2,6-diethylcyclohexylamine | 19962-50-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,6-diethylcyclohexylamine
• 英文别名: 2,6-Diethylcyclohexanamine；2,6-diethylcyclohexan-1-amine
• CAS: 19962-50-6
• 化学式: C₁₀H₂₁N
• 分子量: 155.283
• InChiKey: LRFRFHYTHMPJIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,6-diethylcyclohexylamine 、 钯 以96%的产率得到2,6-二乙基苯胺
  参考文献：
  名称：

  Preparation of aromatic amines

  摘要：

  芳香胺（苯胺）是通过在支撑钯催化剂上，利用苯酚与氨和氢气进行氨化/氢化反应直接或通过相应的环脂肪胺获得的，该催化剂还包含周期表1b、2b或7b族元素以及铁、钴或镍，或者以它们的化合物形式存在，并且最好还包含无机碱，这些催化剂还具有脱氢性能。

  公开号：

  US04429155A1

文献信息

• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• [EN] PHOSPHINYL FORMAMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS PHOSPHINYL FORMAMIDINE, COMPLEXES MÉTALLIQUES, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2015094207A1

  公开（公告）日：2015-06-25

  N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are described. Methods for making N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl formamidine metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds and N2- phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物。还公开了制备N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物的方法。还公开了利用N2-磷酰基甲酰胺金属盐配合物的催化剂体系，以及利用N2-磷酰基胺化合物和N2-磷酰基胺金属盐配合物进行烯烃的寡聚和/或聚合的用途。
• Branched amides of L-aspartyl-D-amino acid dipeptides
  申请人：Pfizer Inc.

  公开号：US04517379A1

  公开（公告）日：1985-05-14

  Amides of L-aspartyl-D-amino acid dipeptides of the formula ##STR1## and physiologically acceptable cationic and acid addition salts thereof wherein R.sup.a is CH.sub.2 OH or CH.sub.2 OCH.sub.3 ; R is a branched member selected from the group consisting of fenchyl, diisopropylcarbinyl, d-methyl-t-butylcarbinyl, d-ethyl-t-butylcarbinyl, di-t-butylcarbinyl, 2-methylthio-2,4-dimethylpentan-3-yl, ##STR2## where at least one of R.sup.3, F.sup.4, R.sup.5, R.sup.6 is alkyl having from one to four carbon atoms and the remainder are hydrogen or alkyl having from one to four carbon atoms, X is O, S, SO, SO.sub.2, C.dbd.O or CHOH; m is zero or 1-4, n and p are each zero, 1, 2 or 3 where the sum of n+p is not greater than 3 and the sum of the carbon atoms in R.sup.3, R.sup.4, R.sup.5 and R.sup.6 is not greater than six, and when both of R.sup.3 and R.sup.4 or R.sup.5 and R.sup.6 are alkyl they are methyl or ethyl, ##STR3## where one of R.sup.7, R.sup.8, R.sup.9 is alkyl having from one to four carbon atoms and the remainder are hydrogen or alkyl having from one to four carbon atoms and the sum of the carbon atoms in R.sup.7, R.sup.8 and R.sup.9 is not greater than six, m and q are the same or different and each have the values previously defined for m; ##STR4## where each of R.sup.12 and R.sup.13 are methyl or ethyl, or R.sup.12 is hydrogen and R.sup.13 is alkyl having from one to four carbon atoms, Z is O or NH and t is 1 or 2, ##STR5## where w is 1-4, R.sup.14 and R.sup.16 are each alkyl having from one to four carbon atoms, R.sup.15 is H, OH, methyl or ethyl and the sum of the carbon atoms in R.sup.14, R.sup.15 and R.sup.16 is not greater than six and when both of R.sup.14 and R.sup.15 are alkyl they are methyl or ethyl, and ##STR6## where R.sup.17 and R.sup.19 are alkyl having from one to four carbon atoms, R.sup.18 and R.sup.20 are H or alkyl having one to two carbon atoms, A is OH and B is H, OH or CH.sub.3 and taken together A and B are ##STR7## where the sum of the carbon atoms in R.sup.17, R.sup.18, R.sup.19 and R.sup.20 is not greater than six and when both of R.sup.17 and R.sup.18 or R.sup.19 and R.sup.20 are alkyl they are methyl or ethyl; said amides are potent sweeteners having advantages over the prior art, edible compositions containing them, methods for their use in edible compositions and novel amide intermediates useful in their production.

  L-天冬氨酸-D-氨基酸二肽的酰胺，其化学式为##STR1##以及其生理可接受的阳离子和酸性加成盐，其中R.sup.a是CH.sub.2 OH或CH.sub.2 OCH.sub.3; R是从羟基萜、二异丙基甲基、d-甲基-t-叔丁基甲基、d-乙基-t-叔丁基甲基、二-叔丁基甲基、2-甲硫基-2,4-二甲基戊烷-3-基，##STR2##其中R.sup.3、F.sup.4、R.sup.5、R.sup.6中至少有一个是1-4个碳原子的烷基，其余为氢或1-4个碳原子的烷基，X为O、S、SO、SO.sub.2、C.dbd.O或CHOH; m为0或1-4，n和p各自为0、1、2或3，其中n+p之和不大于3，R.sup.3、R.sup.4、R.sup.5和R.sup.6中碳原子的总和不大于6，当R.sup.3和R.sup.4或R.sup.5和R.sup.6都是烷基时，它们是甲基或乙基，##STR3##其中R.sup.7、R.sup.8、R.sup.9中的一个是1-4个碳原子的烷基，其余为氢或1-4个碳原子的烷基，R.sup.7、R.sup.8和R.sup.9中碳原子的总和不大于6，m和q相同或不同，其值与m的定义相同; ##STR4##其中R.sup.12和R.sup.13都是甲基或乙基，或R.sup.12是氢，R.sup.13是1-4个碳原子的烷基，Z为O或NH，t为1或2，##STR5##其中w为1-4，R.sup.14和R.sup.16都是1-4个碳原子的烷基，R.sup.15为H、OH、甲基或乙基，R.sup.14、R.sup.15和R.sup.16中碳原子的总和不大于6，当R.sup.14和R.sup.15都是烷基时，它们是甲基或乙基，以及##STR6##其中R.sup.17和R.sup.19是1-4个碳原子的烷基，R.sup.18和R.sup.20是氢或1-2个碳原子的烷基，A为OH，B为H、OH或CH.sub.3，且A和B在一起为##STR7##其中R.sup.17、R.sup.18、R.sup.19和R.sup.20中碳原子的总和不大于6，当R.sup.17和R.sup.18或R.sup.19和R.sup.20都是烷基时，它们是甲基或乙基; 这些酰胺是具有优于现有技术的优点的强效甜味剂，可食用组合物包含它们，在可食用组合物中使用它们的方法以及在它们的生产中有用的新型酰胺中间体。
• Substituierte N-Cyclohexyl-isothioharnstoffe, Verfahren zu ihrer Herstellung sowie ihre Verwendung als Mittel zur Bekämpfung von tierischen und pflanzlichen Schädlingen
  申请人：BAYER AG

  公开号：EP0003101A1

  公开（公告）日：1979-07-25

  Die vorliegende Erfindung betrifft neue substituierte N-Cyclohexyl-isothioharnstoffe, Verfahren zu ihrer Herstellung sowie ihre Verwendung als Mittel zur Bekämpfung von tierischen und pflanzlichen Schädlingen, insbesondere als Ektoparasitizide, Insektizide und Akarizide.

  本发明涉及新型取代的 N-环己基-异硫脲类化合物、其制备工艺及其作为控制动植物害虫的药剂的用途，特别是作为杀寄生虫剂、杀虫剂和杀螨剂的用途。
• Branched amides of L-aspartyl-D-amino acid dipeptides and compositions thereof
  申请人：PFIZER INC.

  公开号：EP0034876A2

  公开（公告）日：1981-09-02

  Amides of L-aspartyl-D-amino acid dipeptides of the formula and physiologically acceptable cationic and acid addition salts thereof wherein Ra is methyl, ethyl, n-propyl or isopropyl and R is a branched aliphatic, alicyclic or heterocyclic member which is branched at the alpha carbon atom (the carbon atom bearing the amide nitrogen atom) and also branched again at one or both of the beta carbon atoms, are potent sweeteners which are free from undesirable flavour qualities and of high stability in conventional food processing. Sweetening compositions and sweetened edible compositions of such amides are also claimed

  式中 L-天冬氨酰-D-氨基酸二肽的酰胺类 及其生理上可接受的阳离子盐和酸加成盐，其中 Ra 为甲基、乙基、正丙基或异丙基，R 为支链脂环族、脂环族或杂环族成员，该成员在 α 碳原子（含酰胺氮原子的碳原子）上有支链，在一个或两个β碳原子上也有支链。这种酰胺的甜味组合物和甜味可食用组合物也已申请专利。