5,5'-dihydroxy-4,4'-dimethoxy-7,7'-dimethyl-2,2'-binaphthylidene-1,1'-quinone | 60548-89-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 5,5'-dihydroxy-4,4'-dimethoxy-7,7'-dimethyl-2,2'-binaphthylidene-1,1'-quinone
• 英文别名: 5,5'-Dihydroxy-4,4'-dimethoxy-7,7'-dimethyl-2,2'-binaphthyliden-1,1'dion；diosindigo B；(2E)-5-hydroxy-2-(5-hydroxy-4-methoxy-7-methyl-1-oxonaphthalen-2-ylidene)-4-methoxy-7-methylnaphthalen-1-one
• CAS: 60548-89-2
• 化学式: C₂₄H₂₀O₆
• 分子量: 404.419
• InChiKey: HVSMANGMDQFHLH-BUHFOSPRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5,5'-dihydroxy-4,4'-dimethoxy-7,7'-dimethyl-2,2'-binaphthylidene-1,1'-quinone 在 硝酸 作用下， 以92%的产率得到5,5'-二羟基-7,7'-二甲基-2,2'-联萘-1,1',4,4'-四酮
  参考文献：
  名称：

  Laatsch, Hartmut, Liebigs Annalen der Chemie, 1980, # 8, p. 1321 - 1347

  摘要：

  DOI：
• 作为产物：
  描述：

  4-氯-3-甲基苯酚 在 10% palladium on active carbon 盐酸 、 sodium hydroxide 、 三氯化铝 、 sodium dithionite 、 水 、 氢气 、 sodium acetate 、 potassium carbonate 、 potassium iodide 、 sodium chloride 、 silver(l) oxide 、 锌 作用下， 以 1,4-二氧六环 、 吡啶 、 甲醇 、 乙醚 、 氯仿 、 水 为溶剂， 反应 39.33h， 生成 5,5'-dihydroxy-4,4'-dimethoxy-7,7'-dimethyl-2,2'-binaphthylidene-1,1'-quinone
  参考文献：
  名称：

  Laatsch, Hartmut, Liebigs Annalen der Chemie, 1980, # 8, p. 1321 - 1347

  摘要：

  DOI：

文献信息

• Oxidative coupling of methoxynaphthylenediols
  作者：Bhim C. Maiti、Oliver C. Musgrave、Douglas Skoyles

  DOI：10.1016/j.tet.2005.04.058

  日期：2005.7

  5-naphthylenediol using lead(IV) oxide gives the symmetrical bisnaphthalene indigos diosindigo A and diosindigo B together with the corresponding unsymmetrical isomer. Oxidation of the first two by nitric acid gives the binaphthyldiquinones mamegakinone and biramentaceone, respectively; the third gives the unsymmetrical diquinone rotundiquinone. Similar oxidations of related naphthylenediols are described.

  使用氧化铅（IV）氧化1-甲氧基-7-甲基-4,5-萘二醇和4-甲氧基-7-甲基-1,5-萘二醇的混合物，得到对称的双萘靛蓝靛蓝A和靛蓝B以及相应的不对称异构体。前两个被硝酸氧化，分别得到双萘基二醌类马格基酮和双歧ra酮；第三个给出了不对称的对苯二酚罗通二醌。描述了相关萘二醇的类似氧化。
• A pentacyclic quinone diosindigo B from the heartwood of Diospyros melanoxylon
  作者：Akella V.B. Sankaram、Vaddu V. Narayana Reddy、Gurbachan S. Sidhu

  DOI：10.1016/0031-9422(81)83034-8

  日期：1981.1

  Abstract Diosindigo A, diosindigo B and biramentaceone have been isolated from heartwood of Diospyros melanoxylon . A violet pigment isolated from the same source has been shown to be a new pentacyclic quinone. Sunlight causes diosindigo B to change to the pentacyclic quinone and biramentaceone. The intense peaks at m/e 389 and 388 in the mass spectrum of diosindigo B are doublets which arise by fragmentation

  摘要 从Diospyros melanoxylon 的心材中分离得到薯蓣A、薯蓣B 和biramentaceone。从同一来源分离的紫罗兰色素已被证明是一种新的五环醌。阳光导致diosindigo B 变成五环醌和biramentaceone。diosindigo B 质谱中 m/e 389 和 388 处的强峰是双峰，由 M + 和 M + + 2 裂解产生。
• Maiti, Bhim C; Musgrave, Oliver C., Journal of the Chemical Society. Perkin transactions I, 1986, p. 675 - 682
  作者：Maiti, Bhim C、Musgrave, Oliver C.

  DOI：——

  日期：——
• COMPOSITION COMPRISING A HYDROPHOBIC DYE, A PARTICULAR ORGANIC AND/OR MINERAL ALKALINE AGENT, A PARTICULAR COMPOUND (I) AND A PARTICULAR ORGANIC COMPOUND (II), AND DYEING USE THEREOF
  申请人：Lalleman Boris

  公开号：US20120204357A1

  公开（公告）日：2012-08-16

  Composition comprising a hydrophobic dye, a particular organic and/or mineral alkaline agent, a particular compound (I) and a particular organic compound (II), and dyeing use thereof. The present invention relates to a dye composition comprising one or more hydrophobic direct dyes with a log P of greater than or equal to 2, one or more organic alkaline agents, and/or one or more mineral alkaline agents chosen from carbonates, hydrogen carbonates, sodium hydroxide and potassium hydroxide, and mixtures thereof, one or more compounds (I) comprising in their structure a sequence: and one or more organic compounds (II) with a Hansen solubility parameter δH of less than or equal to 16 MPa 1/2 and with a molecular weight of less than 250 g/mol. The invention also relates to a dyeing process that consists in applying such a composition to keratin fibers.
• US8551188B2
  申请人：——

  公开号：US8551188B2

  公开（公告）日：2013-10-08