公开号：US20190337966A1

  公开（公告）日：2019-11-07

  In order to provide a naphthobischalcogenadiazole derivative that can be used as an intermediate for producing a naphthobischalcogenadiazole compound into which a fluorine atom has been introduced, the naphthobischalcogenadiazole derivative in accordance with an aspect of the present invention is represented by a formula (I): where each of A 1 and A 2 is independently an oxygen atom, a sulfur atom, a selenium atom, or a tellurium atom; and each of X 1 and X 2 is independently a hydrogen atom, a halogen atom, a boronic acid group, a boronic acid ester group, a boronic acid diaminonaphthalene amide group, an N-methyliminodiacetic acid boronate group, a trifluoroborate salt group, or a triolborate salt group.

  为了提供一种可用作生产引入氟原子的萘基双硫/硒/碲-二唑化合物的中间体的萘基双硫/硒/碲-二唑衍生物，本发明的一个方面提供的萘基双硫/硒/碲-二唑衍生物由式(I)表示：其中，A1和A2分别独立地为氧原子、硫原子、硒原子或碲原子；X1和X2分别独立地为氢原子、卤素原子、硼酸基、硼酸酯基、硼酸二氨基萘酰胺基、N-甲基亚乙二酸硼酸酯基、三氟硼酸盐基或三羟基硼酸盐基。
• Reduction of the naphthazarin molecule as studied by pulse radiolysis. Part 2.—Second one-electron step
  作者：Edward J. Land、Tulsi Mukherjee、A. John Swallow、J. Malcolm Bruce

  DOI：10.1039/f19837900405

  日期：——

  function of pH. E17 of the radicals is equal to E27 of the parent and is –15 mV. The two-electron reduction potential of naphthazarin is –62 mV at pH 7 and –351 mV at pH 0. The optical absorption spectra of 1,4,5,8-tetrahydroxynaphthalene prepared in different ionised forms by radiolysis and by chemical reduction have been determined. The redox data and the absorption spectra show that this compound has

  观察到由萘达那林单电子还原形成的自由基的歧化与pH在1-14范围内的函数关系。自由基最不容易在pH 8–9时歧化，在pH约为ca时稳定常数。8.5为0.4。将数据与萘他沙林的单电子还原电势相结合以获得自由基的单电子还原电势（即母体的第二单电子还原电势）随pH的变化。自由基的E 1 7等于E 2 7母端的电压为–15 mV。萘他林的双电子还原电位在pH 7时为–62 mV，在pH 0时为–351 mV。通过电离和化学还原以不同电离形式制备的1,4,5,8-四羟基萘的光吸收光谱已被测定。决心。氧化还原数据和吸收光谱表明，该化合物具有的p K a值为7.6和8.7，并且没有进一步的p K a值低于ca。14。
• Polymer scale preventive agent, polymerization vessel effective in
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US05399613A1

  公开（公告）日：1995-03-21

  A polymer scale preventive agent for use in polymerization of a monomer having an ethylenically unsaturated double bond, comprising a condensation product of: (A) an aromatic amine compound, and (B) an aromatic hydroxyl compound condensate. This agent is used for forming a coating on the inner wall, etc. of a polymerization vessel. Such a vessel is effective in preventing polymer scale deposition and useful in producing a polymer that shows very few fish eyes and good whiteness when formed into sheets or the like.

  一种聚合物防垢剂，用于具有乙烯基不饱和双键的单体的聚合反应，包括以下凝结产物：（A）芳香胺化合物和（B）芳香羟基化合物凝结物。该剂用于在聚合反应器的内壁等处形成涂层。这种反应器可以有效地防止聚合物结垢沉积，并在制成片材等时产生极少的鱼眼和良好的白度，因此非常有用。