1,1'-((2,3-bis(3,4-bis(octyloxy)phenyl)quinoxaline-6,7-diyl)bis(azanediyl))bis(dodec-1-en-3-one) | 1384190-24-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 1,1'-((2,3-bis(3,4-bis(octyloxy)phenyl)quinoxaline-6,7-diyl)bis(azanediyl))bis(dodec-1-en-3-one)
• CAS: 1384190-24-2
• 化学式: C₇₆H₁₂₀N₄O₆
• 分子量: 1185.81
• InChiKey: HDUDWNPVPHOPDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  23.19
• 重原子数：
  86.0
• 可旋转键数：
  56.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.66
• 拓扑面积：
  120.9
• 氢给体数：
  2.0
• 氢受体数：
  10.0

反应信息

• 作为产物：
  描述：

  1,2,4,5-benzenetetraamine tetrahydrochloride 在 sodium acetate 、 溶剂黄146 作用下， 以 乙醇 、 水 为溶剂， 反应 0.25h， 生成 1,1'-((2,3-bis(3,4-bis(octyloxy)phenyl)quinoxaline-6,7-diyl)bis(azanediyl))bis(dodec-1-en-3-one)
  参考文献：
  名称：

  Mesogenic Enaminoketone Ni(II) Complexes of Phenazine and Quinoxaline Derivatives

  摘要：

  The new Ni(II) metallomesogenes were synthesized. Their mesogenic cores are constructed from tetradental enaminoketone unit connected to 1,2: 3,4-di(4,5-dioctyloxybenzo) phenazine or 2,3-di(3,4-dioctyloxyphenylo) quinoxaline. The described compounds form columnar hexagonal phase (Col(hd)) in very broad temperature range. The high stability of the columnar phase results from presence of a permanent dipol moment in enaminoketone moieties created by strong electron withdrawing properties of carbonyl groups.

  DOI：

  10.1080/15421406.2011.653714

文献信息

• Mesogenic Enaminoketone Ni(II) Complexes of Phenazine and Quinoxaline Derivatives
  作者：Paulina Krzyczkowska、Adam Krówczyński、Joanna Kowalewska、Jerzy Romiszewski、Damian Pociecha、Jadwiga Szydłowska

  DOI：10.1080/15421406.2011.653714

  日期：2012.5.30

  The new Ni(II) metallomesogenes were synthesized. Their mesogenic cores are constructed from tetradental enaminoketone unit connected to 1,2: 3,4-di(4,5-dioctyloxybenzo) phenazine or 2,3-di(3,4-dioctyloxyphenylo) quinoxaline. The described compounds form columnar hexagonal phase (Col(hd)) in very broad temperature range. The high stability of the columnar phase results from presence of a permanent dipol moment in enaminoketone moieties created by strong electron withdrawing properties of carbonyl groups.