tetrabutylammonium 4-vinylbenzenesulfonate | 151164-21-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrabutylammonium 4-vinylbenzenesulfonate
• 英文别名: 4-Ethenylbenzenesulfonate;tetrabutylazanium
• CAS: 151164-21-5
• 化学式: C₈H₇O₃S*C₁₆H₃₆N
• 分子量: 425.676
• InChiKey: IQLCKUDTYNJVFN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.24
• 重原子数：
  29
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  65.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  sodium p-styrenesulfonate 在 proton-exchange resin 作用下， 以 水 为溶剂， 反应 0.5h， 生成 tetrabutylammonium 4-vinylbenzenesulfonate
  参考文献：
  名称：

  Synthesis of high proton conducting nanoparticles by emulsion polymerization

  摘要：

  High ion-exchange capacity (IEC) sulfonated polystyrene nanoparticles were synthesized by an emulsion copolymerization of styrene, divinyl benzene and sulfonated styrene (SS). The effects of varying the counterion of the sulfonated styrene monomer, the SS concentration, the surfactant and the addition of a crosslinking agent on the ability to stabilize the emulsion nanoparticles to high IEC were studied. Water-insoluble nanoparticles, 20-160 nm in diameter, with IEC as high as 5.2 meq/g were achieved using sulfonated styrene with a quaternary alkyl ammonium cation, a non-ionic surfactant and a crosslinking agent in the emulsion formulation. That IEC corresponds to fully sulfonated crosslinked polystyrene. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2010.11.055

文献信息

• Synthesis of chiral iridium complexes immobilized on amphiphilic polymers and their application to asymmetric catalysis
  作者：Shinichi Itsuno、Yosuke Hashimoto、Naoki Haraguchi

  DOI：10.1002/pola.27351

  日期：2014.11.1

  successfully applied to asymmetric transfer hydrogenation of cyclic imines. Polymeric catalysts prepared from amphiphilic achiral monomers have high catalytic activity in the reaction and can be used both in organic solvents and water to give chiral cyclic amines with a high level of enantioselectivity (up to 98% ee). The asymmetric reaction allows for reuse of the heterogeneous catalyst without any loss

  本文详细介绍了交联的，聚合物固定的，基于Ir的手性配合物的对映选择性催化性能，用于将环亚胺氢化成手性胺。非手性乙烯基单体，二乙烯基苯和可聚合的手性1,2-二胺单磺酰胺配体的聚合，然后与[IrCl 2 Cp *] 2络合提供了交联的聚合物手性配合物，其可以成功地用于环状亚胺的不对称转移氢化。由两亲性非手性单体制备的聚合催化剂在反应中具有较高的催化活性，可用于有机溶剂和水中，以得到具有高对映选择性（最高98％ee）的手性环胺。不对称反应允许多相催化剂的再利用，而在几次运行中活性或对映选择性没有任何损失。©2014 Wiley Periodicals，Inc. J. Polym。科学，A部分：Polym。化学 2014，52，3037-3044
• A facile method for the preparation of poly(vinylidene fluoride) membranes filled with cross-linked sulfonated polystyrene
  作者：Naeun Kang、Junhwa Shin、Taek Sung Hwang、Youn-Sik Lee

  DOI：10.1016/j.reactfunctpolym.2015.12.006

  日期：2016.2

  poly(vinylidene fluoride) (PVDF) membranes were filled with tetrabutylammonium 4-vinylbenzene sulfonate (TVS), a cross-linking agent, and a radical initiator in dimethyl sulfoxide, followed by radical polymerization and subsequent replacement of tetrabutylammonium ions by protons. This pore-filling method using an organic-soluble sulfonate monomer was very efficient and convenient, as it avoids the highly acidic

  摘要用二乙烯基亚砜中的4-乙烯基苯磺酸四丁基铵，交联剂和自由基引发剂填充聚偏二氟乙烯（PVDF）膜的孔，然后进行自由基聚合，随后用质子取代四丁基铵离子。使用有机可溶性磺酸盐单体的这种孔填充方法非常有效和方便，因为它避免了高酸性的磺化步骤。填充有交联磺化聚苯乙烯的PVDF膜的长度尺寸变化与Nafion 212类似，但吸水率更高，并且机械模量和伸长率大大提高。在相同条件下，改性膜的质子电导率也高于Nafion 212。
• Process for the preparation of modified polybutylene terephthalate resin
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0678552A1

  公开（公告）日：1995-10-25

  The present invention provides a process for the preparation of a polyester from an acid component comprising terephthalic acid or a lower alcohol ester thereof as a main component and a diol component comprising 1,4-butanediol as a main component, wherein 0.001 to 0.5 mol % (based on the acid component) of a specific aromatic sulfonic acid compound is dissolved in the diol component or a mixture of the diol component with the acid component and thereafter a catalyst is added to the resulting reaction system to conduct esterification (or transesterification) and polycondensation successively, for the purpose of providing a modified polybutylene terephthalate resin which little generates gas such as tetrahydrofuran even in high-temperature service and little gives sublimate in melting.

  本发明提供了一种由包括对苯二甲酸或其低级醇酯作为主要成分的酸组分和包括 1,4-丁二醇作为主要成分的二元醇组分制备聚酯的工艺，其中 0.001 至 0.5 mol %（以酸组分为基准）的特定芳香族磺酸化合物溶解在二元醇组分或二元醇组分与酸组分的混合物中，然后向生成的反应体系中添加催化剂，以先后进行酯化（或酯交换）和缩聚反应，目的是提供一种改性聚对苯二甲酸丁二醇酯树脂，这种树脂即使在高温下使用也很少产生四氢呋喃等气体，在熔化时也很少产生亚硝酸盐。
• Synthesis of high proton conducting nanoparticles by emulsion polymerization
  作者：Emmanuel Pitia、M.T. Shaw、R.A. Weiss

  DOI：10.1016/j.polymer.2010.11.055

  日期：2011.1

  High ion-exchange capacity (IEC) sulfonated polystyrene nanoparticles were synthesized by an emulsion copolymerization of styrene, divinyl benzene and sulfonated styrene (SS). The effects of varying the counterion of the sulfonated styrene monomer, the SS concentration, the surfactant and the addition of a crosslinking agent on the ability to stabilize the emulsion nanoparticles to high IEC were studied. Water-insoluble nanoparticles, 20-160 nm in diameter, with IEC as high as 5.2 meq/g were achieved using sulfonated styrene with a quaternary alkyl ammonium cation, a non-ionic surfactant and a crosslinking agent in the emulsion formulation. That IEC corresponds to fully sulfonated crosslinked polystyrene. (C) 2010 Elsevier Ltd. All rights reserved.