2-methyl-6-sulfobenzoxazole | 6761-90-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶唑类
• 英文名称: 2-methyl-6-sulfobenzoxazole
• 英文别名: 6-Benzoxazolesulfonic acid, 2-methyl-；2-methyl-1,3-benzoxazole-6-sulfonic acid
• CAS: 6761-90-6
• 化学式: C₈H₇NO₄S
• 分子量: 213.214
• InChiKey: VXRHUDBMQAYGBE-UHFFFAOYSA-N

物化性质

• 熔点：
  283-285 °C
• 密度：
  1.538±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  88.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-methyl-6-sulfobenzoxazole 、 氢氧化钾 以 异丙醇 为溶剂， 生成 2-methyl-6-sulfobenzoxazole potassium salt
  参考文献：
  名称：

  WO2008/40994

  摘要：

  公开号：
• 作为产物：
  描述：

  2-甲基苯并唑 在 iron(III) chloride 、 硫酸 、 三氧化硫 作用下， 以 丙酮 为溶剂， 反应 2.0h， 生成 2-methyl-6-sulfobenzoxazole
  参考文献：
  名称：

  WO2008/40994

  摘要：

  公开号：

文献信息

• FLUORO-SUBSTITUTED BENZOXAZOLE POLYMETHINE DYES
  申请人：Said Najeeb

  公开号：US20100015054A1

  公开（公告）日：2010-01-21

  Disclosed are reactive polyfluoro benzoxazole polymethine dyes that are useful for labelling and detecting biological and other materials. The dyes are of formula (I): in which X is selected from the group consisting of —O—, —S— and at least one of groups R 1 and R 2 is the group -L-R x or -L-R p , where L is a linking group, R x is a group suitable for covalent attachment of the dye to a component and R p is a component; and at least one of groups R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and R 10 comprises fluorine. The use of polymethine dyes substituted by fluorine and having additional substitution by sulphonic acid groups, for labelling biological target molecules results in a labelled product in which there is reduced dye-dye aggregation and improved photostability, compared with cyanine dyes having no such substitutions.

  本发明涉及一种反应性聚氟苯并噁唑聚甲烷染料，用于标记和检测生物和其他材料。该染料的化学式为(I)：其中X选自—O—、—S—和至少一个R1和R2中的基团是-L-Rx或-L-Rp，其中L是连接基团，Rxis适合于染料与组分的共价连接的基团，Rp是组分；且R3、R4、R5、R6、R7、R8、R9和R10中的至少一个含有氟。使用由含有氟的聚甲烷染料取代并具有额外的磺酸基团取代的方法，用于标记生物靶分子，结果是标记的产物中染料-染料聚集减少，光稳定性得到改善，与没有这种取代的青霉素染料相比。
• Coloring composition, ink jet recording ink, ink jet recording method, and ink jet printer cartridge
  申请人：FUJIFILM Corporation

  公开号：US10703910B2

  公开（公告）日：2020-07-07

  Provided are a coloring composition including a compound represented by Formula (1) shown in this specification and a compound represented by Formula (D) shown in this specification, an ink jet recording ink including the coloring composition, an ink jet recording method using the ink jet recording ink, and an ink jet printer cartridge that is filled with the ink jet recording ink.

  提供了一种着色组合物（包括本说明书所示式 (1) 所代表的化合物和本说明书所示式 (D) 所代表的化合物）、一种喷墨记录墨水（包括该着色组合物）、一种使用该喷墨记录墨水的喷墨记录方法，以及一种装有该喷墨记录墨水的喷墨打印机墨盒。
• Ink composition, ink set and recording method
  申请人：Fujifilm Corporation

  公开号：EP1777273B1

  公开（公告）日：2008-09-10
• INK COMPOSITION, MANUFACTURING METHOD OF INK, INK SET, AND RECORDING METHOD
  申请人：Fujifilm Corporation

  公开号：EP1969071B1

  公开（公告）日：2013-07-03
• Ink composition and recording method using the same
  申请人：Arai Yoshimitsu

  公开号：US20070176991A1

  公开（公告）日：2007-08-02

  An ink composition which comprises a compound represented by formula (1), which is described in the specification; and a plurality of water-soluble organic solvents, wherein the water-soluble organic solvents contains at least a water-soluble organic solvent having a thioether or sulfoxide moiety in an amount of 10 mass % to 80 mass %, and a recording method which uses the ink composition.