sulfur deuteride | 13780-23-9

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属有机物
• 英文名称: sulfur deuteride
• 英文别名: thiodeuterium；d, sulfur；sulfur-d
• CAS: 13780-23-9
• 化学式: HS
• 分子量: 34.066
• InChiKey: PXQLVRUNWNTZOS-MICDWDOJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  1
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  sulfur deuteride 在 溴 作用下， 以 gas 为溶剂， 生成
  参考文献：
  名称：

  巯基与溴，氯化溴，氯和氟反应的动力学和机理

  摘要：

  Motivated by the need to improve the understanding of radical-molecule reactivity, the rate constants for the reactions of the SD radical with an interhalogen series (Br2, BrCl, Cl2, and F2) were measured as a function of temperature with a discharge-flow apparatus. The SD radical was monitored by a laser-induced fluorescence technique. The reactions were found to proceed by halogen atom abstraction with the following bimolecular rate constants (95% confidence level, in units of cm3 molecule-1 s-1): SD + Br2 --> BrSD + Br, k1 = (6.0 +/- 1.5) x 10(-11) exp[(160 +/- 100)/T] for 273 K < T < 373 K; SD + BrCl --> products, k2 = (2.3 +/- 0.3) x 10(-11) exp[(350 +/- 80)/T] for 298 K < T < 373 K; SD + BrCl --> ClSD + Br, k2b = (2.3 +/- 2) x 10(-11) exp[(100 +/- 200)/T] for 298 K < T < 373 K; SD + Cl2 --> ClSD + Cl, k3 = (1.7 +/- 0.4) x 10(-11) exp[(-690 +/- 90)/T] for 273 K < T < 373 K; SD + F2 --> FSD + F, k4 = (4.3 +/- 1.4) x 10(-11) exp[(-1390 +/- 100)/T] for 298 K < T < 373 K. We examine these results within the framework of a reactivity trend that correlates the room-temperature rate constants with the parameter (IP - EA), where IP and EA represent the ionization potential of the electron density donating reactant and the electron affinity of the electron density acceptor, respectively. It was found that the trend fails for these and other halogen atom abstraction reactions unless a correction for the effects of polarizability is included.

  DOI：

  10.1021/j100161a041
• 作为产物：
  描述：

  硫化氘 在 ArF 作用下， 生成 sulfur deuteride
  参考文献：
  名称：

  HS自由基的光谱学和反应动力学

  摘要：

  激光诱导荧光技术用于监测HS自由基浓度。已经确定了HS自由基与各​​种添加的清除剂的反应在室温下的速率常数。

  DOI：

  10.1016/0009-2614(81)85111-1

文献信息

• Excitation of OH- and SH-Band Systems in Fluorescence
  作者：P. J. DYNE、D. W. G. STYLE

  DOI：10.1038/167899a0

  日期：1951.6

  Dawsey, Urey and Rice1 claimed to have excited the OH-band 3064 A. in fluorescence in hydrogen peroxide vapour, the processes involved being: H2O2 + hν1 → HO + OH* OH* → OH + hν2. In these experiments, light from a zinc spark was passed through an acetone filter, which removed light of wave-lengths shorter than λ 2025, down a quartz tube containing hydrogen peroxide vapour and thence to the slit of

  Dawsey、Urey 和 Rice1 声称在过氧化氢蒸汽中激发了 OH 带 3064 A.的荧光，涉及的过程是：H2O2 + hν1 → HO + OH* OH* → OH + hν2。在这些实验中，来自锌火花的光通过丙酮滤光器，滤除波长短于 λ 2025 的光，沿着含有过氧化氢蒸气的石英管向下到达光谱仪的狭缝。OH 带在火花“背景”下显得微弱，该区域的强度被丙酮过滤器部分降低。没有给出曝光时间，可以假设火花在空气中运行。
• Two-photon resonance enhanced MPI-PES above the lowest ionization threshold. Observation of the [a1Δ]5pπ 2Φ state of the SH (SD) radical
  作者：J.B. Milan、W.J. Buma、C.A. de Lange、C.M. Western、M.N.R. Ashfold

  DOI：10.1016/0009-2614(95)00488-p

  日期：1995.6

  A (2 + 1) resonance enhanced multiphoton ionization photoelectron spectroscopy (REMPI-PES) study of the hitherto unobserved Rydberg state of the SH (SD) radical is reported. Despite the fact that this state has an excitation energy which exceeds the lowest ionization energy, ionization is observed to occur preferentially by the absorption of a third photon after the two-photon excitation step, rather

  报道了迄今未观察到的SH（SD）自由基的Rydberg态的（2 +1）共振增强多光子电离光电子能谱（REMPI-PES）研究。尽管该状态具有超过最低电离能的激发能的事实，但是观察到电离优先通过在双光子激发步骤之后吸收第三光子而不是通过自电离而发生。光电子光谱在旋转支化比中显示出较大的不对称性，这归因于离子态的Λ +值较高。
• Rotational state dependence of transient linewidths in the CO2 0001 vibrational level due to translational energy recoil from hot H and D atom collisions
  作者：John F. Hershberger、James Z. Chou、George W. Flynn、Ralph E. Weston

  DOI：10.1016/0009-2614(88)80347-6

  日期：1988.8

  The nascent transient linewidths of the CO2 0001, J→0002, J−1 transitions were measured immediately following collisions with hot H and D atoms of 2.30 and 2.16 eV energy, respectively. All lineshapes were well fitted by Gaussian profiles, but were significantly broader than the room-temperature Doppler profiles. D atom collisions resulted in broader linewidths than H atom collisions. The observed

  在分别与2.30和2.16 eV能量的热H和D原子碰撞后，立即测量了CO 2 00 0 1，J →00 0 2，J -1跃迁的新生瞬态线宽。所有的线形都可以很好地拟合高斯剖面，但比室温多普勒剖面要宽得多。与H原子碰撞相比，D原子碰撞产生的线宽更宽。对于特定的旋转水平J，观察到的宽度与简单的台球模型非常吻合。但是，对于热的H和热的D原子碰撞，在00 0 1流形中观察到线宽随旋转状态的增加而增加。
• Isotope effects in reactions of trifluoromethyl radicals with hydrogen chloride and hydrogen sulphide
  作者：N. L. Arthur、Peter Gray

  DOI：10.1039/tf9696500434

  日期：——

  Rate constants, Arrhenius parameters and primary kinetic isotope effects have been measured for the reactions of trifluoromethyl radicals with H2S, D2S, HCl and DCl: [graphic omitted] Quotients of A-factors do not differ significantly from unity, but values for (ED–EH) are significantly less than the respective zero-point-energy differences ΔE0 of 1.1 kcal mole–1. The reactivity of CF3 radicals towards the two substances is markedly less than that of CH3 radicals; the differences reside in the higher activation energies and may be attributed to the polar character of CF3.

  测量了三氟甲基自由基与 H2S、D2S、HCl 和 DCl 反应的速率常数、阿伦尼乌斯参数和主要动力学同位素效应：[图略] A 系数之差与统一值相差不大，但 (ED-EH) 的值明显小于各自的零点能差 ΔE0 1.1 千卡摩尔-1。CF3 自由基对这两种物质的反应活性明显低于 CH3 自由基；差异在于活化能较高，这可能归因于 CF3 的极性。
• Two-photon laser-induced fluorescence studies of HS radicals, DS radicals, and I atoms
  作者：J.J. Tiee、M.J. Ferris、G.W. Loge、F.B. Wampler

  DOI：10.1016/0009-2614(83)80723-4

  日期：1983.4

  A two-photon laser-induced excitation and fluorescence technique has been used to study the A 2Σ+-X 2Π transition of HS and DS radicals and various high-lying 4Po, 2Do, and 4Do states of the I atom. The two-photon excitation cross sections and detection sensitivity are discussed.

  双光子激光诱导激发和荧光技术已用于研究阿2 Σ + -X 2 HS和DS自由基和各种高地势的Π过渡4 P ø，2 d ø，和4 d Ò的状态我原子。讨论了双光子激发截面和检测灵敏度。