anilino radical | 2348-49-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: anilino radical
• 英文别名: Anilino-Radikal；aniline radical；Phenylamino
• CAS: 2348-49-4
• 化学式: C₆H₆N
• 分子量: 92.1203
• InChiKey: HSMPSHPWCOOUJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  phenylnitrene anion radical 在 六氟异丙醇 作用下， 以 gas 为溶剂， 生成 anilino radical
  参考文献：
  名称：

  Gas-phase generation of phenylnitrene anion radical - proton affinity and .DELTA.Hf.degree. of phN-.cntdot. and its clustering with ROH molecules

  摘要：

  DOI：

  10.1021/ja00412a011

文献信息

• The photochemically induced oxidation of aniline by hydroperoxides: An electron paramagnetic resonance study. Part II.
  作者：Loris Grossi

  DOI：10.1016/s0040-4020(01)85525-3

  日期：——

  The oxidation reaction of aniline by tertiary hydroperoxides, induced photochemically, was studied. The peculiar radical intermediates, nitroxides and peroxy radicals, involved in the reaction mechanism were detected and identified by EPR spectroscopy. The presence of these intermediates confirm that PhNO is the first product of the oxidation of aniline and the PhNH· radical as its precursor.

  研究了光化学诱导的叔氢过氧化物对苯胺的氧化反应。通过EPR光谱法检测并鉴定了参与反应机理的特殊自由基中间体，氮氧化物和过氧自由基。这些中间体的存在证实了PhNO是苯胺和PhNH·自由基作为其前体氧化的第一产物。
• Kinetic applications of electron paramagnetic resonance spectroscopy. 42. Some reactions of the bis(trifluoromethyl)aminoxyl radical
  作者：T. Doba、K. U. Ingold

  DOI：10.1021/ja00326a012

  日期：1984.7

  Determination des constantes de vitesse, dans des freons, de l'enlevement d'hydrogene par (CF 3 ) 2 NO . d'un certain nombre de substrats et de l'addition de ce radical a CH 2 =CCl 2

  Determination des constantes de vitesse, dans des freons, de l'enlevement d'hydrogene par (CF 3 ) 2 NO。d'un 某些 nombre de substrats et de l'addition de ce 自由基 a CH 2 =CCl 2
• High resolution electronic absorption spectra of aniline, anilino and silicon dioxide
  作者：Fuat Bayrakçeken、İpek Ş. Karaaslan

  DOI：10.1016/s1386-1425(03)00061-1

  日期：2003.10

  absorption spectra of aniline and anilino free radical have been recorded in the vapor phase at room temperature by flash photolysis technique, and subsequent reactions have been investigated by kinetic spectroscopy. It was possible to follow the kinetics of the anilino radical's decay which occurred predominantly by bimolecular recombination. Decay parameters of anilino free radical were measured from the absorption

  通过快速光解技术在室温下以气相记录了苯胺和苯胺基自由基的高分辨率电子吸收光谱，并通过动力学光谱研究了后续反应。可以追踪主要通过双分子重组发生的苯胺基自由基衰变的动力学。从吸收带测量苯胺基自由基的衰变参数。
• Hypovalent radicals. 13. Gas-phase nucleophilic reactivities of phenylnitrene (PhN^- •) and sulfur anion radicals (S^-•) at sp³ and carbonyl carbon
  作者：Richard N. McDonald、A. Kasem Chowdhury

  DOI：10.1021/ja00340a010

  日期：1983.1
• Gas-phase nucleophilic addition reactions of phenylnitrene anion radical with certain carbonyl-containing molecules
  作者：Richard N. McDonald、A. Kasem Chowdhury

  DOI：10.1021/ja00393a032

  日期：1981.2